• Title/Summary/Keyword: Thermal time-of-flight

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Structure of epitaxial MgO layers on TiC(001) studied by time-of-flight impact-collision ion scattering spectroscopy (비행시간형 직충돌 이온산란 분광법을 사용한 TiC(001)면에 성장된 MgO막의 구조해석)

  • Hwang, Yeon;Souda, Ryutaro
    • Journal of the Korean Vacuum Society
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    • v.6 no.3
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    • pp.181-186
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    • 1997
  • Time-of-flight impact-collision ion scattering spectroscopy (TOF-ICISS) was applied to study the geometrical structure of epitaxially grown MgO layers on a TiC(001). The hetero-epitaxial MgO layer was able to be deposited by thermal evaporation of magnesium onto the TiC(001) surface and subsequent exposure of oxygen at room temperature. A slight heating of the substrate at around $300^{\circ}C$ was necessary to overcome a thermal barrier for the ordering. The well-ordered MgO structure was confirmed with the 1$\times$1 LEED pattern. TOF-ICISS was useful in studying interface structure between oxide and substrate. The results revealed that the MgO layer is formed at the on-top sites of the TiC(001) substrate and the lateral lattice constant of MgO layer is the same as that of the TiC substrate. The MgO was deposited within two layers on the most parts of the surface.

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Feedback flow control using the POD method on the backward facing step wall model

  • Cho, Sung-In;Lee, In;Lee, Seung-Jun;Lee, Choong Yun;Park, Soo Hyung
    • International Journal of Aeronautical and Space Sciences
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    • v.13 no.4
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    • pp.428-434
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    • 2012
  • Missiles suffer from flight instability problems at high angles of attack, since vortex flow over a fuselage cause lateral force to the body. To overcome this problem at a high angle of attack, the development of a real time vortex controller is needed. In this paper, Proper Orthogonal Decomposition (POD) and feedback controllers are developed for real time vortex control. The POD method is one of the most well known techniques for modeling low order models that represent the original full-order model. An adaptive control algorithm is used for real time control.

Screening Molecular Chaperones Similar to Small Heat Shock Proteins in Schizosaccharomyces pombe

  • Han, Jiyoung;Kim, Kanghwa;Lee, Songmi
    • Mycobiology
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    • v.43 no.3
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    • pp.272-279
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    • 2015
  • To screen molecular chaperones similar to small heat shock proteins (sHsps), but without ${\alpha}$-crystalline domain, heat-stable proteins from Schizosaccharomyces pombe were analyzed by 2-dimensional electrophoresis and matrix assisted laser desorption/ionization time-of-flight mass spectrometry. Sixteen proteins were identified, and four recombinant proteins, including cofilin, NTF2, pyridoxin biosynthesis protein (Snz1) and Wos2 that has an ${\alpha}$-crystalline domain, were purified. Among these proteins, only Snz1 showed the anti-aggregation activity against thermal denaturation of citrate synthase. However, pre-heating of NTF2 and Wos2 at $70^{\circ}C$ for 30 min, efficiently prevented thermal aggregation of citrate synthase. These results indicate that Snz1 and NTF2 possess molecular chaperone activity similar to sHsps, even though there is no ${\alpha}$-crystalline domain in their sequences.

Numerical Analysis on RF (Radio-frequency) Thermal Plasma Synthesis of Nano-sized Ni Metal (고주파 열플라즈마 토치를 이용한 Ni 금속 입자의 나노화 공정에 대한 전산해석 연구)

  • Nam, Jun Seok;Hong, Bong-Guen;Seo, Jun-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.5
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    • pp.401-409
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    • 2013
  • Numerical analysis on RF (Radio-Frequency) thermal plasma treatment of micro-sized Ni metal was carried out to understand the synthesis mechanism of nano-sized Ni powder by RF thermal plasma. For this purpose, the behaviors of Ni metal particles injected into RF plasma torch were investigated according to their diameters ($1{\sim}100{\mu}m$), RF input power (6 ~ 12 kW) and the flow rates of carrier gases (2 and 5 slpm). From the numerical results, it is predicted firstly that the velocities of carrier gases need to be minimized because the strong injection of carrier gas can cool down the central column of RF thermal plasma significantly, which is used as a main path for RF thermal plasma treatment of micro-sized Ni metal. In addition, the residence time of the injected particles in the high temperature region of RF thermal plasma is found to be also reduced in proportion to the flow rate of the carrier gas In spite of these effects of carrier gas velocities, however, calculation results show that a Ni metal particle even with the diameter of $100{\mu}m$ can be completely evaporated at relatively low power level of 10 kW during its flight of RF thermal plasma torch (< 10 ms) due to the relatively low melting point and high thermal conductivity. Based on these observations, nano-sized Ni metal powders are expected to be produced efficiently by a simple treatment of micro-sized Ni metal using RF thermal plasmas.

로켓 모션테이블 실시간 모의시험

  • Sun, Byung-Chan;Park, Yong-Kyu;Choi, Hyung-Don;Cho, Gwang-Rae
    • Aerospace Engineering and Technology
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    • v.3 no.1
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    • pp.170-178
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    • 2004
  • This paper deals with six degree-of-freedom HILS(hardware-in-the-loop-simulation) of KSR-III rocket using a TAFMS(three axis flight motion simulator). This TAFMS HILS test is accomplished before main HILS tests in order to verify the control stability in the presence of TAFMS dynamic effects. The TAFMS HILS test includes initial attitude holding tests for INS initial alignment procedures, timer synchronization tests with an auxiliary lift-off signal, real-time calibration tests using an external thermal recorder, open-loop TAFMS operating tests, and final closed-loop TAFMS HILS tests using the TAFMS attitude measurements as inputs to the closed control loop. The HILS tests are accomplished for several flight conditions composed with nominal flight condition, TWD effect added condition, slosh modes and/or bending modes existing condition, and windy condition, etc.

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Temporal Evolution and Ablation Mechanism of Laser-induced Graphite Plume at 355 nm

  • 최영구;임훙선;정광우
    • Bulletin of the Korean Chemical Society
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    • v.20 no.12
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    • pp.1501-1505
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    • 1999
  • Expansion dynamics of C$^{+}$ ions ejected from 355-nm laser ablation of graphite target in vacuum has been investigated by pulsed-field time-of-flight (TOF) mass spectrometry. A strong nonlinear dependence of the amount of desorbed C$^{+}$ ions on laser fluence is interpreted by the mechanism that C$^{+}$ ions are produced directly from the graphite via conversion of the multiphoton energy into thermal energy. The temporal evolution of C$^{+}$ ions was measured by varying the delay time of the ion repelling pulse with respect to the laser irradiation, which provides significant information on the ablated plume characterization. The TOF distributions of ablated ions showed a bimodal shape and could be fitted by shifted Maxwell-Boltzmann distributions. The velocity of the fast component increases with the delay time, whereas the slow component (< 500 m/s) exhibits a constant velocity. Also studied were the effects of the laser fluence on the energetics of C$^{+}$ ions.

Quasi-Transient Method for Thermal Response of Blunt Body in a Supersonic Flow (준-비정상해석 기법을 통한 초음속 유동 내 무딘 물체의 열응답 예측)

  • Bae, Hyung Mo;Kim, Jihyuk;Bae, Ji-Yeul;Jung, Daeyoon;Cho, Hyung Hee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.6
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    • pp.495-500
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    • 2017
  • In the boundary layer of supersonic or hypersonic vehicles, there is the conversion from kinetic energy to thermal energy, called aerodynamic heating. Aerodynamic heating has to be considered to design supersonic vehicles, because it induces severe heat flux to surface. Transient heat transfer analysis with CFD is used to predict thermal response of vehicles, however transient heat transfer analysis needs excessive computing powers. Loosely coupled method is widely used for evaluating thermal response, however it needs to be revised for overestimated heat flux. In this research, quasi-transient method, which is combined loosely coupled method and conjugate heat transfer analysis, is proposed for evaluating thermal response with efficiency and reliability. Defining reference time of splitting flight scenario for transient simulation is important on accuracy of quasi-transient method, however there is no algorithm to determine. Therefore the research suggests the algorithm with various flow conditions to define reference time. Supersonic flow field of blunt body with constant acceleration is calculated to evaluate quasi-transient method. Temperature difference between transient and quasi-transient method is about 11.4%, and calculation time reduces 28 times for using quasi-transient method.

Beam Characteristics of Polychromatic Diffracted Neutrons Used for Prompt Gamma Activation Analysis

  • S. H. Byun;G. M. Sun;Park, H. D.
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.30-41
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    • 2002
  • The neutron beam is fully characterized for the prompt gamma activation analysis facility at Hanaro in the Korea Atomic Energy Research Institute(KAERI). The facility uses thermal neutrons which are diffracted vertically from a horizontal beam port by a set of pyrolytic graphite(PG) crystals positioned at the Bragg angle of 45" Neutron spectra, neutron flux and Cd-ratio are determined for the three extraction modes of diffracted beam by means of the theoretical and experimental efforts. To obtain theoretical result, the reflectivity of pyrolytic graphite is calculated in the diffraction model for mosaic crystal and the angular divergence after diffraction by mosaic crystal is estimated from Monte Carlo simulation. The time-of-flight spectrometer and gold activation wire are used for measuring the neutron spectra. Both the calculated and measured spectra have proven that the unique feature of polychromatic beam obtained by PG crystals are useful for PGAA. The thermal neutron flux of 7.9$\times$107 n/cm$^2$s and the Cd-ratio of 266 for gold have been achieved at the sample position while the reactor operates at 24 MW The uniformity of beam flux is 12% in the central 1$\times$1 cm$^2$ area. Finally, the beam is briefly characterized by the effective velocity and temperature which are determined by measuring the prompt Y-ray spectra for thin and thick boron samples.ples.

LIMITED OXIDATION OF IRRADIATED GRAPHITE WASTE TO REMOVE SURFACE CARBON-14

  • Smith, Tara E.;Mccrory, Shilo;Dunzik-Gougar, Mary Lou
    • Nuclear Engineering and Technology
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    • v.45 no.2
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    • pp.211-218
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    • 2013
  • Large quantities of irradiated graphite waste from graphite-moderated nuclear reactors exist and are expected to increase in the case of High Temperature Reactor (HTR) deployment [1,2]. This situation indicates the need for a graphite waste management strategy. Of greatest concern for long-term disposal of irradiated graphite is carbon-14 ($^{14}C$), with a half-life of 5730 years. Fachinger et al. [2] have demonstrated that thermal treatment of irradiated graphite removes a significant fraction of the $^{14}C$, which tends to be concentrated on the graphite surface. During thermal treatment, graphite surface carbon atoms interact with naturally adsorbed oxygen complexes to create $CO_x$ gases, i.e. "gasify" graphite. The effectiveness of this process is highly dependent on the availability of adsorbed oxygen compounds. The quantity and form of adsorbed oxygen complexes in pre- and post-irradiated graphite were studied using Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and Xray Photoelectron Spectroscopy (XPS) in an effort to better understand the gasification process and to apply that understanding to process optimization. Adsorbed oxygen fragments were detected on both irradiated and unirradiated graphite; however, carbon-oxygen bonds were identified only on the irradiated material. This difference is likely due to a large number of carbon active sites associated with the higher lattice disorder resulting from irradiation. Results of XPS analysis also indicated the potential bonding structures of the oxygen fragments removed during surface impingement. Ester- and carboxyl-like structures were predominant among the identified oxygen-containing fragments. The indicated structures are consistent with those characterized by Fanning and Vannice [3] and later incorporated into an oxidation kinetics model by El-Genk and Tournier [4]. Based on the predicted desorption mechanisms of carbon oxides from the identified compounds, it is expected that a majority of the graphite should gasify as carbon monoxide (CO) rather than carbon dioxide ($CO_2$). Therefore, to optimize the efficiency of thermal treatment the graphite should be heated to temperatures above the surface decomposition temperature increasing the evolution of CO [4].

The Determination of Stress Distribution in WC-Ni Cemented Carbide Composites by Neutron Diffraction

  • Seol, Kyeongwon
    • Korean Journal of Materials Research
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    • v.5 no.2
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    • pp.232-238
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    • 1995
  • The thermal stress distribution of WC and Ni binder phases In WC-26st.%Ni and WC-6wt.%Ni composites has been investigated over the temperature range 100-900 K using a time-of-flight neutron diffractometer. To determine the stress distribution, the breadths of WC and Ni peaks in the reference powder and the composites were analyzed. The peak breadths were corrected for particle size effect using a procedure based on the integral peak breadth method of particle size-strain analysis. The result shows a broad range of strain, and thus stress, is present in the WC and Ni binder phases of the composites. The strain distribution of both phases broadens as the temperature decreases, and some fraction of total strain distribution of the WC phase remains tensile regardless of the temperature. The strain distribution of the WC phase broadens as the binder content increases, and that of Ni binder phase broadens as the binder content decreases, which means the strain distribution broadens as the absolute value of residual stress increase.

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