• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.2
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• pp.66-73
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• 2020

In the hydrogen compression cycle, which is currently being developed, hydrogen is compressed to a very high pressure using a compressor, and then stored and used in a high-pressure vessel. This shows that an increase in the temperature of hydrogen in the vessel due to a pressure rise during the filling process and the pressure fatigue due to the repeated cycle may cause problems in the reliability of the vessel. In this paper, for the entire processes in a 50 MPa hydrogen compression system, theoretical and numerical methods were conducted to analyze the following: the temperature increase of hydrogen in the vessel and the time required to reach thermal equilibrium with the surroundings, the change in temperature of hydrogen passing through the pressure reducing valve, and the required capacity of the heat exchanger for cooling the vessel. The results will be useful for the design and construction of hydrogen compression systems, such as hydrogen charging stations.

• Environmental and Resource Economics Review
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• v.16 no.1
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• pp.27-63
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• 2007

Using the CGE model, this paper investigates economic impacts of a shortage in crude oil resulting from voluntary export restraints, OPEC's agreement of a cut in oil production, and/or a storing on speculation. Unlike most previous studies considering oil price as the unpredictable variable, this study constructs the model to determine the oil price endogenously under the condition of an insufficient supply of crude oil. According to IEA's extraordinary steps for a shortage of crude oil, we investigate an economic impact of 7~12% shortage below the level of business as usual. The results show that oil price soars by 17.3~33.5%, the rate of economic growth falls by 0.52~0.96%p, and the consumer price index(CPI) rises by 0.8~1.51%p. These results imply that increasing in 1%p of oil price results in decreasing in 0.03%p of economic growth and increasing in 0.045%p of consumer price index. The production of electricity declines because of the increase in production cost. A shortage of crude oil has an effect on sources of electricity. Most reduction in electricity generation occurs from the reduction in the thermal power generation which is highly dependent on crude oil. The shortage of crude oil causes demand for petroleum to significantly decline but demand for coal and heat to increase because of the substitution effect with petroleum. Demand for gas rise in the first year but falls from the second year.

• Journal of Korean Ophthalmic Optics Society
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• v.6 no.2
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• pp.71-75
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• 2001

In this paper, a three-dimensional measuring system of thermoluminescence(TL) spectra based on temperature, wavelength and luminescence intensity was introduced. The system was composed of a spectrometer, temperature control unit for thermal stimulation, photon detector and personal computer for control the entire system. Temperature control was achieved by using feedback to ensure a linear-rise in the sample temperature. Digital multimeter(KEITHLEY 195A) measures the electromotive force of Copper-Constantan thermocouple and then transmits the data to the computer through GPIB card. The computer converts this signal to temperature using electromotive force-temperature table in program, and then control the power supply through the D/A converter. The spectrometer(SPEX 1681) is controlled by CD-2A, which is controlled by the computer through RS-232 communication port. For measuring the luminescence intensity during the heating run, the electrometer(KEITHLEY 617) measures the anode current of photomultiplier tube(HAMAMATSU R928) and transmits the data to computer through the A/D converter. And, we measured and analyzed thermoluminescence of $CaSO_4$ : Dy, P using the system. The measuring range of thermoluminescence spectra was 300K-575K and 300~800 nm, $CaSO_4$ : Dy. P was fabricated by the Yamashita's method in Korea Atomic Energy Research Institute(KAERI) for radiation dosimeter. Thermoluminesce spectra of the $CaSO_4$ : Dy, P consist of two main peak at temperature of $205^{\circ}C$, wavelength 476 nm and 572 nm and with minor ones at 658 nm and 749 nm.

• Journal of the Korean Institute of Intelligent Systems
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• v.26 no.3
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• pp.246-252
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• 2016

Since thermal power plant (TPP) equipment is operated under very high pressure and temperature, failures of the equipment give rise to severe losses of life and property. To prevent the losses, fault detection method is, therefore, absolutely necessary to identify abnormal operating conditions of the equipment in advance. In this paper, we present Mahalanobis distance (MD) based fault detection method for steam boiler tube in TPP. In the MD-based method, it is supposed that abnormal data samples are far away from normal samples. Using multivariate samples collected from normal target system, mean vector and covariance matrix are calculated and threshold value of MD is decided. In a test phase, after calculating the MDs between the mean vector and test samples, alarm signals occur if the MDs exceed the predefined threshold. To demonstrate the performance, a failure case due to boiler tube leakage in 200MW TPP is employed. The experimental results show that the presented method can perform early detection of boiler tube leakage successfully.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.6
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• pp.585-592
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• 2011

The enhancement of the cold-start capability of polymer electrolyte fuel cells is of great importance in terms of the durability and reliability of fuel-cell vehicles. In this study, vanadium oxide films deposited onto the flat surface of metallic bipolar plates were synthesized to investigate the feasibility of their use as an efficient self-heating source to expedite the temperature rise during startup at subzero temperatures. Samples were prepared through the dip-coating technique using the hydrolytic sol-gel route, and the chemical compositions and microstructures of the films were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and field-emission scanning electron microscopy. In addition, the electrical resistance hysteresis loop of the films was measured over a temperature range from -20 to $80^{\circ}C$ using a four-terminal technique. Experimentally, it was found that the thermal energy (Joule heating) resulting from self-heating of the films was sufficient to provide the substantial amount of energy required for thawing at subzero temperatures.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.28 no.1
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• pp.71-78
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• 1992

Zr-4 used for a cladding and an end plug of reactor component has creep deformation under operation at high temperature. Creep is regarded as the time dependent deformation of a material under constant applied stress. Although the major source of the deformation of zirconium component in water-cooled reactors is irradiation creep, the thermal creep may give a rise to significant deformation in reactor component especially at relatively high temperatures and at various constant stresses, and therefore it must be predicted accurately. Stress relaxation is the time dependent change of stress at constant strain and it is a process related intimately to creep. In this paper, the creep behavior and stress relaxation of Zr-4 is examined at the temperature of 50$0^{\circ}C$ that is 40% of the absolute melting temperature of Zr-4 under the stress below yield stress and under the various constant strains. The results obtained are summarized as follows: 1) With an increase of stress, the steady state creep rate increases and the creep rupture time decreases. 2) The steady state creep rate $\varepsilon$(%/s) for the stress $\sigma$sub(c) (kgf/mm super(2)) of Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 are in accord with Norton's model equation($\varepsilon$=K$\sigma$ sub(c) super (n)). The constants of materials computed are as follows: K=3.9881$\times$10 super(-5), n=1.9608 3) The rupture time T sub(r) (hr) decreases linearly with the increase of stress on the log-log scaled graph. The empirical equations computed for Zr-4 are in accord with Bailey's model equation (T sub(r)=K sub(1)$\sigma$sub(c) super(m)). The constants of materials computed are as follows: K sub(1)=1.2875$\times$10 super(16), m=-3.467 4) It seems clear that the strain could be quantitatively dependent on the high temperature creep properties such as creep stress, rupture time, steady state creep rate and total creep rate. It is found that these relationships are linear on the log-log graph. 5) In stress relaxation test, as the critical constant strain that can be allowed to the specimen is larger, stress relaxation becomes more rapid, and as the constant strain is smaller, the stress relaxation becomes slower.

• Journal of the Korea Institute of Building Construction
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• v.12 no.2
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• pp.203-210
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• 2012

Recently, the interest and demand for large-scale buildings and skyscrapers have been on the rise, and the performance of concrete is an area of high priority. Securing 'mass concrete and high strength concrete' is very important as a key construction technology. For high strength concrete, the high heat of hydration takes place inside the concrete because of the vitality of hydration in cement due to the large amount of powder, and leads to problems such as an increase of thermal stress due to the temperature difference with the outside, which results in cracks and slump loss. For this reason, measures to solve these problems are needed. This study aims to reduce the hydration heat of high strength concrete to control the hydration heat of mass concrete and high strength concrete, by replacing the type of admixture, The purpose of this study is to control the hydration heat of high strength concrete and mass concrete. Our idea for this purpose is to apply not only the types and contents of admixture but also incorporation mixing water to ice-flake. As a result of the test, the use of blast furnace slag and fly ash as admixture, and the use of ice-flake as mixing water can improve the liquidity of concrete and reduce slump loss. Significantly dropping the maximum temperature will contribute greatly to reducing cracks due to hydration heat in mass concrete and high strength concrete, and improve quality.

• Journal of Preventive Medicine and Public Health
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• v.27 no.1 s.45
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• pp.59-73
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• 1994

The purpose of this study is to experiments the environmental conditions and the adaption of the human body in the vinyl house. The study was done in spring and winter and experimental clothes were used working clothes in the vinyl house. The results are as follows. 1. Environmental Conditions In the spring season, the indoor air temperature was $27.4{\pm}3.7^{\circ}C$ and the outdoor air temperature was $14.4{\pm}2.7^{\circ}C$. In the winter season, the indoor air temperature was $18.3{\pm}4.8^{\circ}C$ and the outdoor air temperature was $7.6{\pm}2.5^{\circ}C$ on the average. 2. Skin Temperature In the spring season, the mean skin temperatures indoor and outdoor were $33.81{\pm}0.7^{\circ}C\;and\;31.57{\pm}0.8^{\circ}C$ respectively, a difference of $2.24^{\circ}C$. In the winter season, they were $31.95{\pm}1.93^{\circ}C\;and\;29.86{\pm}0.55^{\circ}C$ respectively, a difference of $2.09^{\circ}C$. 3. Clothing Climate In the spring season, the temperature and humidity in the inner layer of clothing were $34.77{\pm}0.80^{\circ}C\;and\;70.75{\pm}1.65%$ indoor, $31.9{\pm}0.52^{\circ}C\;and\;51.9{\pm}3.70%$ outdoor respectively. In the winter season, those were $32.52{\pm}1.04^{\circ}C\;and\;64.65{\pm}3.68%$ indoor, $30.27{\pm}0.96^{\circ}C\;and\;45.07{\pm}2.68%$ outdoor respectively. 4. Physiological Factors Body temperature increased slightly and the pulse rate also rises, but blood pressure decreased a little with the rise of environmental temperature both in the spring and winter seasons. 5. Psychological Factors Thermal sensation in the spring season was expressed as 'slightly warm' or 'warm' indoor and as 'neutral' in the open air, while in the winter it was expressed as 'neutral' or 'slightly warm' outdoor the house and as 'cold' in the open air. Comfort sensation was characterized as 'uncomfortable' or 'slightly uncomfortable' indoor both in the spring and winter seasons, but in the open air it was characterized as 'comfortable' in the spring and as 'slightly uncomfortable' in the winter.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.434-435
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• 2012

Plasma enhanced chemical vapor deposition (PECVD) silicon dioxide thin films have many applications in semiconductor manufacturing such as inter-level dielectric and gate dielectric metal oxide semiconductor field effect transistors (MOSFETs). Fundamental chemical reaction for the formation of SiO2 includes SiH4 and O2, but mixture of SiH4 and N2O is preferable because of lower hydrogen concentration in the deposited film [1]. It is also known that binding energy of N-N is higher than that of N-O, so the particle generation by molecular reaction can be reduced by reducing reactive nitrogen during the deposition process. However, nitrous oxide (N2O) gives rise to nitric oxide (NO) on reaction with oxygen atoms, which in turn reacts with ozone. NO became a greenhouse gas which is naturally occurred regulating of stratospheric ozone. In fact, it takes global warming effect about 300 times higher than carbon dioxide (CO2). Industries regard that N2O is inevitable for their device fabrication; however, it is worthwhile to develop a marginable nitrous oxide free process for university lab classes considering educational and environmental purpose. In this paper, we developed environmental friendly and material cost efficient SiO2 deposition process by substituting N2O with O2 targeting university hands-on laboratory course. Experiment was performed by two level statistical design of experiment (DOE) with three process parameters including RF power, susceptor temperature, and oxygen gas flow. Responses of interests to optimize the process were deposition rate, film uniformity, surface roughness, and electrical dielectric property. We observed some power like particle formation on wafer in some experiment, and we postulate that the thermal and electrical energy to dissociate gas molecule was relatively lower than other runs. However, we were able to find a marginable process region with less than 3% uniformity requirement in our process optimization goal. Surface roughness measured by atomic force microscopy (AFM) presented some evidence of the agglomeration of silane related particles, and the result was still satisfactory for the purpose of this research. This newly developed SiO2 deposition process is currently under verification with repeated experimental run on 4 inches wafer, and it will be adopted to Semiconductor Material and Process course offered in the Department of Electronic Engineering at Myongji University from spring semester in 2012.

• Membrane Journal
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• v.27 no.2
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• pp.154-166
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• 2017

Polymeric films for gas barrier applications such as food packaging and electronic devices have attracted great interest due to their cheap, light and easy processability among gas barrier materials. Especially in electronic devices, extremely low gas permeance is necessary for maintaining the device performance. However, current polymeric barrier films still suffer from relatively high gas permeance than other materials. Therefore, there have been strong needs to enhance the gas barrier performance of polymeric barrier films while keep their own advantages. Recently, graphene is highlighted as a 2D-layered material for gas barrier applications. However, owing to the poor workability and difficulty to produce in engineering scale, graphene oxide (GO) is on the rise. GO consists of oxygen-containing functional groups on surface with intrinsic 2D-layered structure and high aspect ratio, and it can be well-dispersed in aqueous polar solvents like water, resulting in scalable mass production. Here, we prepared GO incorporated polyimide (PI) nanocomposites. PI is widely used barrier polymer with high mechanical strength and thermal and chemical stability. We demonstrated that PI/GO nanocomposites could perform as a gas barrier. Furthermore, surfactants (Triton X-100 (TX) and Sodium deoxycholate (SDC)) are introduced to enhance the gas barrier performance by improving the degree of dispersion of GO in PI matrix. As a result, TX enhanced the gas barrier performance of PI/GO nanocomposites which is similar to predicted value. This finding will provide new insight to polymer nanocomposites for gas barrier applications.