• 한국잠사곤충학회지
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• 제34권1호
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• pp.49-56
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• 1992

반응개시제로 potassium persulfate를 사용하여 견섬유에 MAA를 처리하였을 때의 반응 mechanism을 구명하기 위하여, 열분석과 일련의 기구분석을 행하였으며, 이 중 열분석에 의해 얻어진 결과는 다음과 같다. Differential scanning calorimeter 관찰로부터는 metharcrylamide에 의한 가공견섬유는 견 fibroin과 methacrylamide polymer의 열분석에 의한 peak가 뚜렷하게 분리되어 나타났으며, 가공율이 증가함에 따라 두 peak가 모두 고온측으로 이동하는 것으로 나타났다. 가공견섬유의 흡습율은 가공율이 증가함에 따라 증가하였다.

• 한국산학기술학회논문지
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• 제17권9호
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• pp.126-132
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• 2016

본 연구는 전산유체역학 기법을 이용하여 수소 생산 플랜트의 개질 튜브 공정가스와 버너 가스 온도에 따른 화학반응과 열변형 특성을 분석한다. 개질로 내부의 온도는 약 800 K 내지 1000 K 이상으로 고온으로 유지되기 때문에 튜브의 열변형 문제가 심각하게 발생할 수 있다. 따라서 개질로의 구조건전성을 평가하고 안정된 생산력을 가진 장비를 운영하기 위해서 반응과 열변형 특성에 대한 이해는 필수적이다. 본 연구는 상용 전산해석 코드(ANSYS Fluent/Mechanical V.13.0)를 사용하여, 대류, 전도 및 복사 열전달을 포함한 복합 열전달과 난류유동을 3차원적으로 해석하였다. 특히, 열유동 특성에 따른 연성해석(Fluid-Solid Interaction: FSI)를 수행하였으며 고온 버너가스와 공정가스 운전조건에 따른 반응 특성과 열변형 변화를 분석하였다. 수치해석 결과, 개질 공정가스와 버너 가스의 주입온도가 각각 200 K 감소하면, 수소생성량은 최대 약 4 배, 최소 약 2 배 감소한다. 또한, 공정가스와 버너 가스의 주입온도에 따라 열변형은 최대 약 20%, 최소 약 15% 감소한다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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• pp.267-273
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• 2012

Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber-the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam-was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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• pp.80-86
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• 2011

Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber - the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam - was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

• 대한기계학회논문집B
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• 제25권11호
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• pp.1594-1605
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• 2001

In this study, a numerical simulation was developed which was capable of predicting the characteristics of NO formation in pilot scale combustor adopting the air-staged burner flame. The numerical calculation was constructed by means of establishing the mathematical models fur turbulence, turbulent combustion, radiation and turbulent nitric oxide chemistry. Turbulence was solved with standard k-$\xi$ model and the turbulent combustion model was incorporated using a two step reaction scheme together with an eddy dissipation model. The radiative transfer equation was calculated by means of the discrete ordinates method with the weighted sum of gray gases model for CO$_2$and H$_2$O. In the NO chemistry model, the chemical reaction rates for thermal and prompt NO were statistically averaged using the $\beta$ probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-air staged burner has been designed and fabricated. Only when the radiation was taken into account, the predicted gas temperature was in good agreement with the experimental one, which meant that the inclusion of radiation was indispensable for modeling multi-air staged gas flame. This was also true of the prediction of the NO formation, since it heavily depended on temperature. Subsequently, it was found that the multi-air staged combustion technique might be used as a practical tool in reducing the NO formation by controlling the peak flame temperature.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제20권4호
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• pp.355-374
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• 2016

This work is devoted to investigate heat and mass transfer effects on MHD natural convection flow past an inclined plate with ramped temperature numerically. The dimensionless governing equations for this investigation are solved by using finite element method. The effects of angle inclination, buoyancy ratio parameter, permeability parameter, magnetic parameter, Prandtl number, heat generation, thermal radiation, Eckert number, Schmidt number, chemical reaction parameter and time on velocity, temperature and concentration fields are studied and presented with the aid of figures. The effects of the pertinent parameters on skin friction, rate of heat transfer and mass transfer coefficients are presented in tabular form. The numerical results are compared graphically with previously published result as special case of the present investigation and results found to be in good agreement.

• 대한기계학회논문집B
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• 제27권2호
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• pp.215-226
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• 2003

Experimental and numerical studies have been done to examine the effects of excess air ratio and tertiary air swirl number on the formation characteristics of NOx in a pilot scale combustor adopting a multi-air staged burner. In numerical calculation the mathematical models for turbulence, radiation and nitric oxide chemistry were taken into account. The radiative transfer equation was solved using the discrete ordinates method with the weighted sum of gray gases model. In the NOx chemistry model, the chemical reaction rates for thermal and prompt NOx were statistically averaged using a probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-staged air burner has been designed and fabricated. Using the numerical simulation developed here, a variation of thermal and prompt NOx formation was predicted by changing the excess air ratio and tertiary air swirl number. As the excess air ratio increased up to 1.9, the formation of the total as well as thermal NOx at exit increased while the prompt NOx decreased. The formation of thermal NOx was more affected by concentration of $O_2$ and $N_2$ than gas temperature. When the tertiary air swirl number increased, the formation of the total as well as the prompt NOx slightly decreased.

• 폴리머
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• 제34권5호
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• pp.485-489
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• 2010

본 연구에서는 폴리락트산(PLA)의 용융강도를 높이기 위하여 PLA에 글리시딜 메타크릴레이트(GMA)를 PLA에 첨가한 후 전자선을 조사하여 PLA를 개질하였다. GMA는 5 phr(parts per hundred parts of resin)로 고정하고 전자선 조사량을 변화시키며 개질 PLA을 제조하였으며, 이후 열적, 유변학적 특성 및 젤화도를 조사하였다. 주파수 0.1 rad/s에서 조사량 300 kGy로 개질된 PLA와 순수 PLA의 유변학적 물성을 서로 비교해보면 복합점도는 약 210배, 탄성률은 약 14500배 상승하는 예외적으로 아주 큰 변화를 보였다. 젤화도의 결과로 조사량 200 kGy 이하로 조사된 시료에서 일어난 분자반응은 가교화 반응보다는 가지화 반응이 우세하다는 것을 알 수 있었다.

• 한국분말재료학회지
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• 제6권4호
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• pp.314-319
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• 1999

The solid state reaction by mechanical alloying(MA) generally proceeds by lowering the free energy as the result of a chemical reaction at the interface between the two adjacent layers. However, Lee et $al.^{1-5)}$ reported that a mixture of Cu and Ta, the combination of which is characterized by a positive heat of mixing of +2kJ/mol, could be amorphized by mechanical alloying. This implies that there exists an up-hill process to raise the free energy of a mixture of pure Cu and la to that of an amorphous phase. It is our aim to investigate to what extent the MA is capable of producing a non-equilibrium phase with increasing the heat of mixing. The system chosen was the ternary $Cu_{30}Ta_{ 70-x}Mo_ x$ (x=35, 10). The mechanical alloying was carried out using a Fritsch P-5 planetary mill under Ar gas atmosphere. The MA powders were characterized by the X-ray diffraction with Cu-K $\alpha$ radiation, thermal analysis, electron diffraction and TEM micrographs. In the case of x=35, where pure Cu powders were mixed with equal amount of pure Ta and Mo powders, we revealed the formation of bcc solid solution after 150 h milling but its gradual decomposition by releasing fcc-Cu when milling time exceeded 200 h. However, an amorphous phase was clearly formed when the Mo content was lowered to x=10. It is believed that the amorphization of ternary $Cu_{30}Ta_{60}Mo_{10}$ powders is essentially identical to the solid state amorphization process in binary $Cu_{30}Ta_{70}$ powders.

• 해양환경안전학회지
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• 제27권7호
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• pp.1074-1081
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• 2021

아산화질소(N₂O, Nitrous Oxide)는 6대 온실가스 중 하나로 대기 중에서 적외선을 흡수하여 온실효과를 유발하는 것으로 알려져 있다. 특히 지구온난화지수(GWP)는 CO₂에 비해 310배 높아 국내뿐만 아니라 전 세계적으로 이슈화되고 있으며, 그에 따른 강력한 환경 규제 강화법들이 발의되고 있다. N₂O 저감 기술에는 물리적인 방식에 따라 농축회수, 촉매분해, 그리고 열분해로 구분할 수 있는데, 본 연구에서는 그 중 가장 효과적인 열분해 처리방식에 대해 논의하고자 일반적인 연소 조건 내 고온 열분해 방식을 이용하여 비용 저감과 함께 질소산화물을 저감시키는 온도 조건 및 반응 시간에 대한 정보를 제공하고자 한다. 열분해 조건으로 선정된 고온 영역은 1073 K부터 1373 K까지 100 K 간격을 두고 계산을 수행하였다. 1073 K과 1173 K의 온도조건에 경우, N₂O 저감율과 일산화질소 농도가 체류시간에 따라 비례관계를 이루는 것이 관측되었으며, 1273 K에 경우, 체류시간이 증가함에 따라 발생되는 역반응으로 인해 N₂O 저감율이 감소되는 것이 관측되었다. 특히 1373 K에 경우, 모든 체류시간에 대해 정반응과 역반응이 화학 평형상태에 도달하여 N₂O 저감에 대한 반응진행율이 오히려 감소하는 것으로 확인되었다.