• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.17.2-17.2
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• 2011

Double-walled carbon nanotubes (DWCNTs) were grown with vertical alignment on a Si wafer by using catalytic thermal chemical vapor deposition. This study investigated the effect of pre-annealing time of catalyst on the types of CNTs grown on the substrate. The catalyst layer is usually evolved into discretely distributed nanoparticles during the annealing and initial growth of CNTs. The 0.5-nm-thick Fe served as a catalyst, underneath which Al was coated as a catalyst support as well as a diffusion barrier on the Si substrate. Both the catalyst and support layers were coated by using thermal evaporation. CNTs were synthesized for 10 min by flowing 60 sccm of Ar and 60 sccm of H2 as a carrier gas and 20 sccm of C2H2 as a feedstock at 95 torr and $750^{\circ}C$. In this study, the catalyst and support layers were subject to annealing for 0~420 sec. As-grown CNTs were characterized by using field emission scanning electron microscopy, high resolution transmission electron microscopy, Raman spectroscopy, and atomic force microscopy. The annealing for 90~300 sec caused the growth of DWCNTs as high as ~670 ${\mu}m$ for 10 min while below 90 sec and over 420 sec 300~830 ${\mu}m$-thick triple and multiwalled CNTs occurred, respectively. Several radial breathing mode (RBM) peaks in the Raman spectra were observed at the Raman shifts of 112~191 cm-1, implying the presence of DWCNTs, TWCNTs, MWCNTs with the tube diameters 3.4, 4.0, 6.5 nm, respectively. The maximum ratio of DWCNTs was observed to be ~85% at the annealing time of 180 sec. The Raman spectra of the as-grown DWCNTs showed low G/D peak intensity ratios, indicating their low defect concentrations. As increasing the annealing time, the catalyst layer seemed to be granulated, and then grown to particles with larger sizes but fewer numbers by Ostwald ripening.

• Journal of Institute of Convergence Technology
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• v.5 no.1
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• pp.13-17
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• 2015

In wafer level molding progress, the thermal releasing failure phenomenon is shown up as the important problem. This phenomenon can cause the problem including the warpage, crack of the molded wafer. The thermal releasing failure is due to the insufficiency of adhesion strength degradation of the molding tape. To solve this problem, we studied experimental method increasing the release property of the molding tape through the plasma surface treatment on the wafer substrate. In this research, the vacuum plasma treatment system is used for release property improvement of the molding tape and controls the operating condition of the hydrophilic($O_2$, 100kW, 10min) and hydrophobic($C_2F_6$, 200kW, 10min). In order to perform the peeling test for measuring the releasing force precisely, we remodel the micro scale material property evaluation system developed by Korea institute of industrial technology. In case of hydrophilic surface treatment on the wafer substrate, we can figure out the releasing property of molding tape increase. In order to grasp the effect that it reaches to the release property increase when repeating the hydrophilic treatment, we make an experiment with twice treatment and get the result to increase about 12%. We find out the hydrophilic surface treatment method using plasma can improve releasing property of molding tape in the wafer level molding process.

• Tribology and Lubricants
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• v.30 no.4
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• pp.224-233
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• 2014

We prepared polyester-polyamines to improve the effect of carbon black dispersibility for use in thermal transfer ink, and synthesized polymeric dispersing agents by two-step reactions. In the first step, we made polyester by polycondensing 1,6-hexanediol and adipic acid. The resulting polymers had carboxylic acid, which was linked with polyamine via an acid-base reaction. We then characterized the polyester-polyamine structure by NMR spectroscopy and Fourier transform infrared spectroscopy (FT-IR). We also determined the basic characterizations such as total acid numbers (TAN) (5.0-67.5 mgKOH/g), hydroxyl values (27.1-67.5 mgKOH/g), and molar masses ($M_n=1.6-8.4kg\;mol^{-1}$) for the polyester and total base numbers (TBN) (15.3-57.1 mgKOH/g), hydroxyl values (33.0-79.8 mgKOH/g), and nitrogen contents (1.02-3.48%) for the polyester-polyamine polymers. We thus prepared thermal transfer ink using carbon blacks and the polyester-polyamine dispersing agents, and evaluated the resulting mixtures for printability, adhesive force, storage stability, ink appearance, ink gloss, and processability. These mixtures showed significant dispersibility for carbon black in the ink. Thus, we concluded that the dispersibility of the polymeric materials depended on the polyamine structure and the hydrophilicity-hydrophobicity distribution of the polymeric dispersants.

• The KSFM Journal of Fluid Machinery
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• v.17 no.6
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• pp.104-108
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• 2014

The recent Fukushima nuclear power plant accidents shows that the core make up at high RCS pressure condition is very important to prevent core melting. The core make up flow at high pressure condition should be driven by gravity force or passive forces because the AC-powered safety features are not available during a Station Black Out (SBO) accident. The reactor Coolant System (RCS) mass inventory is continuously decreased by releasing steam through the pressurizer safety valves after reactor trip during a SBO accident. The core will be melted down within 2~3 hours without core make up action by active or passive mode. In the new design concept of a Hybrid Safety Injection Tank (Hybrid SIT) both for low and high RCS pressure conditions, the low pressure nitrogen gas serves as a charging pressure for a LBLOCA injection mode, while the PZR high pressure steam provides an equalizing pressure for a high pressure injection mode such as a SBO accident. After the pressure equalizing process by battery driven initiation valve at a high pressure SBO condition, the Hybrid SIT injection water will be passively injected into the reactor downcomer by gravity head. The SBO simulation by MARS code show that the core makeup injection flow through the Hybrid SIT continued up to the SIT empty condition, and the core heatup is delayed as much.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2523-2528
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• 2014

In the present study, at first, azo Schiff base ligand of (N,N'-bis(5-phenylazosalicylaldehyde)-ethylenediamine) ($H_2L$) has been synthesized by condensation reaction of 5-phenylazosalicylaldehyde and ethylenediamine in 2:1 molar ratio, respectively. Then, its cobalt complex (CoL) was synthesized by reaction of $Co(OAc)_2{\cdot}4H_2O$ with ligand ($H_2L$) in 1:1 molar ratio in ethanol solvent. This ligand and its cobalt complex containing azo functional groups were characterized using elemental analysis, $^1H$-NMR, UV-vis and IR spectroscopies. Subsequently, the interaction between native calf thymus deoxyribonucleic acid (ct-DNA) and CoL complex was investigated in 10 mM Tris/HCl buffer solution, pH = 7 using UV-vis absorption, thermal denaturation technique and viscosity measurements. From spectrophotometric titration experiments, the binding constant of CoL complex with ct-DNA was found to be $(2.4{\pm}0.2){\times}10^4M^{-1}$. The thermodynamic parameters were calculated by van't Hoff equation.The enthalpy and entropy changes were $5753.94{\pm}172.66kcal/mol$ and $43.93{\pm}1.18cal/mol{\cdot}K$ at $25^{\circ}C$, respectively. Thermal denaturation experiments represent the increasing of melting temperature of ct-DNA (about $0.93^{\circ}C$) due to binding of CoL complex. The results indicate that the process is entropy-driven and suggest that hydrophobic interactions are the main driving force for the complex formation.

• Journal of the Korean Society for Precision Engineering
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• v.7 no.1
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• pp.37-52
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• 1990

In this study, the characteristics of cooling and rolling during strip casting process is obtained in comparison with the experimental and analytical results. The prupose of this study is to effectively analyze the thermal and mechanical deformation of roller applying the results of the heat transfer and the pressure distribution to boundary conditions. And then the relation between strip thickness and roll deformation is shown. The second purpose is to obtain the proper condition of the continuous casting for stainless steel. The summary and conclusions can be made on the basis of the results obtained by the theories and experiments. a) The strip casting condition for the fine surface quality of tin-alloy as-cast material was obtained in accordance with the velocity of roll rotation and initial roll gap. b) The experimental condition that the dimension of the cast strip thickness coincide with that of the initial roll gap was according to the experimental result of continuous casting by twin-roll type. c) The thermoelastic finite element model to calculate the roll deformation is represented. Thermoelastic model prediction for the roll deformation are in good agreement with the experimental results considering the thermal expansion of the roll. d) The higher cooling rates were obtained by a twin-roller quenching technique. Also quenched microstructure of the rapidly solidified shell was verified. e) The magnitude of roll deformation due to the thermal expansion and roll separating force is quantit- atively represented in the analysis of continuous casting for stainless steel.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.19 no.1
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• pp.44-51
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• 2005

In this paper, reduction characteristics of the AC and DC flashover voltage in the horizontal air gap of sphere-sphere electrode system were investigated when the combustion flame was present near the high voltage electrode. The voltage and current waveforms were measured, when the flashover is occurred, in order to examine the flashover polarity by flame. The reduction characteristics of AC flashover voltage were discussed with the thermal ionization process, the relative air density and the deflection phenomena in the shape of flames that caused by the coulomb's force. As the results of an experimental investigation, It was found that the reduction of flashover voltages in sphere-sphere system, in comparison with the no flame case, are $79.9[\%]$ for k=0, $82.9[\%]$ for k=0.5, $87.5[\%]$ for k=1.0, $85.0[\%]$ for h=0[cm], $40.8[\%]$ for h=5[cm] and $28.2[\%]$ for h=9[cm] when ac voltage is applied. The influence for thermal ionization process of the combustion flame in small scale no particular change is recognized.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.11
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• pp.1979-1985
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• 2003

Fretting is a kind of surface degradation mechanism observed in mechanical components and structures. The fretting damage decreases in 50-70% of the plain fatigue strength. This may be observed in the fossil power plant and the nuclear power plant used in special environments and various loading conditions. The thermal degradation of material is observed when the heat resisting steel is exposed for long period time at the high temperature. In the present study, the degraded 1Cr-0.5Mo steel used for long period time at high temperature (about 515$^{\circ}C$) and artificially reheat-treated materials are prepared. These materials are used for evaluating an effect of thermal aging on the fretting fatigue behavior. Through the experiment, it is found that the fretting fatigue endurance limit of the reheat-treated 1Cr-0.5Mo steel decreased about 46% from the non-fretting fatigue endurance limit, while the fretting fatigue endurance limit of the degraded 1Cr-0.5Mo steel decreased about 53% from the non-fretting fatigue endurance limit. The maximum value of fatigue endurance limit difference is observed as 57%(244 MPa) between the fretting fatigue of degraded material and non-fretting fatigue of reheat-treated material. These results can be a basic data to a structural integrity evaluation of heat resisting steel considered to thermal degradation effect.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.9
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• pp.1227-1233
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• 2010

In the hot section of a gas turbine, the turbine blades were protected from high temperature by providing a thermal barrier coating (TBC) as well as by cooling air flowing through internal passages within the blades. The cooling air then passed through discrete holes on the blade surface, creating a film of cooling air that further protects the surface from the hot mainstream flow. The holes are subjected to stresses resulting from the lateral growth of thermally grown oxide, the thermal expansion misfit between the constituent layers, and the centrifugal force due to high-speed revolution; these stresses often result in cracking. In this study, the deformation and cracks occurring near a hole on a heat-resistant alloy subjected to thermo-mechanical cycling were investigated. The experiment showed that cracks formed around the hole depending on the applied stress level and the number of cycles. These results could be explained by our analytic solution.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2012.10a
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• pp.255-258
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• 2012

In this paper, with a thermoelectric device using the seebeck effect which generates electromotive force by temperature difference generates electric energy an energy harvesting circuit using MPPT(Maximun Power Point Traking) control is designed. After periodically sampling the open voltage of the thermoelectric device, the 1/2 voltage of open voltage which in a maximum power point is maintained through MPPT control circuit and harvested energy from thermoelectric device is delivered to load through a switch. The proposed thermal energy harvesting circuit is designed with $0.35{\mu}m$ CMOS process and the chip area excluding pads is $1168.7{\mu}m{\times}541.3{\mu}m$.