• Proceedings of the KSME Conference
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• 2001.06a
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• pp.138-143
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• 2001

To perform the rigorous integrity evaluation of RPV, it is necessary to consider metallurgical factors such as microstructure evolution during multi-pass welding process and PWHT. The microstructures of the heat affected zone(HAZ) of SA508 steel were predicted by a combination of simulated thermal analysis and a simple kinetic models for austenite grain growth and austenite-ferrite transformation. Phase equilibrium of SA508 steel were calculated using a Thermo-Calc package. Carbide growth in th HAZ were predicted by a empirical model, taking into account the predicted microstructure evolution.

• Journal of the Korean institute of surface engineering
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• v.32 no.6
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• pp.686-694
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• 1999

Insoluble anodes of the Ta/Ir mixed metal oxide for electrodeposition of Ni-W alloy in ammoniacal citrate bath were prepared by thermal decomposition method. Ti plate was etched in boiling oxalic acid solution and coated with ethanol solution of $TaCl_{5}$ and $IrCl_4$ mixed in a fixed ratio, followed by drying and treating at various temperatures. The coating layer of these insoluble anode was characterized by SEM, EDX, XRD and DSC. The decomposition rate of citric acid in plating bath was determined by measuring the $CO_2$ gas evolved at the anodes with Gas Chromatography. Evolution of $CO_2$ gas from Ta/Ir oxide anodes decreased about 5% compared with that of Pt. The $CO_2$ gas evolution was increased with the amount of Ir-oxide in the coatings. The coatings which have more than 40% ratio of Ta content and heat-treated at the temperature higher than $400^{\circ}C$ showed better efficiency

• Proceedings of the KSR Conference
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• 2008.06a
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• pp.964-968
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• 2008

Infrared thermography using high-speed infrared camera has been recognized as a powerful method for various potential applications, such as nondestructive inspection, failure analysis, stress analysis, and medical fields, due to non-contact, high-speed, and high spatial resolution at various temperature ranges. In this investigation, damage evolution due to generation of hot spots on railway brake disc was investigated using the infrared thermography method. A high-speed infrared camera was used to measure the surface temperature of brake disc as well as for in-situ monitoring of hot spot evolution. From the thermographic images, the observed hot spots and thermal damage of railway brake disc during braking operation were qualitatively analyzed. Moreover, in this investigation, the previous experimental and theoretical studies on hot spots phenomenon were reviewed, and the current experimental results were introduced and compared with theoretical prediction.

• Journal of the Korean Ceramic Society
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• v.43 no.8 s.291
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• pp.469-471
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• 2006

The effects of $Cr_2O_3$ on the microstructural evolution and mechanical properties of $Al_2O_3$ polycrystalline were investigated. The microstructure of $Al_2O_3-Cr_2O_3$ composites (ruby) was carefully controlled in order to obtain dense and fine-grained ceramics, thereby improving their properties and reliability with respect to numerous applications related to semiconductor bonding technology. Ruby composites were produced by Ceramic Injection Molding (CIM) technology. Room temperature strength, hardness, Young's modulus and toughness were determined, as well as surface strengthening induced by thermal treatment and production of a fine-grained homogenous microstructure.

• Bulletin of the Korean Chemical Society
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• v.20 no.12
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• pp.1501-1505
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• 1999

Expansion dynamics of C$^{+}$ ions ejected from 355-nm laser ablation of graphite target in vacuum has been investigated by pulsed-field time-of-flight (TOF) mass spectrometry. A strong nonlinear dependence of the amount of desorbed C$^{+}$ ions on laser fluence is interpreted by the mechanism that C$^{+}$ ions are produced directly from the graphite via conversion of the multiphoton energy into thermal energy. The temporal evolution of C$^{+}$ ions was measured by varying the delay time of the ion repelling pulse with respect to the laser irradiation, which provides significant information on the ablated plume characterization. The TOF distributions of ablated ions showed a bimodal shape and could be fitted by shifted Maxwell-Boltzmann distributions. The velocity of the fast component increases with the delay time, whereas the slow component (< 500 m/s) exhibits a constant velocity. Also studied were the effects of the laser fluence on the energetics of C$^{+}$ ions.

• Journal of the Korean Chemical Society
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• v.68 no.2
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• pp.87-92
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• 2024

The commercialization of rechargeable metal-air batteries is extremely desirable but designing stable oxygen reduction reaction (ORR) catalysts with non-noble metal still has faced challenges to replace platinum-based catalysts. The nonnoble metal catalysts for ORR were prepared to improve the catalytic performance and stability by the thermal decomposition of ZIF-8 with optimum cobalt loading. The porous carbon was obtained by the calcination of ZIF-8 and different loading amounts of Co nanoparticles were anchored onto porous carbon forming a Co/PC catalyst. Co/PC composite shows a significant increase in the ORR value of current and stability (500 h) due to the good electronic conductive PCN support and optimum cobalt metal loading. The significantly improved catalytic performance is ascribed to the chemical structure, synergistic effects, porous carbon networks, and rich active sites. This method develops a new pathway for a highly active and advantageous catalyst for electrochemical devices.

• Journal of the Korean Geotechnical Society
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• v.27 no.9
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• pp.77-86
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• 2011

The stress condition mainly dominates the thermal conductivity of soils whereas governing factors such as unit weight and porosity suggested by empirical correlations are still valid. The 3D thermal network model enables evaluation of the stress-dependent thermal conductivity of particulate materials generated by discrete element method (DEM). The relationship among dominant factors is analyzed based on the coordination number and porosity determined by stress condition and thermal conductivity of pore fluid. Results show that the variation of thermal conductivity is strongly attributed to the enlargement of inter-particle contact area by loading history and pore fluid conductivity. This study highlights that the anisotropic evolution of thermal conductivity depends on the directional load and that the particle-scale mechanism mainly dictates the heat transfer in soils.

• Computers and Concrete
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• v.20 no.5
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• pp.605-616
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• 2017

Concrete filled steel tubular (CFST) composite girder is a new type of structures for bridge constructions. The existing design codes cannot be used to predict the thermal stress in the CFST truss girder structures under solar radiation. This study is to develop the temperature gradient curves for predicting thermal stress of the structure based on field and laboratory monitoring data. An in-field testing had been carried out on Ganhaizi Bridge for over two months. Thermal couples were installed at the cross section of the CFST truss girder and the continuous data was collected every 30 minutes. A typical temperature gradient mode was then extracted by comparing temperature distributions at different times. To further verify the temperature gradient mode and investigate the evolution of temperature fields, an outdoor experiment was conducted on a 1:8 scale bridge model, which was installed with both thermal couples and strain gauges. The main factors including solar radiation and ambient temperature on the different positions were studied. Laboratory results were consistent with that from the in-field data and temperature gradient curves were obtained from the in-field and laboratory data. The relationship between the strain difference at top and bottom surfaces of the concrete deck and its corresponding temperature change was also obtained and a method based on curve fitting was proposed to predict the thermal strain under elevated temperature. The thermal stress model for CFST composite girder was derived. By the proposed model, the thermal stress was obtained from the temperature gradient curves. The results using the proposed model were agreed well with that by finite element modelling.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.2
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• pp.119-126
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• 2002

The mica/epoxy composite used in generator(rated 22 kV and 500 MW) stator windings was aged at 180$\^{C}$ for up to 1000 hours in air and hydrogen. The degradation mechanism was investigated through the defect of evolution and microstructural analysis by performing SEM(Scanning Electron Microscope). As the thermal aging time increases, the number of voids per unit volume increases at the mica/epoxy interface of generator stator windings. The aged specimens in hydrogen showed retarded generation and growth of voids. Accelerated aging tests were conducted using the combination of thermal and electrical aging in air and hydrogen. The aging was carried out at a combined stress such as thermal aging at 110$\^{C}$, electrical aging at 5.5 kV/mm and frequencies 420 Hz in air, and electrical aging at 5.5 kV/mm and frequencies 420 Hz in hydrogen (pressure 4 kg/㎠). Thermal and electrical aging generates large voids at the mica/epoxy interface in air. Electrical aging in hydrogen also generates small voids, delaminations and cracks in mica tapes.

• Corrosion Science and Technology
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• v.2 no.3
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• pp.155-160
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• 2003

Plasma spraying technique was used to fabricate functionally graded coating (FGC) of NiCrAIY/YSZ 8wt%$Y_2O_3-ZrO_2$ on a Co-base superalloy (HAYNES 188) substrate. Six layers were coated on the substrate for building up compositionally graded architecture. Conventional thermal barrier coating (TBC) of NiCrAIY/SZ with sharp interface was also fabricated. As-coated FGC and TBC samples were exposed at the temperature of $1100^{\circ}C$ for 10, 50, 100 hours in air. Microstructural change of thermally exposed samples was examined. Pores and microcracks were formed in YSZ layer due to evolution of thermal internal stress at high temperature. The amount of pores and microcracks in YSZ layer were increased with increasing exposure time at high temperature. High temperature oxidation of coatings occurred mainly at the NiCrAIY/YSZ interface. In comparison with the case of TBC. the increased area of the NiCrAIY/YSZ interface in FGC is likely to attribute to forming the higher amount of oxides.