• Title/Summary/Keyword: Thermal and mechanical properties

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Mechanical Properties of Radiation-Curing Vinyl Ester Resin (방사선 경화 비닐에스터 수지의 기계적 특성 연구)

  • Shin, Bum-Sik;Jeun, Joon-Pyo;Kim, Hyun Bin;Kang, Phil-Hyun
    • Journal of Radiation Industry
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    • v.4 no.1
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    • pp.19-23
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    • 2010
  • Vinyl ester (VE) resins, introduced in the late 1960s, have made large strides in reinforced plastics applications as adhesive and matrix materials on their appropriate mechanical performance characteristics in the glassy state. Generally, VE resins are a group of dimethacrylate resins based on bisphenol A type epoxy resin. They exhibit easy handling properties as well as good resistance to most chemical agents due to their mechanical and thermal properties. In this study, the effects of curing methods of vinyl ester resins on gel contents, flexural strength and dynamic mechanical properties were investigated. Thermal curing (room temperature, $80^{\circ}C$) and electron beam curing were used to crosslink a VE resin/styrene complex (65/35 wt%) with methyl ethyl ketone peroxide (MEKPO) as a catalyst and an 8 wt% cobalt naphthenate in styrene solution as a accelerator. For the samples, gel contents as well as flexural strength and dynamic mechanical properties were characterized and compared by soxhlet apparatus, universal testing machine (UTM) and dynamic mechanical analysis (DMA). As a result, the electron-cured VE resin was confirmed as a better condition than those for gel contents, flexural strength and dynamic mechanical properties, respectively.

Thermal effects on the mechanical properties of cement mortars reinforced with aramid, glass, basalt and polypropylene fibers

  • Mazloom, Moosa;Mirzamohammadi, Sajjad
    • Advances in materials Research
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    • v.8 no.2
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    • pp.137-154
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    • 2019
  • In this study, thermal effects on the mechanical properties of cement mortars with some types of fibers is investigated. The replaced fibers were made of polypropylene (PP), aramid, glass and basalt. In other words, the main goal of this paper is to study the effects of different fibers on the mechanical properties of cement mortars after subjecting to normal and sub-elevated temperatures. The experimental tests used for investigating these effects were compressive, splitting tensile, and four-point bending tests at 20, 100 and $300^{\circ}C$, respectively. Moreover, the microstructures of the specimens in different temperatures were investigated using scanning electron microscope (SEM). Based on the experimental results, the negative effects of sub-elevated temperatures on four-point bending tests were much more than the others. Moreover, using the fibers with higher melting points could not improve the qualities of the samples in sub-elevated temperatures.

Effects of Nano-silica/Nano-alumina on Mechanical and Physical Properties of Polyurethane Composites and Coatings

  • Swain, Sarojini;Sharma, Ram Avatar;Bhattacharya, Subhendu;Chaudhary, Lokesh
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.1
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    • pp.1-8
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    • 2013
  • The present approach shows the use of nano-silica/nano-alumina in polyurethane (PU) matrix, which lead to significant improvements in the mechanical and thermal properties of the nano-composite. It is observed that with incorporation of 1% of nano-alumina into the PU matrix, there is an improvement in the tensile strength of around 50%, and for nano-silica the improvement is around 41%, at the same concentration. The morphological data shows that above 3% of the nano particles there are agglomerations in the nanocomposite. Again with the absorption of moisture, there is a decrease in the thermal and mechanical properties of the PU resin, but in this research work it is observed that with the incorporation of the nano particles, in the presence of absorbed moisture there is an improvement in mechanical and thermal properties of the composite, over that of the PU matrix.

Investigation of Thermal Stability of Epoxy Composite Reinforced with Multi-Walled Carbon Nanotubes and Micrometer-Sized Silica Particles (다중벽 탄소나노튜브와 마이크로미터 크기 실리카 입자로 강화된 에폭시 복합재료의 열 안정성에 관한 연구)

  • Oh, Ryun;You, Byeong Il;Ahn, Ji Ho;Lee, Gyo Woo
    • Composites Research
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    • v.29 no.5
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    • pp.306-314
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    • 2016
  • In this study, to improve the thermal stabilities of the epoxy composite specimens in addition to the enhanced mechanical properties, those were reinforced with carbon nanotubes and micrometer-sized silica particles. To disperse the filler in matrix relatively simple physical process, specimens were fabricated using shear mixing and sonication. Tensile strength, coefficients of thermal expansion and thermal conductivity of the specimens were measured with varied contents of the two fillers. The mechanical and thermal properties were also discussed, and the experimental results of thermal expansion related to the thermal stability of the specimens were compared with those from several micromechanics models. The hybrid composites specimens incorporating 0.6 wt% of carbon nanotubes and 50 wt% of silica particles showed better mechanical properties than the others with increase in tensile strength up to 11%, with respect to those of the baseline specimens. As the silica contents were increased the thermal expansion was reduced down to 36%, and the thermal stability was improved with the decreased thermal deformation. Thermal conductivity of the epoxy composite specimens incorporating 50 wt% of silica particles was enhanced, which demonstrate improvement of 72%. The mechanical and thermal properties of the hybrid composites specimens incorporating the two fillers were improved simultaneously.

Beryllium oxide utilized in nuclear reactors: Part I: Application history, thermal properties, mechanical properties, corrosion behavior and fabrication methods

  • Ming-dong Hou;Xiang-wen Zhou;Bing Liu
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4393-4411
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    • 2022
  • In recent years, beryllium oxide has been widely utilized in multiple compact nuclear reactors as the neutron moderator, the neutron reflector or the matrix material with dispersed nuclear fuels due to its prominent properties. In the past 70 years, beryllium oxide has been studied extensively, but rarely been systematically organized. This article provides a systematic review of the application history, thermal properties, mechanical properties, corrosion behavior and fabrication methods of beryllium oxide. Data from previous literature are extracted and sorted out, and all of these original data are attached as the supplementary material, so that subsequent researchers can utilize this paper as a database for beryllium oxide research in reactor design or simulation analysis, etc. In addition, this review article also attempts to point out the insufficiency of research on beryllium oxide, and the possible key research areas about beryllium oxide in the future.

Evaluation of Thermal Durability of Thermal Barrier Coating and Change in Mechanical Behavior

  • Lee, Dong Heon;Kang, Nam Kyu;Lee, Kee Sung;Moon, Heung Soo;Kim, Hyung Tae;Kim, Chul
    • Journal of the Korean Ceramic Society
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    • v.54 no.4
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    • pp.314-322
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    • 2017
  • This study investigates changes in the mechanical behavior, such as changes in indentation load-displacement curve, wear resistance and contact fatigue resistance of thermal barrier coatings (TBCs) by thermal cycling test and thermal shock test. Relatively dense and porous TBCs on nickel-based bondcoat/superalloy are prepared; the highest temperature applied during thermal durability test is $1350^{\circ}C$. The results indicate that the porous TBCs have relatively longer lifetime during thermal cycling and thermal shock tests, while denser TBCs have relatively higher wear and contact fatigue resistance. The mechanical behavior is influenced by sintering of the TBCs by exposure to high temperature during tests.

Thermal, Mechanical, and Electrical Properties for EMNC_60 and EMNC_65 (EMNC_60과 EMNC_65에 대한 열적, 기계적, 전기적 특성 연구)

  • Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.895-901
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    • 2012
  • In order to application for high voltage heavy electric equipments, epoxy/microsilica 60 wt%/nano layered silicate composites (EMNC_60) and epoxy/microsilica 65 wt%/nano layered silicate composites (EMNC_65) respectively was synthesized by our electric field dispersion method and the result was obtained completely dispersion state. Thermal properties such as glass transition temperature (Tg) and thermal expansion coefficient, and DMA characteristics were studied, and mechanical properties such as tensile and flexural tests were performed. AC electrical insulation strength was also tested. The study on thermal property, EMNC_65 was better than EMNC_60 and mechanical, electrical properties much improved EMNC_60 compared with EMNC_65.

Thermal Characteristics of Epoxy-Nanocomposites filled Several Types Nano Layered Silicate Particles (나노층상실리케이트가 충진된 에폭시-나노콤포지트의 열적특성 연구)

  • Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.8
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    • pp.749-754
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    • 2008
  • A large number of studies on the various characteristics of epoxy-layered silicate nanocomposites, such as electric and mechanical, morphology have been conducted and contributed to improve their characteristics. However, studies on the effects of its thermal conductivities in the thermal properties are not enough, even though there are some excellent evaluations for its insulation performances. Thermal properties will cause thermal degradation and significantly affect the reliability of these epoxy-layered silicate nanocomposites. In the results of the analysis of epoxy-layered silicate nanocomposites $T_g$ for various types of organoclays (10A, 15A, 20A, 30B, and 93A), it showed an excellent thermal property of 10A. Also, it represented low values in storage modulus and mechanical Tan (Delta) at a high temperature section 140$^{\circ}C$ and excellent thermal properties due to its movement to the high temperature section in the case of the property of 10A in the measurement of DMA elastics and mechanical losses. In the results of the measurement of thermal conductivities, power ultrasonic applications represented a significant increase in thermal conductivities in the case of the applications of power ultrasonic and planetary centrifugal mixers. Based on these results, it is necessary to perform related studies because it can be applied as useful materials for future power facilities applications in mold and impregnate insulation.

Thermal stabilities and dynamic mechanical properties of dielectric materials for thermal imprint lithography (임프린트 공법적용을 위한 절연재료의 열적, 기계적 성질)

  • Cho, Jae-Choon;Ra, Seung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.220-221
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    • 2007
  • Recently, imprint lithography have received significant attention due to an alternative technology for photolithography on high performance microelectronic devices. In this work, we investigated thermal stabilities and dynamic mechanical properties of dielectric materials for thermal imprint lithography. Curing behaviours, thermal stabilities, and dynamic mechanical properties of the dielectric materials cured with various curing agent and spherical filler were studied using dynamic differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), rheometer and universal test machine(UTM).

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Evaluation of Mechanical Properties with Thermal Aging in CF8M/SA508 Welds (CF8M과 SA508 용접재의 열화거동과 기계적특성 평가)

  • 우승완;최영환;권재도
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.12
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    • pp.1968-1973
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    • 2004
  • Structural degradations are often experienced on the components of nuclear power plants in reactor pressure vessels (RPV) and steam generators (SG) when these components are exposed to high temperature and high pressure for a long period of time. Such conditions result in the change of microstructures and of mechanical properties of materials, which requires an evaluation of the safeguards related to structural integrity. In a primary reactor cooling system (RCS), a dissimilar weld zone exists between cast stainless steel (CF8M) in a pipe and low-alloy steel (SA508 cl.3) in a nozzle. Thermal aging is observed in CF8M as the RCS is exposed for a long period of time under the operating temperature between 290 and 33$0^{\circ}C$. Under the same conditions, it is well known that degradation is not observed in low alloy steel. An investigation of the effect of thermal aging on the various mechanical properties of the dissimilar weld zone is required. The purpose of the present investigation is to find the effect of thermal aging on the dissimilar weld zone. The specimens are prepared by an artificially accelerated aging technique maintained for various times at 43$0^{\circ}C$, respectively. Then, The various mechanical test for the dissimilar welds are performed.