• Title/Summary/Keyword: Thermal and electrical degradation

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Electric Properties of Thermal Conductive Silicone Rubber due to Thermally Degradation (열 열화한 열전도성 실리콘 고무의 전기특성)

  • Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.835-840
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    • 2016
  • In this study, the electrostatic capacity and dielectric loss tangent for $20{\mu}m$ thick thermal conductivity silicone rubber which is heated at 80 degrees for 8 hours has been measured at temperature of $30^{\circ}C{\sim}170^{\circ}C$, frequency of 0.1~1 MHz. The results of degradation evaluation by this study are as follows. In low frequency, it found that the electrostatic capacity decreased with increasing temperature. On the other hand, it confirmed that the range of the electrostatic capacity narrowed with increasing frequency. It confirmed that there are the carboxylic acid structure and C-O bonding at range of wave number 1,000cm-1 to 1,300cm-1.

Numerical Analysis on Thermal-Induced Degradation of n-i-p Structure Perovskite Solar Cells Using SCAPS-1D (SCAPS-1D 시뮬레이션을 이용한 n-i-p 구조 페로브스카이트 태양전지의 열적 열화 원인 분석)

  • Kim, Seongtak;Bae, Soohyun;Jeong, Younghun;Han, Dong-Woon;Kim, Donghwan;Mo, Chan Bin
    • Current Photovoltaic Research
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    • v.10 no.1
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    • pp.16-22
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    • 2022
  • The long-term stability of PSCs against visual and UV light, moisture, electrical bias and high temperature is an important issue for commercialization. In particular, since the operation temperature of solar cell can rise above 85℃, a study on thermal stability is required. In this study, the cause of thermal-induced degradation of PSCs was investigated using the SCAPS-1D simulation tool. First, PSCs of TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au structure were exposed to a constant temperature of 85℃ to observe changes in conversion efficiency and quantum efficiency. Because the EQE reduction above 500 nm was remarkable, we simulated PSCs performance as a function of lifetime, doping density of perovskite and spiro-OMeTAD. Consequently, the main cause of thermal-induced degradation is considered to be the change in the perovskite doping concentration and lifetime due to ion migration of perovskite.

Characterisrics of Dissolved Gas Distribution in Oil with Thermal and Electrical Degradation in Oil Imersed Paper Insulation (유침 절연에서 전기적 및 열적 열화에 따른 유중가스분포특성)

  • Sun, Jong-Ho;Yi, Sang-Hwa;Kim, Kwang-Hwa
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.6
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    • pp.136-144
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    • 2004
  • Dissolved gas in oil analysis has been used for fault diagnosis of oil immersed insulation. In this paper to improve the reliability in deciding the degradation causes of the oil immersed insulation, we carried out electrical and thermal degradations for the insulations, and analyzed the characteristics of dissolved gases distribution on each situation. As a result more reliable faults discrimination is possible if we use the interrelation of factors like key gases and gas compositions of hydrocarbon gases and ratios of CO/$CO_2$.

The Analysis of Temperature Distribution Electric incoming Apparatus Using a Infrared Thermal Imaging System (적외선 열화상 카메라를 이용한 수전설비 온도분포해석)

  • Jeong, Seung-Cheon;Lim, Yeung-Bae;Kim, Jong-Seo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1113-1116
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    • 2004
  • This paper presents the method for analyzing surface temperature of Electric incoming Apparatus. For the experiment, the surface temperature of electric power apparatus was measured and analyzed by using a infrared thermal imaging system. Surface Discharges(SD) have very complex characteristics of discharge patterns, therefore it requires the development of precise analysis methods. recently, studies on infrared thermal imaging system are carried out to analyze temperature distribution of power equipments through condition diagnosis and to diagnose the degradation of power equipments. The changes in suface temperature was measured by using the infrared thermal imaging system under hot line condition. The system was set up based on the diagnostic method of the electric incoming apparatus.

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A Study on the Electrical and Mechanical Properties of a Epoxy Powder for Compact Bus Duct (콤팩트 부스덕트용 에폭시분체도료의 전기적.기계적 특성연구)

  • Kim, Sang-Hyun;Choi, Jin-Wook;Kim, Dong-Wook;Kim, Hyun-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.3
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    • pp.210-217
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    • 2009
  • Insulated methods of compact bus duct has been applied a way of coating Epoxy powder. The problem which is caused by degradation during operation is very important in severe environment. Therefore, this study compared and verified many kind of properties ; electrical breakdown by thermal and water aging, v-t characteristic, arc discharge, mechanical properties, bending test and cross cut. Sample D was stable before the $T_g$ to be about $7{\sim}10 %$ decrease in the breakdown test according to temperature change. In case of V-t and arc discharge, it had been kept up suitable characteristic. Also, in case of electrical and mechanical characteristic, both sample D and A have excellent capacity.

Degradation Mechanism of the ZnO-Varistor Fabricated with the content of a 3-Composition Seed grain (3-성분 종입자법으로 제조된 ZnO-Varistor의 열화기구)

  • 장경욱;박춘배;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.97-100
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    • 1992
  • The Degradation mechanism of the ZnO-varistor fabricated with the content of a 3-Composition seed grain is discussed using the method of Thermally Stimulated Current (TSC). The spectra of TSC is measured in the temperature range of -130~270$^{\circ}C$ with a various forming electric fields E$\sub$f/, temperature T$\sub$f/ time tf, and a various rising rate of temperature. It is observed that there are appeared the peaks of ${\alpha}$, ${\alpha}$$_2$, ${\beta}$ and ${\gamma}$from high temperature in a TSC spectrum. It seems that ${\alpha}$$_1$ peak is due to thermal depolarization of donor ions forming the space charge in the depletion layer, and ${\alpha}$$_2$peak is due to the detrapping of trapped electrons in deep trap level of intergranular layer, and ${\beta}$ peak is due to the thermal exciting of carrier existing in the donor level of grain itself, and ${\gamma}$ peak is due to the thermal exciting of trapped carrier in all shallow trap site randomly distributed in the inner of sample and/or a intrinsic impurity existing in it.

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Thermal Properties of Semiconducting Materials for Power Cable by Carbon Nanotube Content (CNT 함량에 따른 전력케이블용 반도전층 재료의 열적 특성)

  • Yang, Jong-Seok;Lee, Kyoung-Yong;Shin, Dong-Hoon;Park, Bae-Hee
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.12
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    • pp.570-575
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    • 2006
  • In this paper, we have investigated thermal properties by changing the content of carbon nanotube, which is component part of semiconductive shield in underground power transmission cable. Heat capacity (${\Delta}H$), glass transition temperature (Tg) and melting temperature (Tm) were measured with the samples of eight, through DSC (Differential Scanning Calorimetry), and the measurement ranges of temperature selected from $-100[^{\circ}C]\;to\;100[^{\circ}C]$ with heating temperature selected per $4[^{\circ}C/min]$ Also, high temperature, heat degradation initiation temperature, and heat weight loss were measured by TGA (Thermogravimetric Analysis) in the temperature from $0[^{\circ}C]\;to\;700[^{\circ}C]$ with rising temperature of $10[^{\circ}C/min]$. As a result, the Glass transition temperatures of the sample were showed near $-20[^{\circ}C]{\sim}25[^{\circ}C]$, and the heat capacity and melting temperature from the DSC was increased according to increasing the content of carbon nanotube, while, thermal diffusivity was increased according to increasing the content of carbon nanotube. Also, heat degradation initiation temperature from the TGA results was increasing according to increasing the content of carbon nanotube with CNT/EEA. Therefore, heat stabilities of EVA, which contained the we VA (vinyl acetate), showed the lowest.

N-type Silicon Solar Cell Based on Passivation Layer Grown by Rapid Thermal Oxidation (Rapid Thermal Oxidation 기반의 표면 보호막을 이용한 n-type 실리콘 태양전지의 제작과 전기적 특성 분석)

  • Ryu, Kyungsun;Kim, Sung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.1
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    • pp.18-21
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    • 2013
  • $SiO_2$ layer grown by rapid thermal oxidation and $SiN_x$ layer were used for passivating the surface of n-type silicon solar cell, instead of only $SiN_x$ layer generally used in photovoltaic industry. The rapid thermal oxidation provides the reduction of processing time and avoids bulk life time degradation during the processing. Improvement of 30 mV in Voc and $2.7mA/cm^2$ in Jsc was obtained by applying these two layers. This improvement led to fabrication of a large area ($239cm^2$) n-type solar cell with 17.34% efficiency. Internal quantum efficiency measurement indicates that the improvement comes from the front side passivation, but not the rear side, by using $SiO_2/SiN_x$ stack.

Radiation Effects on ${\gamma}$-Ray Irradiated Ethylene Propylene Rubber using Dielectric Analysis

  • Kim, Ki-Yup;Ryu, Boo-Hyung;Lee, Chung;Lim, Kee-Joe
    • KIEE International Transactions on Electrophysics and Applications
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    • v.3C no.2
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    • pp.48-54
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    • 2003
  • To evaluate the radiation degradation of ethylene propylene rubber (EPR), radiation effects on EPR were investigated by using dielectric analysis and thermal-gravimetric analysis. Permittivity, loss factor, tan$\delta$, and thermal decomposition temperature were observed for ${\gamma}$-ray irradiated EPR. As the radiation dose was increased, the peak temperature of the loss factor and tans of EPR were increased and loss factor and tan$\delta$ at peak temperature were decreased. Activation energies were calculated using loss factor and thermal decomposition for ${\gamma}$-ray irradiated EPR as well. The trends of both calculated activation energies showed the same tendencies as radiation dose was increased.

Thermal Characteristics of Epoxy-Nanocomposites filled Several Types Nano Layered Silicate Particles (나노층상실리케이트가 충진된 에폭시-나노콤포지트의 열적특성 연구)

  • Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.8
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    • pp.749-754
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    • 2008
  • A large number of studies on the various characteristics of epoxy-layered silicate nanocomposites, such as electric and mechanical, morphology have been conducted and contributed to improve their characteristics. However, studies on the effects of its thermal conductivities in the thermal properties are not enough, even though there are some excellent evaluations for its insulation performances. Thermal properties will cause thermal degradation and significantly affect the reliability of these epoxy-layered silicate nanocomposites. In the results of the analysis of epoxy-layered silicate nanocomposites $T_g$ for various types of organoclays (10A, 15A, 20A, 30B, and 93A), it showed an excellent thermal property of 10A. Also, it represented low values in storage modulus and mechanical Tan (Delta) at a high temperature section 140$^{\circ}C$ and excellent thermal properties due to its movement to the high temperature section in the case of the property of 10A in the measurement of DMA elastics and mechanical losses. In the results of the measurement of thermal conductivities, power ultrasonic applications represented a significant increase in thermal conductivities in the case of the applications of power ultrasonic and planetary centrifugal mixers. Based on these results, it is necessary to perform related studies because it can be applied as useful materials for future power facilities applications in mold and impregnate insulation.