• Title/Summary/Keyword: Thermal analysis characteristics

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Preparation of PVdF/Fe3O4-GO (MGO) Composite Membrane by Using Electrospinning Technology and its Arsenic Removal Characteristics (전기방사법을 이용한 PVdF/Fe3O4-GO(MGO) 복합 분리막 제조 및 비소 제거 특성평가)

  • Jang, Wongi;Hou, Jian;Byun, Hongsik;Lee, Jae Yong
    • Membrane Journal
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    • v.26 no.6
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    • pp.480-489
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    • 2016
  • In this study, the PVdF/MGO composite nanofiber membranes (PMGs) introducing Iron oxide-Graphene oxide ($Fe_3O_4/GO$, Metallic graphene oxide; MGO) was prepared via electrospinng method and its arsenic removal characteristics were investigated. The thermal treatment was carried out to improve the mechanical strength of nanofiber membranes and then the results showed that of outstanding improvement effect. However, in case of PMGs, the decreasing tendency of mechanical strength was indicated as increasing MGO contents. From the results of pore-size analysis, it was confirmed that the porous structured membranes with 0.3 to $0.45{\mu}m$ were prepared. For the water treatment application, the water flux measurement was carried out. In particular, PMG2.0 sample showed about 70% improved water flux results ($153kg/m^2h$) compared to that of pure PVdF nanofiber membrane ($91kg/m^2h$) under the 0.3 bar condition. In addition, the PMGs have indicated the high removal rates of both As(III) and As(V) (up to 81% and 68%, respectively). Based on the adsorption isotherm analysis, the adsorption of As(III) and As(V) ions were both more suitable for the Freundlich. From all of results, it was concluded that PVdF/MGO composite nanofiber membranes could be utilized as a water treatment membrane and for the Arsenic removal applications.

Conceptual Design of a Riser for 10 MW OTEC (10MW급 해양온도차발전을 위한 라이저 개념설계)

  • Jung, Dongho;Kwon, Yongju;Kim, Hyeonju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.1
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    • pp.29-35
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    • 2015
  • The concept design of a riser for Ocean Thermal Energy Conversion in 10 MW is proposed and its dynamic behaviour characteristics is analyzed with numerical method. A riser pipe with a hollow along its thickness in the cross-section to increase the effective modulus of its cross-section is designed considering the manufacture. The riser pipe without hollows along its thickness needs a lumped weight at the bottom end of a riser in order to keep its vertical hanging configuration from large buoyancy and the strong current. The riser is designed to control its density by inserting materials in high or low density into a hollow. The dynamic behaviour characteristics of the two designed risers is evaluated with the developed numerical analysis tool. The combined stress of the riser with a lumped weight is showed to be dominated by weight of a lumped mass. The riser with no hollow shows large combined stress near sea surface by strong current. Local structural analysis for the cross-section of a hollow riser is needed in detail.

A Study on the Characteristics of Coffee Ground(CG)-RDF by Using Different Drying Method (건조법에 따른 커피박 고형연료의 특성 고찰 연구)

  • Kim, Sang-bin;Ha, Jin-wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.451-457
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    • 2019
  • In this study, the characteristics of coffee grounds were reviewed by making them from solid fuel through heat-drying and oil-drying method. The differences in the higher calorific power by each dried sample were compared. And industrial analysis using the thermogravimetric analyzer was considered for applicability to organic waste and oily samples. Before and after drying, the surface of the specimen was observed with SEM equipment and the ingredients were measured through the EDS equipment. As a result, no other hazardous substances, such as heavy metals, were measured. Next, The differences between thermal decomposition and combustion reactions were considered through the TG and DTG curves. As a result, it is that the oil-dried coffee grounds is longer to burn than the heat-dried coffee grounds. Finally, the combustion gases emitted through the thermogravimetric analyzer were collected and the carbon monoxide and carbon dioxide performed qualitative and quantitative analysis using GC over time.

Preparation and Properties of Polyurethanes Containing Polycarbonate Polyol/Bio Polyol for Wet Type Artificial Leather (폴리카보네이트 폴리올/바이오 폴리올을 이용한 습식 인조피혁용 폴리우레탄의 제조 및 물성)

  • Sur, Suk-Hun;Ko, Jae-Wang;Choi, Pil-Jun;Lee, Jae-Yeon;Lee, Young-Hee;Kim, Han-Do
    • Clean Technology
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    • v.25 no.2
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    • pp.114-122
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    • 2019
  • The synthesis of bio polyol from renewable resources has attracted attention in recent years. In particular, it is important to take advantage of bio polyols in the synthesis of polymers. In this study, a series of dimethylformamide (DMF) based polyurethanes were synthesized using polycarbonate polyol/bio polyol (PO3G: polytrimethylene ether glycol prepared from 1, 3-propanediol produced by fermentation from corn sugar), methylene diphenyl diisocyanate (MDI) and 1,4-butandiol (BD). The properties of prepared polyurethane films and the cell structure of wet type artificial leather were investigated. As the bio polyol content increased, the tensile strength of polyurethane films decreased, however, the elongation at break increased significantly. As a result of thermal characteristics analysis, the glass transition temperature of polyurethanes increased when increasing the content of polycarbonate polyol. As a result of comparing the cell characteristics of wet type artificial leathers prepared in this study, it was found that the number and uniformity of cells formed in the artificial leather samples increased when increasing the content of polycarbonate polyol in polycarbonate polyol/bio polyol. From these results, it was found that DMF-based polyurethane containing an appropriate amount of bio polyol could be used for wet type artificial leather. The bio textile analysis system according to ASTM standard was used to measure the bio carbon content of polyurethane. The content of bio carbon increased proportionally with the increase of bio polyol content used in polyurethane synthesis.

Effects of acute heat stress on salivary metabolites in growing pigs: an analysis using nuclear magnetic resonance-based metabolomics profiling

  • Kim, Byeonghyeon;Kim, Hye Ran;Kim, Ki Hyun;Ji, Sang Yun;Kim, Minji;Lee, Yookyung;Lee, Sung Dae;Jeong, Jin Young
    • Journal of Animal Science and Technology
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    • v.63 no.2
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    • pp.319-331
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    • 2021
  • Heat stress (HS) causes adverse impacts on pig production and health. A potential biomarker of HS is required to predict its occurrence and thereby better manage pigs under HS. Information about the saliva metabolome in heat-stressed pigs is limited. Therefore, this study was aimed to investigate the effects of acute HS on the saliva metabolome and identify metabolites that could be used as potential biomarkers. Growing pigs (n = 6, 3 boars, and 3 gilts) were raised in a thermal neutral (TN; 25℃) environment for a 5-d adaptation period (CON). After adaptation, the pigs were first exposed to HS (30℃; HS30) and then exposed to higher HS (33℃; HS33) for 24 h. Saliva was collected after adaptation, first HS, and second HS, respectively, for metabolomic analysis using 1H-nuclear magnetic resonance spectroscopy. Four metabolites had significantly variable importance in the projection (VIP > 1; p < 0.05) different levels in TN compared to HS groups from all genders (boars and gilts). However, sex-specific characteristics affected metabolites (glutamate and leucine) by showing the opposite results, indicating that HS was less severe in females than in males. A decrease in creatine levels in males and an increase in creatine phosphate levels in females would have contributed to a protective effect from protein degradation by muscle damage. The results showed that HS led to an alteration in metabolites related to energy and protein. Protection from muscle damage may be attributed to the alteration in protein-related metabolites. However, energy-related metabolites showed opposing results according to sex-specific characteristics, such as sex hormone levels and subcutaneous fat layer. This study had shown that saliva samples could be used as a noninvasive method to evaluate heat-stressed pigs. And the results in this study could be contributed to the development of a diagnostic tool as a noninvasive biomarker for managing heat-stressed pigs.

Time-series Analysis of Pyroclastic Flow Deposit and Surface Temperature at Merapi Volcano in Indonesia Using Landsat TM and ETM+ (Landsat TM과 ETM+를 이용한 인도네시아 메라피 화산의 화산쇄설물 분포와 지표 온도 시계열 분석)

  • Cho, Minji;Lu, Zhong;Lee, Chang-Wook
    • Korean Journal of Remote Sensing
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    • v.29 no.5
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    • pp.443-459
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    • 2013
  • Located on Java subduction zone, Merapi volcano is an active stratovolcano with a volcanic activity cycle of 1-5 years. Merapi's eruptions were relatively small with VEI 1-3. However, the most recent eruption occurred in 2010 was quite violent with VEI 4 and 386 people were killed. In this study, we have attempted to study the characteristics of Merapi's eruptions during 18 years using optical Landsat images. We have collected a total of 55 Landsat images acquired from July 6, 1994 to September 1, 2012 to identify pyroclastic flows and their temporal changes from false color images. To extract areal extents of pyroclastic flows, we have performed supervised classification after atmospheric correction by using COST model. As a result, the extracted dimensions of pyroclastic flows are nearly identical to the CVP monthly reports. We have converted the thermal band of Landsat TM and ETM+ to the surface temperature using NASA empirical formula and calculated time-series of the mean surface temperature in the area of peak temperature surrounding the crater. The mean surface temperature around the crater repeatedly showed the tendency to rapidly rise before eruptions and cool down after eruptions. Although Landsat satellite images had some limitations due to weather conditions, these images were useful tool to observe the precursor changes in surface temperature before eruptions and map the pyroclastic flow deposits after eruptions at Merapi volcano.

Electrical Characterization of Ultrathin $SiO_2$ Films Grown by Thermal Oxidation in $N_2O$ Ambient ($N_2O$ 분위기에서 열산화법으로 성장시킨 $SiO_2$초박막의 전기적 특성)

  • Gang, Seok-Bong;Kim, Seon-U;Byeon, Jeong-Su;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.63-74
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    • 1994
  • The ultrathin oxide films less than 100$\AA$ were grown by thermal oxidation in $N_2O$ ambient to improve the controllability of thickness, thickness uniformity, process reproducibility and their electrical properties. Oxidation rate was reduced significantly at very thin region due to the formation of oxynitride layer in $N_2O$ ambient and moreover nitridation of the oxide layer was simultaneously accompanied during growth. The nitrogen incorporation in the grown oxide layer was characterized with the wet chemical etch-rate and ESCA analysis of the grown oxide layer. All the oxides thin films grown in $N_2O$, pure and dilute $O_2$ ambients show Fowler-Nordheim electrical conduction. The electrical characteristics of thin oxide films grown in $N_2O$ such as leakage current, electrical breakdown, interface trap density generation due to the injected electron and reliability were better than those in pure or dilute ambient. These improved properties can be explained by the fact that the weak Si-0 bond is reduced by stress relaxation during oxidation and replacement by strong Si-N bond, and thus the trap sites are reduced.

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Analysis on Temperature Distribution and Current-Carrying Capacity of GIL Filled with Fluoronitriles-CO2 Gas Mixture

  • Chen, Geng;Tu, Youping;Wang, Cong;Cheng, Yi;Jiang, Han;Zhou, Hongyang;Jin, Hua
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2402-2411
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    • 2018
  • Fluoronitriles-$CO_2$ gas mixtures are promising alternatives to $SF_6$ in environmentally-friendly gas-insulated transmission lines (GILs). Insulating gas heat transfer characteristics are of major significance for the current-carrying capacity design and operational state monitoring of GILs. In this paper, a three-dimensional calculation model was established for a GIL using the thermal-fluid coupled finite element method. The calculated results showed close agreement with experimentally measured data. The temperature distribution of a GIL filled with the Fluoronitriles-$CO_2$ mixture was obtained and compared with those of GILs filled with $CO_2$ and $SF_6$. Furthermore, the effects of the mixture ratio of the component gases and the gas pressure on the temperature rise and current-carrying capacity of the GIL were analyzed. Results indicated that the heat transfer performance of the Fluoronitriles-$CO_2$ gas mixture was better than that of $CO_2$ but worse than that of $SF_6$. When compared with $SF_6$, use of the Fluoronitriles-$CO_2$ gas mixture caused a reduction in the GIL's current-carrying capacity. In addition, increasing the Fluoronitriles gas component ratio or increasing the pressure of the insulating gas mixture could improve the heat dissipation and current-carrying capacity of the GIL. These research results can be used to design environmentally-friendly GILs containing Fluoronitriles-$CO_2$ gas mixtures.

Autohesion Behavior of Brominated-Isobutylene-Isoprene Gum Nanocomposites with Layered Clay (층상점토 충전 브롬화 이소부틸-이소프렌 검 나노복합체의 점착거동)

  • Mensah, Bismark;Kim, Sungjin;Lee, Dae Hak;Kim, Han Gil;Oh, Jong Gab;Nah, Changwoon
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.43-52
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    • 2014
  • The effect of nanoclay (Cloisite 20A) on the self-adhesion behavior of uncured brominated-isobutylene-isoprene rubber (BIIR) has been studied. The dispersion state of nanoclay into the rubber matrix was examined by SEM, TEM and XRD analysis. The thermal degradation behavior of the filled and unfilled samples was examined by TGA and improvement in the thermal stability of the nanocomposites occurred based on the weight loss (%) measurements. Also, addition of nanoclay enhanced the cohesive strength of the material by reinforcement action thereby reducing the degree of molecular diffusion across the interface of butyl rubber. However, the average depth of penetration of the inter-diffused chains was still adequate to form entanglement on either side of the interface, and thus offered greater resistance to peeling, resulting in high tack strength measurements. The improvement in tack strength was only achieved at critical nanoclay loading above 8 phr. Contact angle measurement was also made to examine the surface characteristics. There was no significant interfacial property change by employing the nanoclay.

Observational Study of Thermal Characteristics by Distribution Ratio of Green Area at Urban in Summer Season (하절기 관측을 통한 도시의 지역별 공간녹지분포율에 따른 열환경 특성 연구)

  • Jung, Im-Soo;Choi, Dong-Ho;Lee, Bu-Yong
    • Journal of the Korean Solar Energy Society
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    • v.31 no.3
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    • pp.8-16
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    • 2011
  • The objective of this study is to analyze the characteristic of thermal environment in the summer season by conducting the field observation of temperature, relative humidity, and globe temperature in some parts of the city. Observation point was divided to a densely populated area, a residential area, a green area, a waterfront green area and a suburban district by the distribution ratio of green area. In this study, the correlation between maximum temperature and globe temperature, study on index for intensity of the tropical night and the temperature distribution characteristic of measurement points by the distribution ratio of green area were analyzed. The results of this study are as follows. (1) The difference between temperature and globe temperature by the distribution ratio of green area is confirmed. The difference of nighttime is more clearly that of daytime. (2) The average temperature and globe temperature of the densely populated area($29.2^{\circ}C$, $33.7^{\circ}C$) are higher than that of the waterfront green area($27.9^{\circ}C$, $32.0^{\circ}C$) by $1.3^{\circ}C$ and $1.7^{\circ}C$, respectively. (3) The number of tropical nights has different days of tropical nights by the distribution ratio of green area of 17days for the Daegu weather station, 14days for adensely populated area, 14days for a residential area, 6days for a green area, 2days for a waterfront green area, and 2days for a suburban district. (4) The results of the slope of trend line for the effects of the temperature on globe temperature change and the intercept for the size of the impact of radiant energy gained around by the analysis of the correlation between the maximum temperature and globe temperature can be utilized objective evaluation index of the each point's artificial effects.