• Title/Summary/Keyword: Thermal Treatment

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Effect of carbonization temperature and chemical pre-treatment on the thermal change and fiber morphology of kenaf-based carbon fibers

  • Kim, Jin-Myung;Song, In-Seong;Cho, Dong-Hwan;Hong, Ik-Pyo
    • Carbon letters
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    • v.12 no.3
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    • pp.131-137
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    • 2011
  • Kenaf fibers, cellulose-based natural fibers, were used as precursor for preparing kenafbased carbon fibers. The effects of carbonization temperature ($700^{\circ}C$ to $1100^{\circ}C$) and chemical pre-treatment (NaOH and $NH_4Cl$) at various concentrations on the thermal change, chemical composition and fiber morphology of kenaf-based carbon fibers were investigated. Remarkable weight loss and longitudinal shrinkage were found to occur during the thermal conversion from kenaf precursor to kenaf-based carbon fiber, depending on the carbonization temperature. It was noted that the alkali pre-treatment of kenaf with NaOH played a role in reducing the weight loss and the longitudinal shrinkage and also in increasing the carbon content of kenaf-based carbon fibers. The number and size of the cells and the fiber diameter were reduced with increasing carbonization temperature. Morphological observations implied that the micrometer-sized cells were combined or fused and then re-organized with the neighboring cells during the carbonization process. By the pre-treatment of kenaf with 10 and 15 wt% NaOH solutions and the subsequent carbonization process, the inner cells completely disappeared through the transverse direction of the kenaf fiber, resulting in the fiber densification. It was noticeable that the alkali pre-treatment of the kenaf fibers prior to carbonization contributed to the forming of kenaf-based carbon fibers.

Heat Treatment Process Design of CrMoSC1 Steel by Prediction of Phase Transformation and Thermal Stress Analysis (상변태 예측 및 열응력 해석에 의한 CrMoSC1 강의 열처리 공정 설계)

  • Choi, B.H.;Kwak, S.Y.;Kim, J.T.;Choi, J.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.4
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    • pp.247-255
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    • 2005
  • Although heat treatment is a process of great technological importance in order to obtain desired mechanical properties such as hardness, the process was required a tedious and expensive experimentation to specify the process parameters. Consequently, the availability of reliable and efficient numerical simulation program would enable easy specification of process parameters to achieve desired microstructure and mechanical properties without defects like crack and distortion. In present work, the developed numerical simulation program could predict distributions of microstructure and thermal stress in steels under different cooling conditions. The computer program is based on the finite difference method for temperature analysis and microstructural changes and the finite element method for thermal stress analysis. Multi-phase decomposition model was used for description of diffusional austenite decompositions in low alloy steels during cooling after austenitization. The model predicts the progress of ferrite, pearlite, and bainite transformations simultaneously during quenching and estimates the amount of martensite also by using Koistinen and Marburger equation. To verify the developed program, the calculated results are compared with experimental ones of casting product. Based on these results, newly designed heat treatment process is proposed and it was proved to be effective for industry.

Endoscopic Laser Irradiation Condition of Urethra in Tubular Structure (관형 요도 조직 대상 내시경적 레이저 조사 조건 연구)

  • Hwarang, Shin;Seonghee, Lim;Yeachan, Lee;Hyun Wook, Kang
    • Journal of Biomedical Engineering Research
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    • v.44 no.1
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    • pp.85-91
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    • 2023
  • Stress urinary incontinence (SUI) occurs when abdominal pressure increases, such as sneezing, exercising, and laughing. Surgical and non-surgical treatments are the common methods of SUI treatment; however, the conventional treatments still require continuous and invasive treatment. Laser have been used to treat SUI, but excessive temperature increase often causes thermal burn on urethra tissue. Therefore, the optimal conditions must be considered to minimize the thermal damage for the laser treatment. The current study investigated the feasibility of the laser irradiation condition for SUI treatment using non-ablative 980 nm laser from a safety perspective through numerical simulations. COMSOL Multiphysics was used to analyze the numerical simulation model. The Pennes bioheat equation with the Beer's law was used to confirm spatio-temporal temperature distributions, and Arrhenius equation defined the thermal damage caused by the laser-induced heat. Ex vivo porcine urethral tissue was tested to validate the extent of both temperature distribution and thermal damage. The temperature distribution was symmetrical and uniformly observed in the urethra tissue. A muscle layer had a higher temperature (28.3 ℃) than mucosal (23.4 ℃) and submucosal layers (25.5 ℃). MT staining revealed no heat-induced collagen and muscle damage. Both control and treated groups showed the equivalent thickness and area of the urethral mucosal layer. Therefore, the proposed numerical simulation can predict the appropriate irradiation condition (20 W for 15 s) for the SUI treatment with minimal temperature-induced tissue.

Incineration Technology of Bone Waste Using Thermal Plasma (열 플라즈마를 이용한 뼈 폐기물 소각 기술)

  • Kim, Woo-Hyung;Kim, Bong-Soo;Han, Sang-Won;Ki, Ho-Beom;Chae, Jae-Ou
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.15-19
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    • 2006
  • The meat consumption produces a lot of bone waste everyday. Dumping bone waste without treatment results into environmental hazards. Conventional treatment by pyrolysis is slow, inefficient and produces hazardous by-products. In the work, an investigation of bone waste incinerated using thermal plasma technology is presented. A high temperature arc plasma torch operated at 33 kW was employed for the experiments. Bone waste was incinerated to remove the infectious organic matter and to vitrify the inorganic matter using plasma torch. Bone waste was reduced its 2/3 weight after the treatment. The process was highly efficient, economical, convenient, and fuel free. This method could be used as an alternative method for disposal of bone waste, small infectious animals, hazardous hospital waste, etc.

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Preparation of Freeze-dried Cefazolin Sodium Bulk Powder with Good Flowability (유동성이 우수한 분체특성을 갖는 세파졸린 나트륨 진공동결건조 분말의 제조)

  • Cho, Jeong-Sik;Jeong, Eun-Ju
    • YAKHAK HOEJI
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    • v.42 no.3
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    • pp.284-289
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    • 1998
  • The effect of reaction condition, solvent addition and thermal treatment on the bulk density, crystallinity and chemical properties of the freeze-dried cefazohn sodium was inves tigated to prepare the cefazolin sodium powder for injection with good flowability. Crystalline cefazolin sodium powder with high untapped-bulk density (about 45%) and low compressibility (about 40%) was obtained by solvent addition to the very highly concentrated cefazohn sodium solution followed by subsequent thermal treatment before freeze-drying. The desirable solvent was low substituted alcohol such as isopropyl alcohol and anhydrous ethanol with the final concentration of about 9%. The pH adjustment and nitrogen gas purging during the reaction did not give significant effect on the chemical properties such as content, color, transmittance and pH of the reconstituted cefazolin sodium aqueous solution.

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Field emission properties of tip-type carbon nanotube emitters with substrate interlayer (기판 삽입층을 갖는 팁 구조 탄소 나노튜브 이미터의 전계방출 특성)

  • Chang, Han-Beet;Kim, Jong-Pil;Kim, Bu-Jong;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1410-1411
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    • 2011
  • Tip-type carbon nanotube(CNT) based electron emitters were fabricated by forming a hafnium(Hf) interlayer between the CNT and the substrate. The CNTs were deposited by using the electrophoretic deposition method and thermally treated. No significant change in the microscopic structure of the CNTs, such as the ratio of length to diameter, was observed after the deposition of Hf interlayer and thermal treatment. As compared with the CNT emitter without the Hf-interlayer and thermal treatment, the CNT emitter with the Hf-interlayer and thermal treatment showed noticeably improved electron-emission properties due to the enhanced adhesion.

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Analysis of Welding Residual Stresses and Heat Treatment used by Finete Element Method (유한요소법을 이용한 용접 잔류응력과 열처리 해석)

  • Lee, Bong-Yeol;Jo, Jong-Rae;Mun, Yeong-Hun
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.334-339
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    • 2003
  • The welding residual stress has on important effect on welding deformation, fatigue fracture, buckling strength, brittle fracture, etc. For the purpose of relaxation of welding residual stress, post welding heat treatment is widely used. In this paper, residual stresses were calculated by two dimensional thermal elasto-plastic analysis using finite element method. Heat transfer analysis are performed by transient analysis. Also structure analysis are carried out by of thermal-mechanical coupled analysis. Numerical analysis are used by ANSYS 5.7.

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A Study on the Prediction of Plate Temperature in Indirectly-Fired Continuous Heat Treatment Furnace (간접 가열방식의 연속식 열처리로내 판(Plate) 온도해석에 관한 연구)

  • Kim Young-Deuk;Kang Deok-Hong;Kim Woo-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.6 s.249
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    • pp.514-522
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    • 2006
  • This study has been performed to predict the transient thermal behavior of the plate in indirectly-fired continuous heat treatment furnace. The temperature profiles in the plate are determined solving the transient one-dimensional heat conduction equations. To verify the validity of the present numerical results, the present results obtained from the transient analysis are compared with those of experiments. Extensive parametric investigations are performed to examine the effects of the emissivities of the plate and refractory, plate thickness and velocity, as well as the gas temperature, on the thermal behavior of the plate.

Structural Characteristics of Regenerated Antheraea pernyi Silk Fibroin Film treated with ethanol (에탄올처리 재생 작잠 견피브로인 필름의 구조 특성)

  • 우순옥;권해용;엄인철;박영환
    • Journal of Sericultural and Entomological Science
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    • v.42 no.2
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    • pp.114-119
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    • 2000
  • Effects of ethanlo treatment on the structural and thermal characteristics of regenerated Antheraea pernyi silk fibroin (RSF) were investigated. Infrared spectroscopy and X-ray diffractometry showed that the conformational transition of RSF might be affected by concentration of ethanol and its treatment time. The structure of RSF was rapidly changed from random coil to $\beta$-sheet conformation when RSF was treated with les than 75% ethanol concentration. However, RSF treated with ethanol(100%) did not show conformational change. Differential scanning calorimetry showed that exotherm at 232$\^{C}$ disappeared and the intensity of endotherm at 228$\^{C}$ decreased with treatment of 75% ethanol. Dynamic thermal analysis showed that loss modulus (E") and tan $\delta$$\_$E/ of RSF treated with aqueous ethanol was broaden and shifted to higher temperature in comparison with those of untreated RSF.

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Field Enhanced Rapid Thermal Process for Low Temperature Poly-Si TFTs Fabrications

  • Kim, Hyoung-June;Shin, Dong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.665-667
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    • 2005
  • VIATRON TECHNOLOGIES has developed FE-RTP system that enables LTPS LCD and AMOLED manufacturers to produce poly-Si films at low cost, high throughput, and high yield. The system employs sequential heat treatment methods using temperature control and rapid thermal processor modules. The temperature control modules provide exceptionally uniform heating and cooling of the glass substrates to within ${\pm}2^a\;C$. The rapid thermal process that combines heating with field induction accelerates the treatment rates. The new FE-RTP system can process $730{\times}920mm$ glass substrates as thin as 0.4 mm. The uniform nature of poly-Si films produced by FE-RTP resulted in AMOLED panels with no laser-Muras. Furthermore, FE-RTP system also showed superior performances in other heat treatment processes involved in poly-Si TFT fabrications, such as dopant activation, gate oxide densification, hydrogenation, and pre-compaction.

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