• Title/Summary/Keyword: Thermal Mass Ratio

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Determination of the Concentration and Isotope Ratio of Uranium in Soil and Water by Thermal Ionization Mass Spectrometry

  • Park, Jong-Ho;Park, Sujin;Song, Kyuseok
    • Mass Spectrometry Letters
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    • v.5 no.1
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    • pp.12-15
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    • 2014
  • Thermal ionization mass spectrometry (TIMS) was used to determine the concentration and isotope ratio of uranium contained in samples of soil and groundwater collected from Korea. Quantification of uranium in ground water samples was performed by isotope dilution mass spectrometry. A series of chemical treatment processes, including chemical separation using extraction chromatography, was applied to the soil samples to extract the uranium. No treatments other than filtration were applied to the groundwater samples. Isotopic analyses by TIMS showed that the isotope ratios of uranium in both the soil and water samples were indistinguishable from those of naturally abundant uranium. The concentration of uranium in the groundwater samples was within the U.S. acceptable standards for drinking water. These results demonstrate the utility of TIMS for monitoring uranium in environmental samples with high analytical reliability.

NATURAL CONVECTION AROUND A HEAT CONDUCTING AND GENERATING SOLID BODY INSIDE A SQUARE ENCLOSURE WITH DIFFERENT THERMAL BOUNDARIES

  • NITHYADEVI, NAGARAJAN;UMADEVI, PERIYASAMY
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.19 no.4
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    • pp.459-479
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    • 2015
  • Two-dimensional steady laminar natural convection around a heat conducting and generating solid body inside a square enclosure with different thermal boundaries is performed. The mathematical model is governed by the coupled equation of mass, momentum and energy. These equations are discretized by finite volume method with power-law scheme and solved numerically by SIMPLE algorithm with under-relaxation technique. Effect of Rayleigh number, temperature difference ratio of solid-fluid, aspect ratio of solid-enclosure and the thermal conductivity ratio of solid-fluid are investigated numerically for Pr = 0.7. The flow and heat transfer aspects are demonstrated in the form of streamlines and isotherms respectively.

A Study on the Performance of Thermal Mass Flowmeter (열량형 질량 유량계의 성능 평가)

  • Choi, Y.M.;Park, K.A.;Yoon, B.H.;Jang, S.;Choi, H.M.;Lee, S.H.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.595-600
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    • 2001
  • Thermal mass flow meter(TMF) and thermal mass flow controller(MFC) were used to measure and to control the mass flow rate of gases. TMF and MFC were designed for specified working pressure and gas. For the case of different working pressure and gases, the flow rate measurement accuracy decreased dramatically. In this study, a TMF and MFC was tested with three different gases and pressure range from 0.2 MPa up to 1.0 MPa. Effect of specific heat causes to increase flow measurement error as much as ratio of specific heat compared with reference gas. Changing of pressure causes to increase flow rate measurement error about -0.2% as the working pressure decreased 0.1 MPa. Response time of MFC was below 3.12 s for the case of increasing of flow rate. But the response time was increased up to 6.92 s for the case of decreasing of flow rate. When the solenoid valve was fully closed, a initial delay time of output of MFC was increased up to 1.36 s.

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The Effects of Pressure and Specific Heat on the Performance of Thermal Mass Flowmeter (열량형 질량유량계에 대한 압력과 비열 영향)

  • Choi, Y. M,;Park, K. A.;Choi, H. M.;Lee, K. S.
    • 유체기계공업학회:학술대회논문집
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    • 1999.12a
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    • pp.109-113
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    • 1999
  • Thermal mass flow meter (TMF) is used measuring the small mass flow rate of gases. Generally, flow rate measuring accuracy of TMF is $\pm2{\%}$ of full scale. TMF is manufactured for specified working pressure and specified working gas by customer. If it were applied for different working pressure and gases, flow rate measurement accuracy decreased dramatically. In this study, a TMF tested with three different gases and pressure range of 0.2 MPa to 1.0 MPa. Effect of specific heat cause to increase flow measurement error as much as ratio of specific heat compare with reference gas. Pressure change cause to increase flowrate measurement deviation about $-0.2{\%}$ as the working pressure decreased 0.1 MPa.

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Comparative Thermodynamic Analysis of Organic Rankine Cycle and Ammonia-Water Rankine Cycle (유기랭킨사이클과 암모니아-물 랭킨사이클의 열역학적 성능의 비교 해석)

  • KIM, KYOUNG HOON;KIM, MAN-HOE
    • Journal of Hydrogen and New Energy
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    • v.27 no.5
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    • pp.597-603
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    • 2016
  • In this paper a comparative thermodynamics analysis is carried out for organic Rankine cycle (ORC) and ammonia-water Rankine cycle (AWRC) utilizing low-grade heat sources. Effects of the working fluid, ammonia concentration, and turbine inlet pressure are systematically investigated on the system performance such as mass flow rate, pressure ratio, turbine-exit volume flow, and net power production as well as the thermal efficiency. Results show that ORC with a proper working fluid shows higher thermal efficiency than AWRC, however, AWRC shows lower mass flow rate of working fluid and lower pressure ratio of expander than ORC.

A Correction Method for the Peak Tailing Backgrounds for Accurate Isotope Ratio Measurements of Uranium in Ultra Trace Levels using Thermal Ionization Mass Spectrometry

  • Park, Jong-Ho;Choi, In-Hee;Park, Su-Jin;Lee, Myung-Ho;Song, Kyu-Seok
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4327-4331
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    • 2011
  • A new method in thermal ionization mass spectrometry (TIMS) was developed to correct peak tailing backgrounds in the isotope ratio measurements of uranium in ultra trace levels for higher accuracy. Two different uranium standard reference materials (U005 and U030) were used to construct databases of signal intensities at mass 234 u and mass 236 u, which correspond to the two uranium minor isotopes, and signal intensity of $^{238}U$. Correlations between peak tailing backgrounds and $^{238}U$ were obtained by least-squares regression on calculated backgrounds at mass 234 u and mass 236 u with respect to the signal intensity of $^{238}U$ followed by separation of the peak tails of the two major isotopes of uranium ($^{235}U$ and $^{238}U$), which enables us to obtain a master equation for peak tailing background correction on all kinds of samples. Verification of the correction method was carried out using U010 and IRMM-040a.

An Experimental Study on Quality Management of Strength in High Strength Mass Concrete Structure Using Thermal Insulation Material (보온재를 사용한 고강도 매스 콘크리트의 품질관리에 관한 연구)

  • Cho, Kyu-Hyun;Back, Min-Soo;Kim, Sung-Sik;Lim, Nam-Gi;Lee, Young-Do
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.2
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    • pp.113-118
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    • 2004
  • This study is a basic experiment on quality management of the compression strength of high strength concrete, aiming. at quality management of high strength mass concrete by giving the temperature hysteresis of the mass test pieces to managerial test pieces. Different from ordinary concrete, high strength concrete generally shows the temperature high rising caused by hydration heat inside the concrete. It is known that, in mass concrete, thermal stress occurs due to the difference in temperature between the inside and the outside, which causes a significant difference in compression strength between structure beams and managerial test pieces. It is also reported that there is a large difference between the compression strength of cylindrical managerial test pieces of standard underwater curing and the strength of structure beam concrete. Thus, this study made concrete test pieces in an optimal mix ratio for each strength level, and also created thermal insulation curing box and managerial test pieces. Then it carried out comparative analysis in relation to core strength and suggested equipment and a technique that can control the strength of high strength concrete mass more conveniently and accurately.

Simplified Technique for 3-Dimensional Core T/H Model in CANDU6 Transient Simulation

  • Lim, J.C.
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.113-116
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    • 1995
  • Simplified approach has been adopted for the prediction of the thermal behavior of CANDU reactor core during power transients. Based on the assumption that the ratio of mass flow rate for each core channel does not vary during the transient, quasy-steady state analysis technique is applied with predicted core inlet boundary conditions(total mass flow rate and specific enthalpy). For restricted transient case, the presented method shows functionally reasonable estimation of core thermal behavior which could be implemented in the fast running reactor simulation program.

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Prediction of thermal stress in concrete structures with various restraints using thermal stress device

  • Cha, Sang Lyul;Lee, Yun;An, Gyeong Hee;Kim, Jin Keun
    • Computers and Concrete
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    • v.17 no.2
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    • pp.173-188
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    • 2016
  • Generally, thermal stress induced by hydration heat causes cracking in mass concrete structures, requiring a thorough control during the construction. The prediction of the thermal stress is currently undertaken by means of numerical analysis despite its lack of reliability due to the properties of concrete varying over time. In this paper, a method for the prediction of thermal stress in concrete structures by adjusting thermal stress measured by a thermal stress device according to the degree of restraint is proposed to improve the prediction accuracy. The ratio of stress in concrete structures to stress under complete restraint is used as the degree of restraint. To consider the history of the degree of restraint, incremental stress is predicted by comparing the degree of restraint and the incremental stress obtained by the thermal stress device. Furthermore, the thermal stresses of wall and foundation predicted by the proposed method are compared to those obtained by numerical analysis. The thermal stresses obtained by the proposed method are similar to those obtained by the analysis for structures with internally as well as externally strong restraint. It is therefore concluded that the prediction of thermal stress for concrete structures with various boundary conditions using the proposed method is suggested to be accurate.

Mechanical Stability Analysis to Determine the Optimum Aspect Ratio of Rock Caverns for Thermal Energy Storage (열에너지 저장용 암반 공동의 최적 종횡비 결정을 위한 역학적 안정성 해석)

  • Park, Dohyun;Ryu, Dongwoo;Choi, Byung-Hee;Sunwoo, Choon;Han, Kong-Chang
    • Tunnel and Underground Space
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    • v.23 no.2
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    • pp.150-159
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    • 2013
  • It is generally well known that the stratification of thermal energy in heat stores can be improved by increasing the aspect ratio (the height-to-width ratio) of the stores. Accordingly, it will be desirable to apply a high aspect ratio so as to demonstrate the good thermal performance of heat stores. However, as the aspect ratio of a store increases, the height of the store become larger compared to its width, which may be unfavorable for the structural stability of the store. Therefore, to determine an optimum aspect ratio of heat stores, a quantitative mechanical stability assessment should be performed in addition to thermal performance evaluations. In the present study, we numerically investigated the mechanical stability of silo-shaped rock caverns for underground thermal energy storage at different aspect ratios. The applied aspect ratios ranged from 1 to 6 and the mechanical stability was examined based on factor of safety using a shear strength reduction method. The results from the present study showed that the factor of safety of rock caverns tended to decrease with the increase in aspect ratio and the stress ratio of the surrounding rock mass was influential to the stability of the caverns. In addition, the numerical results demonstrated that under the same conditions of rock mass properties and aspect ratio, mechanical stability could be improved by the reduction in cavern size (storage volume), which indicates that one can design high-aspect-ratio rock caverns by dividing a single large cavern into multiple small caverns.