• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.168-172
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• 2018

This study first investigates the effect of the choice of cation on three different ionic-liquid-based gel polymer electrolytes (ILPEs) with polyimide membranes. The preparation of three ILPEs based on electrospun membranes of PI and incorporating a room-temperature ionic liquid, 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide complexed with lithium bis(trifluoromethylsulfonyl)imide, is described. ILPE-EMImTFSI has an ionic conductivity as high as $5.3{\times}10^{-3}S\;cm^{-1}$ at $30^{\circ}C$. Furthermore, it shows higher thermal stability and electrochemical oxidation stability compared to the other two ILPEs because of its stronger bonds. These results indicate that polyimide-based ILPE-EMImTFSI is a good candidate for use in high-safety rechargeable lithium metal batteries.

• 한국기계가공학회지
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• 제18권7호
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• pp.97-103
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• 2019

Mn+1AXn (MAX) phases are a family of nano-laminated compounds that possess unique combination of typical ceramic properties and typical metallic properties. As a member of MAX-phase, $Ti_2AlN$ bulk materials are attractive for some high temperature applications. In this study, $Ti_2AlN$ bulk with high density were synthesized by spark plasma sintering method. X-ray diffraction, micro-hardness, electrical and thermal conductivity were measured to compare the effect of material properties both $Ti_2AlN$ bulk samples and a conventional Ti-6Al-4V alloy. A femto-second laser conditions were conducted at a repetition rate of 6 kHz and laser intensity of 50 %, 70% and 90 %, respectively, laser confocal microscope were used to evaluate the width and depth of ablation. Consequently, the laser ablation result of the $Ti_2AlN$ sample than that of the Ti-6Al-4V alloys show a considerably good ablation characteristics due to its higher thermal conductivity regardless of to high densification and high hardness.

• 한국전기전자재료학회논문지
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• 제28권6호
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• pp.390-395
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• 2015

Molded insulation materials are widely used from large electric power transformer apparatus to small electrical machinery and apparatus. In this study, by adding MgO with the average particle of several tens nm and the excellent thermal conductivity into molding material, we improved the problem of insulation breakdown strength decrease according to rising temperature in overload or in bad environmental condition. We confirmed the life evaluation by using the insulation breakdown and inverse involution to investigate the electrical characteristics of nano-composites materials. By using a scanning electron microscope, it is confirmed that MgO power with the average particle size of several tens nm is distributed and the filler particles is uniformly distributed in the cross section of specimens. And it is confirmed that the insulation breakdown strength of Virgin specimens is rapidly decreased at the high temperature area. But it is confirmed that the insulation breakdown strength of specimens added MgO slow decreased by thermal properties in the high temperature area improved by the contribution of the heat radiation of MgO and the suppression of tree. The results of life prediction using inverse involution, it is confirmed that the life of nano-composites is improved by contribution of MgO according to the predicted insulation breakdown strength after 10 years of specimens added 5.0 wt% of MgO is increased about 2.9 times at RT, and 4.9 times at $100^{\circ}C$ than Virgin specimen, respectively.

• 전기화학회지
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• 제19권1호
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• pp.9-13
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• 2016

Electrospun poly(ether sulfone) (PES) membrane impregnated with Nafion (PES-N) have been developed for high-temperature polymer-electrolyte membrane fuel cell (HT-PEMFC). The PES-N obtains highly thermal stability up to $430^{\circ}C$, which is higher than that of the commercial Nafion 212. The PES-N membrane shows a good proton conductivity of about $10^{-2}S\;cm^{-1}$ in a temperature range from $75^{\circ}C$ to $120^{\circ}C$. The membrane-electrode assembly (MEA) with the PES-N membrane exhibits a current density of $1.697A\;cm^{-2}$ at $75^{\circ}C$, and $0.813A\;cm^{-2}$ at $110^{\circ}C$ when the applied voltage is 0.6 V, whereas the MEA with the Nafion 212 membrane shows the current density of $0.647Acm^{-2}$ at $110^{\circ}C$. The results suggest that the PES-N can be a good candidate for a polymer electrolyte membrane of the HT-PEMFC.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.368-371
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• 2006

[ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1306-1308
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• 1998

Diamond like carbon(DLC) thin films possesed not only marvelous material charateristics such as large thermal conductivity, high hardness and being chemically inert, but also possesed negative electron affinity(NEA) properties. The NEA is an extremely desirable property of the material used in microelestronics and vacuum microelestronics device. DLC films were fabricated by pulsed laser deposition(PLD). The effect of the laser energy density and the substrate temperature on the properies of DLC films was investigated. The experiment was accomplished at temperatures in the range of room temperature to $400^{\circ}C$. The laser energy density was in the range of $6 J/cm^2$ to $16 J/cm^2$.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권5호
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• pp.344-348
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• 1999

Diamond like carbon(DLC) thin films possesed not only marvelous material characteristics such as large thermal conductivity, high hardness and being chemically inert, but also possesed negative electron affinity (NEA) properties. The NEA is an extremely desirable property of the material used in microelestronics and vacuum microelestronics device. DLC films were fabricated by pulsed laser deposition(PLD). Theeffect of the laser energy density and the substrate temperature on the properies of DLC films was investigated. The experiment was accomplished at temperatures in the range of room temperature to $600^{\circ}C$. The laser energy density was in the range of 6 $J/cm^2$ to 16 $J/cm^2$.

• 한국조경학회지
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• 제34권1호
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• pp.21-36
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• 2006

This study was undertaken to analyze the effects of pavement thermal properties and water retention characteristics on the surface temperature of the gray permeable cement concrete pavement during the summer. Following is a summary of major results. 1) The hourly surface temperature of pavement could be well predicted with a heat transfer model program that incorporated the input data of major meteorological variables including solar radiation, atmospheric temperature, dew point, wind velocity, cloudiness and the evaporation rate of the pavements predicted by the time domain reflectometry (TDR) method. 2) When the albedo was changed to 0.5 from an arbitrary starting condition of 0.3, holding other variables constant, the peak surface temperature of the pavement dropped by 11.5%. When heat capacity was changed to $2.5\;kJm^{-3}K^{-1}\;from\;1.5\;kJm^{-3}K^{-1}$, surface temperature dropped by 8.0%. When daily evaporation was changed to 1 mm from 2 mm, temperature dropped by 5.7%. When heat conductivity was changed to $2.5\;Wm^{-1}K^{-1}\;from\;1.5\;Wm^{-1}K^{-1}$, the peak surface temperature of the pavement fell by 1.2%. The peak pavement surface temperature under the arbitrary basic condition was $24.46^{\circ}C$ (12 a.m.). 3) It accordingly became evident that the pavement surface temperature can be most effectively lowered by using materials with a high albedo, a high heat capacity or a high evaporation at the pavement surface. The glare situation, however, is intensified by raising of the albedo, moreover if reflected light is absorbed into surrounding physical masses, it is changed into heat. It accordingly became evident that raising the heat capacity and the evaporative capacity may be the moot acceptable measures to improve the thermal characteristics of the pavement. 4) The sensitivity of the surface temperature to major meteorological variables was as follows. When the daily average temperature changed to $0^{\circ}C\;from\;15^{\circ}C$, holding all other variables constant, the peak surface temperature of the pavement decreased by 56.1 %. When the global solar radiation changed to $200\;Wm^{-2}\;from\;600\;Wm^{-2}$, the temperature of the pavement decreased by 23.4%. When the wind velocity changed to $8\;ms^{-1}\;from\;4\;ms^{-1}$, the temperature decreased by 1.4%. When the cloudiness level changed to 1.0 from 0.5, the peak surface temperature decreased by 0.7%. The peak pavement surface temperature under the arbitrary basic conditions was $24.46^{\circ}C$ (12 a.m.)

• 한국세라믹학회지
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• 제36권8호
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• pp.829-834
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• 1999

산화물 첨가에 의한 불투명화 실리카 에어로겔이 졸-겔 초임게 건조법으로 제조 되었으며 그들의 기계적 강도 및 열전도도 특성이 연구되었다. SiO2-10 mol% TiO2와 SiO2-10 mol% Fe2O3 에어로겔의 압축강도는 순수 실리카 에어로겔의 강도(0.025 MPa)에 비해 훨씬 높은 0.11 MPa과 0.047 MPa 정도 이었으며 TiO2에 의한 불투명화 실리카 에어로겔의 열전도도는 $400^{\circ}C$에서 0.0205 W/m · K 정도로 매우 낮은 값이었다. 순수 실리카 에어로겔의 기계적 강도 증진 및 고온 열전도도 증가를 억제하기 위한 불투명화제로는 TiO2가 Fe2O3에 비해 훨씬 효과적임을 알 수 있었다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1203-1204
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• 2006

Cu-$TiB_2$ nanocomposite powders were synthesized by combining high-energy ball-milling of Cu-Ti-B mixtures and subsequent self-propagating high temperature synthesis (SHS). Cu-40wt.%$TiB_2$ powders were produced by SHS reaction and ball-milled. The milled SHS powder was mixed with Cu powders by ball milling to produce Cu-2.5wt.%$TiB_2$ composites. $TiB_2$ particles less than 250nm were formed in the copper matrix after SHS-reaction. The releative density, electrical conductivity and hardness of specimens sintered at $650-750^{\circ}C$ were nearly 98%, 83%IACS and 71HRB, respectively. After heat treatment at 850 to $950^{\circ}C$ for 2 hours under Ar atmosphere, hardness was descedned by 15%. Our Cu-$TiB_2$ composite showed good thermal stability at eleveated temperature.