• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.323-338
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• 2022

Heat generation and temperature of a battery is usually presented by an equation of current. This means that we need to adopt time domain calculation to obtain thermal characteristics of the battery. To avoid the complicated calculations using time domain, 'state of charge (SOC)' can be used as an independent variable. A SOC based calculation method is elucidated through the comparison between the calculated results and experimental results together. Experiments are carried for rapid resistive discharge of a large-capacitive lithium secondary battery to evaluate variations of cell potential, current and temperature. Calculations are performed based on open-circuit cell potential (SOC,T), internal resistance (SOC,T) and entropy (SOC) with specific heat capacity.

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2029-2035
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• 2013

The impact of phosphorous (P)-doping on the electrochemical performance and surface chemistry of soft carbon is investigated by means of galvanostatic cycling and ex situ X-ray photoelectron spectroscopy (XPS). P-doping plays an important role in storing more Li ions and discernibly improves reversible capacity. However, the discharge capacity retention of P-doped soft carbon electrodes deteriorated at $60^{\circ}C$ compared to non-doped soft carbon. This poor capacity retention could be improved by vinylene carbonate (VC) participating in forming a protective interfacial chemistry on soft carbon. In addition, the effect of P-doping on exothermic thermal reactions of lithiated soft carbon with electrolyte solution is discussed on the basis of differential scanning calorimetry (DSC) results.

• 한국잠사곤충학회지
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• 제48권1호
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• pp.1-5
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• 2006

본 연구에서는 뛰어난 물리, 화학적 특성을 가진 CPA에 CSA를 이용하여 $-SO_3H$ group이 도입된 SCPA를 제조하였다. SCPA의 제조과정에서 반응계의 온도가 $10^{\circ}C$ 이상, CSA의 농도가 0.05mol 이상에서는 정상적인 반응이 진행되지 않았다. SCPA의 이온교환 용량에 따라 Tg가 소폭 증가하는 경향을 나타내었다. 치환 반응중 분자간 가교결합이나 주쇄의 분해가 일어났음을 GPC를 통하여 간접적으로 확인 할 수 있었으나, 이들 부 반응에 의한 열적 및 기계적 특성 변화는 거의 없었다.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2259-2264
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• 2009

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

• 설비공학논문집
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• 제24권2호
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• pp.190-195
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• 2012

In this study, as a complementary study of the former study on indoor thermal environment in a tower type apartment house at tropical nights, a field measurement was conducted in winter season. Mainly, characteristics of heat storage and heat emission in apartment structures, in this study, were investigated. As results, indoor air temperature was changed in the range of $22.5^{\circ}C{\pm}1.0^{\circ}C$, and followed not the change of outdoor air temperature but the changed pattern of floor surface temperature. Wall surface temperature was unresponsive to the change of floor surface temperature compared with the change of indoor air temperature because wall structure was composed of concrete which has large heat capacity, and was changed in the range of $22.3^{\circ}C{\pm}0.6^{\circ}C$. Heat was stored continuously into the structures of wall and ceiling through the measurement term. and this means that a large heat capacity of the apartment structure acts as a disadvantage in winter season, too. As a total review of the study with the former study, a large heat capacity of the apartment structure acts against indoor thermal comfort in winter season as well as in summer season.

• 한국의류산업학회지
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• 제11권6호
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• pp.947-952
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• 2009

The purpose of this study is to analyze skin wettedness($w$) used as the rate index of thermal comfort, and to evaluate the wear comfort of outdoorwear. Skin wettedness is widely used to express the degree of thermal comfort. If skin wettedness exceeds a certain threshold, the body feels damp and discomfort. An experiment which consisted of rest(30 min), exercise(30 min) and recovery(20 min) periods was administered in a climate chamber with 10 healthy male participants. Two kinds of outdoorwears made of 100% cotton fabrics (Control) and specially engineered fabrics having feature of quick sweat absorbency and high speed drying fabric (Functional) were evaluated in the experiment. The condition of climate chamber was controlled according to the thermal insulation of 4 kinds of experimental ensembles(E1~E4). Total sweat loss, sweat loss absorbed into clothing and skin temperature were measured. Skin wettedness was calculated from the ratio of evaporative rate to the maximal evaporative capacity. Skin wettedness of 'Functional' was lower than 'Control' in the 3 kinds of ensembles(E1, E2, E4) because the materials of 'Functional' were composed of quick sweat absorbency and high speed drying fabrics, water vapour permeability and waterproof fabrics.

• 한국지반공학회논문집
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• 제19권1호
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• pp.201-207
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• 2003

본 연구에서는 주물공정에서 발생되는 폐주물사를 가공처리한 방식사를 지하 전력구 및 전력선용 보호관로 공사의 되메움재료로 사용하는데에 따른 적합성을 분석하고자 물리적, 화학적, 열저항 특성실험을 실시하고 현재 지하 전력 구공사의 되메움재로 사용하고 있는 강모래와 비교 분석하였다. 분석결과, 방식사는 전력구 되메움재로서 물리적 기준에 적합하며, 화학적으로 유해성이 적은 것으로 판단되나, 허용전류 측면에서는 함수비 변화에 따른 열저항율의 변동폭이 커서 강모래에 비해 불리하게 나타났다. 이는 방식사가 전력선용 보호관로의 되메움재로 사용하기에는 부적합하나, 토양의 열저항과 무관한 콘크리트 Box로 차폐된 전력구에서는 되메움재로 사용할 수 있는 가능성을 보여주는 것이다. 향후, 이러한 측면에서 방식사의 활용성을 높이기 위해서는 열저항율에 대한 저감방안 등이 연구되어야 할 것이다.

• Journal of Information Processing Systems
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• 제14권5호
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• pp.1136-1149
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• 2018

With the increasing of urban electricity demand, making the most use of the power cable carrying capacity has become an important task in power grid system. Contrary to the rated ampacity obtained under extremely conservative conditions, this paper presents the various steady value of cable ampacity by using the changing surrounding parameters under operation, which is based on cable ampacity calculation equation under the IEC-60287 standard. To some degree, the cable ampacity analysis of actual surroundings improves the transmission capacity of cables. This paper reveals the factors that influence cable ampacity such as insulating layer thickness, allowable long-term conductor temperature, the ambient temperature, soil thermal resistance coefficient, and so on, then gives the class of the influence of these parameters on the ampacity, which plays a great role in accurately calculating the real-time ampacity and improving the utilization rate of cable in the complex external environment condition. Furthermore, the transient thermal rating of the cable is analyzed in this paper, and temperature variation of the conductor under different overload conditions is discussed, which provides effective information for the operation and control of the system.

• 대한기계학회논문집B
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• 제31권3호
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• pp.256-263
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• 2007

The purpose of this study is to investigate the cooling performance of heat sinks for an electronic telecommunication system by adequate natural convection. Heat generation rates of electronic components and the temperature distributions of heat sinks and surrounding air are analyzed experimentally and numerically. In order to perform the heat transfer analysis for the thermal design of telecommunication system a program is developed. The program used the graphic user interface environment to determine the arrangement of heat sources, interior fan capacity, and heat sink configuration. The simulation results showed that the heat sinks were able to achieve a cooling capacity of up to 230W at the maximum temperature difference of $19^{\circ}C$. To verify the results from the numerical simulation, an experiment was conducted under the same condition as the numerical simulation, and their results were compared. The design program gave good prediction of the effects of various parameters involved in the design of a heat sinks for an electronic telecommunication system.

• 태양에너지
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• 제17권4호
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• pp.57-66
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• 1997

The performance of gas-fired boilers were experimentally investigated. The heat exchanger used for the experiments consisted of circular tube with longitudinal fins for the gas side and a spiral coil for the water side. The burner was located at the top of the heat exchanger, and the burned gas flowed down to the exit. The experiments carried out for different water flow rates, the heat capacities of the boiler and the number of baffle. The thermal efficiency of the upward flow was higher than that of the downward flow of the water in the heat exchanger. As the boiler capacity increased, the thermal efficiency decreased. As the number of the baffles increase, the thermal efficiency increased and the increasing rate of the efficiency decreased. The gas-side overall heat transfer coefficient was independent of the flow rate of the water. The effect of the number of the baffles on the heat transfer coefficient was greater than that of the boiler capacity.