• Title/Summary/Keyword: Thermal Barrier

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Silicon Carbide Barrier Technology to Enable Flexible OLED Displays

  • Kim, Sang-Jin;Zambov, Ludmil;Weidner, Ken;Shamamian, Vasgen;Cerny, Glenn
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.452-455
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    • 2007
  • This paper provides an overview on the characteristics of a-SiC:H barrier film deposited for flexible display applications. Key characteristics such as high crack resistance, high thermal/hydro stability, excellent adhesion to the polymer substrate, as well as very low permeance has been demonstrated. The excellence of this barrier film has been shown from competitive analysis compared with other barrier coating materials. Finally, flexible Polymer Light Emitting Diode (PLED) test pixels have been fabricated on the barrier coated plastic substrate, demonstrating the viability of the device with lifetime data.

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Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • v.15 no.3
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

Influence of Compressive Stress in TGO Layer on Impedance Spectroscopy from TBC Coatings

  • Kang, To;Zhang, Jianhai;Yuan, Maodan;Song, Sung-Jin;Kim, Hak-Joon;Kim, Yongseok;Seok, Chang Sung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.1
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    • pp.46-53
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    • 2013
  • Impedance spectroscopy is a non-destructive evaluation (NDE) method first proposed and developed for evaluating TGO layers with compressive stress inside thermally degraded plasma-sprayed thermal barrier coatings (PS TBCs). A bode plot (phase angle (h) vs. frequency (f)) was used to investigate the TGO layer on electrical responses. In our experimental study, the phase angle of Bode plots is sensitive for detecting TGO layers while applying compressive stress on thermal barrier coatings. It is difficult to detect TGO layers in samples isothermally aged for 100 hrs and 200 hrs without compressive stress, and substantial change of phase was observed these samples with compressive stress. Also, the frequency shift of the phase angle and change of the phase angle are observed in samples isothermally aged for more than 400 hrs.

Effect of the Raw Material and Coating Process Conditions on the Densification of 8 wt% Y2O3-ZrO2 Thermal Barrier Coating by Atmospheric Plasma Spray

  • Oh, Yoon-Suk;Kim, Seong-Won;Lee, Sung-Min;Kim, Hyung-Tae;Kim, Min-Sik;Moon, Heung-Soo
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.628-634
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    • 2016
  • The 8 wt% yttria($Y_2O_3$) stabilized zirconia ($ZrO_2$), 8YSZ, a typical thermal barrier coating (TBC) for turbine systems, was fabricated under different starting powder conditions and coating parameters by atmospheric plasma spray (APS) coating process. Four different starting powders were prepared by conventional spray dry method with different additive and process parameter conditions. As a result, large- and small-size spherical-type particles and Donut-type particles were obtained. Dense structure of 8YSZ coating was produced when small size spherical-type or Donut-type particles were used. On the other hand, 8YSZ coating with a porous structure was formed from large-size spherical-type particles. Furthermore, a segmented coating structure with vertical cracks was observed after post heat treatment on the surface of dense structured coating by argon plasma flame at an appropriate gun distance and power condition.

Improvement in Long-term Stability of Pd Alloy Hydrogen Separation Membranes (팔라듐 합금 수소분리막의 내구성 향상)

  • Kim, Chang-Hyun;Lee, Jun-Hyung;Jo, Sung-Tae;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.48 no.1
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    • pp.11-22
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    • 2015
  • Pd alloy hydrogen membranes for hydrogen purification and separation need thermal stability at high temperature for commercial applications. Intermetallic diffusion between the Pd alloy film and the porous metal support gives rise to serious problems in long-term stability of Pd alloy membranes. Ceramic barriers are widely used to prevent the intermetallic diffusion from the porous metal support. However, these layers result in poor adhesion at the interface between film and barrier because of the fundamentally poor chemical affinity and a large thermal stress. In this study, we developed Pd alloy membranes having a dense microstructure and saturated composition on modified metal supports by advanced DC magnetron sputtering and heat treatment for enhanced thermal stability. Experimental results showed that Pd-Cu and Pd-Ag alloy membranes had considerably enhanced long-term stability owing to stable, dense alloy film microstructure and saturated composition, effective diffusion barrier, and good adhesive interface layer.

Fabrication and Characterization of Ytterbium Silicates for Environmental Barrier Coating Applications (환경차폐코팅용 이터븀 실리케이트의 제조와 물성평가)

  • Choi, Jae-Hyeong;Kim, Seongwon
    • Journal of the Korean institute of surface engineering
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    • v.54 no.6
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    • pp.331-339
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    • 2021
  • Environmental barrier coatings(EBCs) are applied to the SiC/SiC ceramic matrix composites(CMCs) in order to protect CMCs from being corroded with water vapor by combustion gas in gas turbine engines. Ytterbium silicates, such as ytterbium monosilicate and ytterbium disilicate, are ones of the candidate materials for EBCs due to their excellent resistance to water vapor corrosion as well as thermal-expansion match with SiC. In this study, ytterbium silicates are fabricated with 2-step solid-state synthesis targeting ytterbium disilicate. After synthesizing ytterbium monosilicate, the mixtures of ytterbium monosilicate and SiO2 are heat-treated and densified by using pressureless sintering or hot pressing with a variety of heating conditions. The phase formation, thermal expansion, and oxidation behavior are examined with fabricated specimens. The final densified bodies are found to be composites between ytterbium monosilicate and ytterbium disilicate with different ratios, which results in 4.43 to 6.72×10-6/K range of coefficients of thermal expansion. The probability of these ytterbium silicates for EBC applications is also discussed.

Magnetic Resonance-Guided Focused Ultrasound : Current Status and Future Perspectives in Thermal Ablation and Blood-Brain Barrier Opening

  • Lee, Eun Jung;Fomenko, Anton;Lozano, Andres M.
    • Journal of Korean Neurosurgical Society
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    • v.62 no.1
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    • pp.10-26
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    • 2019
  • Magnetic resonance-guided focused ultrasound (MRgFUS) is an emerging new technology with considerable potential to treat various neurological diseases. With refinement of ultrasound transducer technology and integration with magnetic resonance imaging guidance, transcranial sonication of precise cerebral targets has become a therapeutic option. Intensity is a key determinant of ultrasound effects. High-intensity focused ultrasound can produce targeted lesions via thermal ablation of tissue. MRgFUS-mediated stereotactic ablation is non-invasive, incision-free, and confers immediate therapeutic effects. Since the US Food and Drug Administration approval of MRgFUS in 2016 for unilateral thalamotomy in medication-refractory essential tremor, studies on novel indications such as Parkinson's disease, psychiatric disease, and brain tumors are underway. MRgFUS is also used in the context of blood-brain barrier (BBB) opening at low intensities, in combination with intravenously-administered microbubbles. Preclinical studies show that MRgFUS-mediated BBB opening safely enhances the delivery of targeted chemotherapeutic agents to the brain and improves tumor control as well as survival. In addition, BBB opening has been shown to activate the innate immune system in animal models of Alzheimer's disease. Amyloid plaque clearance and promotion of neurogenesis in these studies suggest that MRgFUS-mediated BBB opening may be a new paradigm for neurodegenerative disease treatment in the future. Here, we review the current status of preclinical and clinical trials of MRgFUS-mediated thermal ablation and BBB opening, described their mechanisms of action, and discuss future prospects.

Thermo-Structural Survivability Evaluation of a Thrust-Measuring Nozzle Extension in a Full-scale Combustor (실물형 연소기의 추력측정용 노즐확장부에 대한 열/구조적 건전성 평가)

  • Kim, Hong-Jip;Choi, Hwan-Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.6
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    • pp.17-23
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    • 2009
  • The survivability of the temporary nozzle extension for an accurate thrust measurement in a full-scaled combustor has been investigated through thermal analyses. The effects of nozzle extension materials and the thickness of thermal barrier coating (TBC) have been elucidated. It has been found that thermal survivability cannot be guaranteed without TBC. The maximum temperature of the nozzle extension decreased with increasing TBC thickness. For hot firing tests, the TBC is thought to be indispensable to the thermo-structural survivability of the nozzle extension made of steel.

Fabrication and Characteristic of ZrO2-8%Y2O3 Powder for Plasma Spray Coating Manufactured by Mechanical Mixing Method (기계적 혼합에 의한 플라즈마 용사용 ZrO2-Y2O3 분말의 제조 및 특성)

  • Han, Jin-Won;Kwak, Chan-Won;Woo, Kee-Do
    • Korean Journal of Materials Research
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    • v.24 no.7
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    • pp.357-362
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    • 2014
  • Thermal barrier coatings(TBCs) are being applied in many industrial fields such as thermal power generation, aviation and seasonal fields. $ZrO_2-Y_2O_3$(8%) thermal spray coating powders are commercially used as thermal-barrier coating materials to protect against oxidation and corrosion of heat-resistant alloys at elevated temperatures. Currently, $ZrO_2-Y_2O_3$(8%) thermal-spray powder is made using the industrial co-precipitation process, which is very complex and requires a lot of time. In this study, orthorhombic $ZrO_2$ and $Y_2O_3$ powders were fabricated by mechanical mixing, which is more economical than the co-precipitation process. A tetragonal, yttria-stabilized zirconia(YSZ) coating-layer was produced by plasma spraying, using orthorhombic $ZrO_2-Y_2O_3$(8%) powder. Our experimental results indicate that $ZrO_2-Y_2O_3$(8%) mixed powder can be used economically in industry because it is no longer necessary to make this powder by liquid and gas-phase methods.