• Title/Summary/Keyword: Thermal Aging

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The Quantitative Evaluation of Aging State of Field Composite Insulators Based on Trap Characteristics and Volume Resistivity-Temperature Characteristics

  • Liang, Ying;Gao, Li-Juan;Dong, Ping-Ping;Gao, Ting
    • Journal of Electrical Engineering and Technology
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    • v.13 no.3
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    • pp.1355-1362
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    • 2018
  • In order to obtain a better understanding of the ageing process of the field composite insulators, it is necessary to explore a quantitative-valuation method for the aging state evaluation. And the linear relationship between volume resistivity and temperature is proposed. In this paper, the composite insulators with different lengths of operating lives from two manufacturers were tested. The relationship between trap characteristics and volume resistivity-temperature characteristics were analyzed based on Thermal Stimulated Current (TSC), volume resistivity-temperature test, Scanning Electron Microscope (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). Furthermore, the application of trap characteristics in the quantitative evaluation of aging state of composite insulators was discussed. The results showed that there was a general negative correlation between the relative variation ratio of trap charges and the volume resistivity-temperature characteristics. Meanwhile, the physicochemical properties would change with the aging time, which would result in the increasing of electron traps. Combined with the TSC and volume resistivity test results, the trap characteristic thresholds which indicated the serious age of the composite insulators had been proposed.

Arrhenius Kinetic Constants Analysis of BKNO3 under Accelerated Aging (가속노화에 따른 BKNO3의 아레니우스 동역학 상수 분석)

  • Jang, Seung-gyo;Kim, Jun-hyung;Ryu, Byung-tae;Hwang, Jung-min
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.4
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    • pp.34-39
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    • 2016
  • Arrhenius kinetic constants, the activation energy and the pre-exponential factor, of energetic material $BKNO_3$ are estimated using Differential Scanning Calorimetry (DSC). Different from the conventional way, the activation energy was estimated more precisely through DSC aging trial, and the consumed fraction by heat was calculated by comparing the integration of heat flow. We suggested the condition of accelerated aging test for the energetic material $BKNO_3$ and reconsidered the meaning of the thermal accelerated aging.

Effect of Strain Aging on Tensile Behavior and Properties of API X60, X70, and X80 Pipeline Steels

  • Lee, Sang-In;Lee, Seung-Yong;Lee, Seok Gyu;Jung, Hwan Gyo;Hwang, Byoungchul
    • Metals and materials international
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    • v.24 no.6
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    • pp.1221-1231
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    • 2018
  • The effect of strain aging on tensile behavior and properties of API X60, X70, and X80 pipeline steels was investigated in this study. The API X60, X70, and X80 pipeline steels were fabricated by varying alloying elements and thermomechanical processing conditions. Although all the steels exhibited complex microstructure consisting of polygonal ferrite (PF), acicular ferrite, granular bainite (GB), bainitic ferrite (BF), and secondary phases, they had different fractions of microstructures depending on the alloying elements and thermomechanical processing conditions. The tensile test results revealed that yielding behavior steadily changed from continuous-type to discontinuous-type as aging temperature increases after 1% pre-strain. After pre-strain and thermal aging treatment in all the steels, the yield and tensile strengths, and yield ratio were increased, while the uniform elongation and work hardening exponent were decreased. In the case of the X80 steel, particularly, the decrease in uniform elongation was relatively small due to many mobile dislocations in PF, and the increase in yield ratio was the lowest because a large amount of harder microstructures such as GB, BF, and coarse secondary phases effectively enhanced work hardening.

Nondestructive Characterization of Degradation of EPDM Rubber for Automotive Radiator Hoses (자동차 냉각기 호스용 EPDM고무의 노화에 대한 비파괴 특성평가)

  • Kwak, Seung-Bum;Choi, Nak-Sam;Choi, Youn-Joung;Shin, Sei-Moon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.5
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    • pp.368-376
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    • 2005
  • Coolant rubber hoses for automobile radiators can be degraded and thus failed due to the influence of contacting stresses of air and coolant liquid under thermal and mechanical loadings. In this study, for EPDM(ethylene-propylene diene monomer) rubber conventionally used as a radiator hose material the aging behaviors of the skin part due to thermo-oxidative and electro-chemical stresses were nondestructively evaluated. Through the thermo-oxidative aging test, it was shown that the surface hardness IRHD(International Rubber Hardness Degrees) of the rubber increased with a considerable reduction of failure strain. On account of the penetration of coolant liquid into the skin part the weight of rubber specimens degraded by electro-chemical degradation(ECD) test increased, whereas their. failure strain and IRHD hardness decreased largely. The penetration of coolant liquid seemed to induce some changes in inner structure and micro hardness distribution of the rubbers. Consequently, EPDM rubbers degraded by thermo-oxidative aging and ECD could be characterized nondestructively by micro-hardness and chemical structure analysis methods.

Aging of Solid Fuels Composed of Zr and ZrNi Part 1: Thermal/Chemical/Spectroscopic Analysis (Zr과 ZrNi로 구성된 고체연료의 노화 연구 Part 1: 열/화학/분광학적 분석)

  • Han, Byungheon;Ryu, Jihoon;Yang, Junho;Oh, Juyoung;Gnanaprakash, K.;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.2
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    • pp.1-13
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    • 2020
  • The characterization of aging of the pyrotechnic device is conducted thermally, chemically, and spectroscopically. The device is comprised of two parts: (i) igniter composed of Zr and (ii) pyrotechnic delay composed of ZrNi alloy. The thermally induced chemical reaction is identified through Differential Scanning Calorimetry (DSC) and Thermogravimetry Analysis (TGA). The peak deconvolution of the themo-chemical data is used to estimate the enthalpy change of each metallic fuel component. Laser Induced Breakdown Spectroscopy (LIBS) and X-ray Photoelectron Spectroscopy (XPS) are used for chemical species analysis. The decomposition of oxidants by moisture significantly affected the fuel aging, and the formation of oxide film and metal oxide on the fuel surface gave rise to the thermal energy decrease.

Influence of the preparation design and artificial aging on the fracture resistance of monolithic zirconia crowns

  • Mitov, Gergo;Anastassova-Yoshida, Yana;Nothdurft, Frank Phillip;See, Constantin von;Pospiech, Peter
    • The Journal of Advanced Prosthodontics
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    • v.8 no.1
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    • pp.30-36
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    • 2016
  • PURPOSE. The aim of this study was to evaluate the fracture resistance and fracture behavior of monolithic zirconia crowns in accordance with the preparation design and aging simulation method. MATERIALS AND METHODS. An upper first molar was prepared sequentially with three different preparation designs: shoulderless preparation, 0.4 mm chamfer and 0.8 mm chamfer preparation. For each preparation design, 30 monolithic zirconia crowns were fabricated. After cementation on Cr-Co alloy dies, the following artificial aging procedures were performed: (1) thermal cycling and mechanical loading (TCML): 5000 cycles of thermal cycling $5^{\circ}C-55^{\circ}C$ and chewing simulation (1,200,000 cycles, 50 N); (2) Low Temperature Degradation simulation (LTD): autoclave treatment at $137^{\circ}C$, 2 bar for 3 hours and chewing simulation; and (3) no pre-treatment (control group). After artificial aging, the crowns were loaded until fracture. RESULTS. The mean values of fracture resistance varied between 3414 N (LTD; 0.8 mm chamfer preparation) and 5712 N (control group; shoulderless preparation). Two-way ANOVA analysis showed a significantly higher fracture loads for the shoulderless preparation, whereas no difference was found between the chamfer preparations. In contrast to TCML, after LTD simulation the fracture strength of monolithic zirconia crowns decreased significantly. CONCLUSION. The monolithic crowns tested in this study showed generally high fracture load values. Preparation design and LTD simulation had a significant influence on the fracture strength of monolithic zirconia crowns.

Study on Change of Thermal Conductivity According to Environmental Conditions (환경 조건에 따른 열전도율 변화에 관한 연구)

  • Seo, Eun-Seok;Kim, Bong-Joo;You, Nam-Gyu;Hong, Sang-Hun;Kim, Han-Nah;Jung, Ui-In
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.66-67
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    • 2019
  • Insulated buildings are exposed to the external environment due to aging and construction problems, resulting in a decrease in building energy efficiency. Therefore, the purpose of this paper is to provide a material for the change in thermal conductivity of the insulation when it is exposed to various external environments. In the experiment, five types of heat insulating materials were selected, stored under different environmental conditions, and the thermal conductivity was measured periodically to confirm the change in thermal conductivity. As a result, the thermal conductivity of all the insulating materials except the PF board increased with the passage of time. This is because thermal insulation absorbs atmospheric moisture under all environmental conditions and the thermal conductivity increases, and in the case of thermal insulation stored indoors in environmental conditions, the temperature differs from the thermal insulation stored outside. It is considered that there is little evaporation of moisture absorbed constantly, and the change in thermal conductivity is large.

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A study on thermal fluid analysis in X-ray tube for non-fire alarm (비화재보를 위한 X-ray tube 내 열 유동해석에 관한 연구)

  • Yun, Dong-Min;Jeon, Yong-Han
    • Design & Manufacturing
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    • v.16 no.2
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    • pp.33-38
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    • 2022
  • Currently, Korea is an aging society, and it is expected to enter a super-aging society in about 4 years. Accordingly, many X-ray technologies are being developed. In X-rays, 99% of X-rays are converted into heat energy and 1% into light energy (X-rays). 99% of the thermal energy raises the temperature of the anode and its surroundings, and the cooling system is an important factor as overheating can affect the deterioration of X-ray quality and shortened lifespan. There is a method of forced air cooling using natural convection. Therefore, in this study, when X-rays were taken 5 times, Flow analysis was performed on heat removal according to temperature rise and cooling time for the heat generated at the anode of the X-ray tube (input power 60kW, 75kW, 90kW). Based on one-shot, the most rapid temperature rise section increased by more than 57% to 0.03 seconds, A constant temperature rises from 0.03 seconds to 0.1 seconds, It is judged that the temperature rises by about 8.2% or more at one time. After one-shot cooling, the cooling drops sharply from about 60% to 0.03 seconds, It is judged that the temperature has cooled by more than 86% compared to the temperature before shooting. One-shot is cooled by more than 86% with cooling time after 0.1 seconds, As the input power of the anode increases, the cooling temperature gradually increases. Since the tungsten of the anode target inside the X-ray tube may be damaged by thermal shock caused by a rapid temperature rise, an improvement method for removing thermal energy is required when using a high-input power supply.

Improvement of stability for organic light emitting devices by thermal and electrical treatment

  • Jung, Jae-Hoon;Lee, Sung-Soo;Choi, Ji-hye;Choi, Joon-Hoo;Chung, Kyu-ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.998-1001
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    • 2006
  • Highly stable organic electroluminescent devices have been achieved by treatment of thermal and electrical annealing. We investigate here the performance of theses devices at temperatures and pulse aging. We also demonstrate improved device stability due to thermal and electrical treatment, and the brightness decays at no treatment, thermal only, electrical only and thermal/electrical treatment were 86.6%, 89.5%, 93.0%, and 96.7%, respectively, in the after 150 h of operation driven with an initial luminance of $1,000\;cd/m^2$.

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The Thermal Stability of Teflon AF/FEP Double Layer Film Electret (Teflon AF/FEP 이중 필름 일렉트렛트의 열적 안정성)

  • 김병수;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.8
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    • pp.693-699
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    • 2003
  • To improve thermal stability of Teflon FEP which is the most widely used materials for electret application, Teflon AF film of 1 $\mu\textrm{m}$ thick was spin coated on FEP film and the charge storage properties were investigated. The surface potential depend on aging temperature. Thermal Stimulated Current(TSC), Atomic Force Microscopy(AFM), and Fourier Transform-Infrared Spectroscope(FT-lR) measurements were carried out. It is shown that the AF/FEP dual film have more higher electrical property and thermal stability than that FEP film have caused by charge stored at interface of AF and FEP.