• Title/Summary/Keyword: Theory of mixtures

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Estimation of Hydraulic Conductivity Using Piezocone Penetration Test (피에조콘 관입 시험을 이용한 투수계수 산정기법 연구)

  • 송정락
    • Journal of the Korean Geotechnical Society
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    • v.17 no.2
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    • pp.31-39
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    • 2001
  • 본 연구에서는 수정 Cam Clay 모델과 혼합체 커플링 이론(coupled theory of mixtures)을 이용하여 피에조콘 관입시험을 해석하여 지반의 투수계수와 과잉간극수압의 정량적 관계를 고찰하였다. 본 연구의 이론적 해석 결과는 시험결과들과 비교하였으며 그 결과 피에조콘 관립 시험시 관측된 과잉간극수압은 지반의 투수계수가 $10^{-9}$m/sec에서 $10^{-6}$m/sec의 범위에서는 투수계수에 따라 피에조콘 관립 시험시 관측된 과잉간극수압이 현저하게 변하는 것으로 나타나 피에조콘 관입시험시 관측한 과잉간극수압을 이용하여 지반의 투수계수를 결정할 수 있음을 알 수 있었다. 또한 지반의 투수계수가 $10^{-9}$m/sec 이하에서는 지반이 거의 완전 비배수 상태에 가까운 거동을 나타내면, 투수계수가 $10^{-6}$m/sec 이상에서는 거의 완전 배수상태에 가까운 거동을 하는 것으로 나타났다.으로 나타났다.

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Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volumes of Isomers of Propanol with Cyclohexane or n-Hexane

  • Gahlyan, Suman;Verma, Sweety;Rani, Manju;Maken, Sanjeev
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.536-541
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    • 2018
  • Excess molar volumes ($V_m^E$) of binary mixtures of 1-propanol or 2-propanol (1) + cyclohexane or n-hexane (2) were measured with V-shaped dilatometer at 303.15 K. The $V_m^E$ data for these mixtures varied as: 2-propanol > 1-propanol and were higher for cyclohexane than n-hexane for both propanol systems. The experimental data were correlated with Redlich-Kister polynomial. The $V_m^E$ data were interpreted qualitatively as well as quantitatively in terms of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory. Both models correctly described the sign and shape of $V_m^E$ vs $x_1$ curves. The values calculated by both the models agree well with the experimental data.

Structural performance of recycled aggregates concrete sourced from low strength concrete

  • Goksu, Caglar;Saribas, Ilyas;Binbir, Ergun;Akkaya, Yilmaz;Ilki, Alper
    • Structural Engineering and Mechanics
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    • v.69 no.1
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    • pp.77-93
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    • 2019
  • Although much research has been carried out using recycled aggregates sourced from normal strength concrete, most of the buildings to be demolished are constructed with low strength concrete. Therefore, the properties of the concrete incorporating recycled aggregates, sourced from the waste of structural elements cast with low strength concrete, were investigated in this study. Four different concrete mixtures were designed incorporating natural and recycled aggregates with and without fly ash. The results of the mechanical and durability tests of the concrete mixtures are presented. Additionally, full-scale one-way reinforced concrete slabs were cast, using these concrete mixtures, and subjected to bending test. The feasibility of using conventional reinforced concrete theory for the slabs made with structural concrete incorporating recycled aggregates was investigated.

불평등 전계에서 $SF_6/N_2$의 초고압 AC전압 절연내력 시뮬레이션

  • Heo, Chang-Su;Lee, Byeong-Taek;Choe, Sun-Ho;Sim, Myeong-Seop;An, Jeong-Sik;Hwang, Cheong-Ho;Jang, Yong-Mu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.37-37
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    • 2010
  • In these days $SF_6$ mixtures and alternative gas has been studied because of global warming. so although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/N_2$ mixtures. In this paper, breakdown experiment values and breakdown simulation value are compared. Streamer theory was used for predicting breakdown voltage. For accurate simulation, this simulation apply utilization factor using CST program. AC breakdown experiments in non-uniform field was performed to compare with the breakdown simulation values. But with gap lengths increasing, the breakdown voltage is saturated. So simulation need surface roughness factor.

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Laboratory Evaluation of Soil Permeability for Sand Using Biot's Acoustic Wave Propagation Theory (Biot 음향 전파 이론을 이용한 실내 사질 시료의 투수계수 산정)

  • Kim, Jin-Won;Song, Chung-Rak
    • Journal of the Korean Geotechnical Society
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    • v.24 no.8
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    • pp.5-12
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    • 2008
  • Biot proposed the frequency dependent formulation for the propagation of elastic waves in saturated media based on the coupled theory mixtures. Based on Biot theory, a special frequency called 'the characteristic frequency' contains unique information of the permeability of soils. The characteristic frequency is measured from I/Q (inverse quality factor) versus frequency curve by an acoustic sweep test, and the permeability of soils is computed from Biot equation. In this paper, laboratory tests are performed at The University of Mississippi using a large test box. The measured characteristic frequency is consistently obtained at 3500 Hz for mortar sands. The computed permeability of mortar sands based on Biot equation turned out 2.01 $10^{-4}m/sec$, while the permeability from the laboratory constant head test turned out 1.49 $10^{-4}m/sec$. This paper addresses the theoretical background and experimental procedure of this technique.

Effect of Radiation on Laminar Film Boiling of Binary Mixtures (2성분 혼합물질의 층류 막비등에서 복사열전달의 효과)

  • Seong Hyeon-Chan;Kim Kyoung-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.10
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    • pp.942-951
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    • 2004
  • This paper presents the results of a theoretical study of the effect of radiation during free convective laminar film boiling for methanol/water binary mixtures on an isothermal vertical wall at atmospheric pressure. With the well-known boundary layer theory as a basis, a theoretical model has been formulated into consideration for mass diffusion at liquid phase. The equations are numerically solved by a similarity method to investigate the effects of radiation emissivity on the surface with various parameters such as wall superheat and composition of more volatile component at liquid phase far from the wall. From the results, the distributions of the physical quantifies are investigated in both phases. New correlations are proposed to predict the heat transfer coefficient of binary mixtures. It is shown that the proposed correlations are in good agreement with numerical results and with Bromley's correlation within maximum $11\%$ errors. It is also found that as the wall superheat is increased, radiation effect becomes more important.

One-fluid Conformal Solution Theory for Lennard-Jones Liquid Mixtures (Lennard-Jones 유체 혼합물의 열역학적 연구)

  • Kwon, Yong Jung
    • Journal of Industrial Technology
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    • v.9
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    • pp.119-125
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    • 1989
  • Lennard-Jones 유체 혹은 거의 구형에 가까운 분자들의 혼합물의 열역학적 성질을 예측하기 위한 용액이론이 유도되었다. 이 이론에는 에너지와 분자직경에 대한 두 개의 변수가 존재하며, 강구(hard sphere)를 중심으로 하여 동경함수(pair distribution function)를 확장시키는 교반이론(perturbation theory)에서 1/kT에 대한 일차와 이차계수의 관계로부터 얻어지는 혼합법칙을 이용하는 HSE이론과 달리 Orstein-Zernike결과와 일치되는 분자직경 변수를 먼저 구한 다음, 일차계수와 함께 얻어진 혼합법칙이 유도되었다. 이 방법으로 위 유체들의 혼합물에 적용시켰을 때, 원래의 HSE나 vdW-1의 방법보다 좋은 결과의 열역학적 성질을 예측할 수 있었다.

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Viscometric Studies of Molecular Interactions in Binary Mixtures of Formamide with Alkanol at 298.15 and 308.15 K

  • Gahlyan, Suman;Verma, Sweety;Rani, Manju;Maken, Sanjeev
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.520-529
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    • 2017
  • Viscosity data were measured at 298.15 K and 308.15 K for formamide + 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol or 2-methyl-2-propanol mixtures. For an equimolar mixture, deviation in viscosity follows the sequence: 2-methyl-2-propanol >2-methyl-1-propanol>1-butanol>2-propanol>1-propanol. The viscosity data were further analyzed in terms of graph theory. Free energy of activation was also calculated from experimental viscosity data along with previously reported excess volume data. The deviation in viscosity and free energy of activation were fitted to Redlich-Kister polynomial equation. The viscosity data were also correlated by correlations like Grunberg-Nissan, Tamura-Kurata, HindMcLaughlin-Ubbelohde, and Katti-Chaudhari relation. Various adjustable parameters, $G_{12}$, $T_{12}$, $H_{12}$, and $W_{vis}/RT$, of various correlations were used to predict viscosity deviation of binary mixtures. Positive value of $G_{12}$ indicates strong interaction in the studied systems. Grunberg-Nissan relation has lowest deviation among the four correlations for formamide + 1-propanol or 2-propanol mixtures; and for mixtures of formamide with 1-butanol or 2-methyl-1-propanol, TamuraKurata has lowest deviation. Grunberg-Nissan gives lowest deviation for formamide + 2-methyl-2-propanol mixtures.

Investigation of Vapor-Liquid Equilibrium and Miscibility for R-410A/POE Oil Mixtures (R-410A/POE 오일 혼합물의 기-액상평형과 상용성에 관한 연구)

  • 김창년;송준석;이은호;박영무;유재석;김기현
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.6
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    • pp.589-598
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    • 2000
  • The vapor-liquid equilibrium and miscibility measurement apparatus was developed and used to obtain data for refrigerant/oil mixture. The vapor-liquid equilibrium and miscibility data for R-410a/POE32 and R-410A/POE46 oil mixtures are obtained over the temperature range from -20 to $60^{\circ}C\;with\;10^{\circ}C$ intervals and the oil concentration range from 0 to 90 wt%. Using the experimental data, an empirical model is developed to predict the temperature-pressure-concentration relations for R-410A/POE oil mixtures at equilibrium. In the R-410A/POE32 oil mixture, the average root-mean-square deviation between measured data and calculated results from the empirical model is 2.00% and in the R-410a/POE46 oil mixture, that is 3.69%. Flory-Huggins theory is also used to predict refrigerant/oil mixture behavior. Miscibility for R-410A/POE32 oil mixture was observed all over the experimental conditions. Immiscibility for R-410A/POE46 oil mixture was observed at the low oil concentrations(10~30 wt%).

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Study of the Partial Miscibilities of Binary Liquid-liquid Systems Predicted by the Extended Flory-Huggins Lattice Theory (확장된 Flory-Huggins의 격자이론에 의해 예측되는 액체 이성분계의 부분혼화도에 대한 고찰)

  • Hae-Young Jung
    • Journal of the Korean Chemical Society
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    • v.31 no.6
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    • pp.481-485
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    • 1987
  • Various partial miscibilities of binary liquid mixtures predicted by the extended Flory-Huggins lattice theory are shown in this article, and the mathematical conditions for each partial miscibility are obtained. And in terms of the theory it is shown that the unusual partial miscibility of water-2-butanol system can occur.

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