• Journal of The Geomorphological Association of Korea
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• v.26 no.1
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• pp.79-91
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• 2019

This study analyzed the distribution of fluvial landforms, fault-related geomorphic features and lineaments around the area of Ungchon-Ungsang in the Dongrae Fault, and discusses the charateristics of geomorphic development based on those. As a result, the NE-SW lineaments are predominantly developed in many numbers within the study area, and the NW-SE or N-S secondary lineaments are developed induced by multiple deformation with the Yangsan Fault. Geomorphologically, the early tectonic history of the Ungchon-Ungsang basin is largely divided into three stages ; 1) the Tertiary fault activity and formation of fracture zone, 2) development of erosional basin, 3) local crustal movements and development of fault-related topography. It is assumed that alluvial fans, deflected channel and stream piracy were formed by local tectonic movements related to faultings during the Quaternary.

• Proceedings of the Membrane Society of Korea Conference
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• 1993.10a
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• pp.58-58
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• 1993

Pervaporation has become important as a method to separate liquid mixtures, sepecially azeotropic and close boiling-point mixtures. Especially, water-alcohol separations have been carried out a lot because of the practical interests in the industries. However, outstanding membranes with high selectivity and high permeability have not been available in common use yet. In order to separate selectively out the water mixed with alcohols with an aim of the purification of the alcohols, a membrane has tO have excellent affinity to water. Among the hydrophilic polymers, polyacrylic acid and poly(vinyl alcohol) are used widely. In recent years, ionomers and polyion complexes, better hydrophitic materials, start to be used. The polyion complex membranes, consisting of polyacrylic acid (PAA) and polycation, showed excellent permeation rates and selectivities. It was known that among the polycations, ioneries, which have quaternary ammonium groups in the backbone chain, were more effective in giving membranes of higher permselectivities. On this base, syntheses and characterizations of the polycations, with different chemical structures from the published ones, for the polyion complex membrane formation were studied in this paper.

• Journal of Environmental Science International
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• v.25 no.9
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• pp.1311-1322
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• 2016

Since the scale and disaster characteristics of volcanic eruptions are determined by their geological features, it is important not only to grasp the current states of the volcanoes in neighboring countries around the Korean Peninsula, but also to analyze the tectonic settings, tectonic regions, geological features, volcanic types, and past eruptional histories of these volcanoes. We created a database of 285 volcanoes around the Korean Peninsula, and then identified a high-risk groups of 29 volcanoes that are highly likely to affect the region, based on conditions such as volcanic activity, the type of rocks at risk of eruption, the distance from Seoul, and high VEI (volcanic explosivity index). In addition, we identified the 10 volcanoes that should be given the highest priority. We selected them through an analysis of data available in literature, such as volcanic ash dispersion results from previous Japanese eruptions, the definition of a large-scale volcano used by Japan's Cabinet Office, and examination of cumulative magma layer volumes from Japan's quaternary volcanoes.

• Journal of the Microelectronics and Packaging Society
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• v.20 no.4
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• pp.65-68
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• 2013

A novel bumping process using solder bump maker (SBM) is developed for fine-pitch flip chip bonding. It features maskless screen printing process. A selective solder bumping mechanism without the mask is based on the material design of SBM. Maskless screen printing process can implement easily a fine-pitch, low-cost, and lead-free solder-on-pad (SoP) technology. Its another advantage is ternary or quaternary lead-free SoP can be formed easily. The process includes two main steps: one is the thermally activated aggregation of solder powder on the metal pads on a substrate and the other is the reflow of the deposited powder on the pads. Only a small quantity of solder powder adjacent to the pads can join the first step, so a quite uniform SoP array on the substrate can be easily obtained regardless of the pad configurations. Through this process, an SoP array on an organic substrate with a pitch of 130 ${\mu}m$ is, successfully, formed.

• Journal of Surface Science and Engineering
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• v.46 no.2
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• pp.75-79
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• 2013

A one-step route was developed to fabricate $Cu(In,Ga)Se_2$ (CIGS) thin films by radio frequency (RF) magnetron sputtering from a single quaternary $CuIn_{0.75}Ga_{0.25}Se_2$ target. The effects of the substrate temperatures on the structural and electrical properties of the CIGS layers were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS) and Hall effect measurements. All the deposited films showed a preferential orientation along the (112) direction. The films deposited at $300^{\circ}C$ and $400^{\circ}C$ revealed that chalcopyrite main (112) peak and weak prominent peaks of (220)/(204) and (312)/(116), indicating polycrystalline structures. The element ratio of the deposited film at $300^{\circ}C$ were almost the same as the near-optimum value. The carrier concentration of the films decreased with increasing substrate temperatures.

• Journal of Integrative Natural Science
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• v.10 no.4
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• pp.175-191
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• 2017

In organic chemistry amide synthesis is performed through condensation of a carboxylic acid and an amine with releasing one equivalent of water via the corresponding ammonium carboxylate salt. This method is suffering from tedious processes and poor atom-economy due to the adverse thermodynamics of the equilibrium and the high activation barrier for direct coupling of a carboxylic acid and an amine. Most of the chemical approaches to amides formations have been therefore being developed, they are mainly focused on secondary amides. Direct carbonylations of tertiary amines to amides have been an exotic field unresolved, in particular direct carbonylation of trimethylamine in lack of commercial need has been attracted much interests due to the versatile product of N,N-dimethylacetamide in chemical industries and the activation of robust N-C($sp^3$) bond in tertiary amine academically. This review is focused mainly on carbonylation of trimethylamine as one of the typical tertiary amines by transition metals of cobalt, rhodium, platinum, and palladium including the role of methyl iodide as a promoter, the intermediate formation of acyl iodide, the coordination ability of trimethylamine to transition metal catalysts, and any possibility of CO insertion into the bond of Me-N in trimethylamine. In addition reactions of acyl halides as an activated form of acetic acid with amines are reviewed in brief since acyl iodide is suggested as a critical intermediate in those carbonylations of trimethylamine.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.97-97
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• 2010

A new electric application method was developed to prepare epoxy/organoclay nanocomposite for the electrical insulation in the AC electric fields and it could be also used in the field of various viscous polymer/organoclay systems. The applied AC electric field condition was as follows; (1) inter-electrode distance: 40 mm, (2) application voltage: 3-11 kV, (3) frequency: 60~1,000 Hz, and (4) application time: 0~60 min. To characterize the epoxy/clay nanocomposite, WAXS and TEM analyses were confirmed. In order to explain how the organic modifier affects the exfoliation phenomena, a mechanism of the oscillating collision of the quaternary ammonium head was proposed and the effects of the AC voltage and frequency and the organoclay content were studied.

• Journal of the korean society of oceanography
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• v.34 no.4
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• pp.207-213
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• 1999

Sediment physical properties (compressional wave velocity, grain density, dry bulk density, and wet bulk density) are correlated to the paleoenvironmental parameters (coarse fraction, oxygen isotope, and planktonic foraminifera fragmentation) to reveal the possible interrelationship in the latest Quaternary sediments of the Ulleung Basin, the East Sea of Korea. Laboratory determinations of physical properties and paleoenvironmental parameters have been conducted on four piston core sediments. There are slight differences in the physical properties between glacial and interglacial period sediment sections. This is due to the large fraction of coarse grains of volcanic and terrigenous sediments relative to carbonate sediments. However, dry bulk density as an indicator of carbonate abundance in pelagic environment shows higher values at the lower part of cores, reflecting deeper CCD in the glacial period. Changes in velocity also relatively parallel to those in sediment coarse fraction, number of planktonic foraminifera, and wet bulk density. Therefore, we suggest that high-resolution physical properties may be used as a valuable tool for paleoenvironmental interpretation in the Ulleung Basin.

• Journal of the Korean Applied Science and Technology
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• v.21 no.4
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• pp.335-344
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• 2004

In this work, the properties as polishing wax for automobile of O/W type microemulsion containing wax, liquid paraffine and quaternaryammonium salt was investigated. The microemulsions were prepared at $96{\sim}97^{\circ}C$ by the phase inversion method, and polyoxyethylene(20) sorbitan monooleate (POE(20)SMO) and distearyl dimethyl ammonium chloride(D.D.A.C) as the emulsifiers were used. The mean particle size of the rnicroemulsions was about 7${\pm}$0.5nm and as the properties of polishing wax, gloss increased degree, water resistant gloss degree, initial and final contact angle after water resistance were tested. The result was that the value of water resistantance and contact angle were decreased with increasing amount of POE(20)SMO and D.D.A.C., while the gloss degree values did not affected. And the rnicroemulsion blended with mono ethylene glycol(MEG) of 5${\sim}$15wt% showed smaller particle size and more stable particle size distribution than without MEG. Finally, this microemulsion showed more excellent values of gloss degree, the water resistant gloss degree and contact angle, than two kinds of commercial polishing wax for automobile.

• Nuclear Engineering and Technology
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• v.52 no.1
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• pp.109-114
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• 2020

This work presents the results of laboratory scale tests of the CARBOFLUOREX (CARBOnate FLUORide EXtraction) process - a novel technology for the recovery of U and Pu from the solid fluorides residue (fluorination ash) of Fluoride Volatility Method (FVM) reprocessing of spent nuclear fuel (SNF). To study the oxidative leaching of U from the fluorination ash (FA) by Na₂CO₃ or Na₂CO₃-H₂O₂ solutions followed by solvent extraction by methyltrioctylammonium carbonate in toluene and purification of U from the fission products (FPs) impurities we used a surrogate of FA consisting of UF₄ or UO₂F₂, and FPs fluorides with stable isotopes of Ce, Zr, Sr, Ba, Cs, Fe, Cr, Ni, La, Nd, Pr, Sm. Purification factors of U from impurities at the solvent extraction refining stage reached the values of 10⁴-10⁵, and up to 10⁶ upon the completion of the processing cycle. Obtained results showed a high efficiency of the CARBOFLUOREX process for recovery and separating of U from FPs contained in FA, which allows completing of the FVM cycle with recovery of U and Pu from hardly processed FA.