• Computers and Concrete
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• v.23 no.3
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• pp.171-188
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• 2019

This study proposed a new and efficient 2D damage-plasticity model within the framework of Isogeometric analysis (IGA) for the geometrically nonlinear damage analysis of concrete. Since concrete exhibits complicated material properties, two internal variables are introduced to measure the hardening/softening behavior of concrete in tension and compression, and an implicit gradient-enhanced formulation is adopted to restore the well-posedness of the boundary value problem. The numerical results calculated by the model is compared with the experimental data of three benchmark problems of plain concrete (three-point and four-point bending single-notched beams and four-point bending double-notched beam) to illustrate the geometrical flexibility, accuracy, and robustness of the proposed approach. In addition, the influence of the characteristic length on the numerical results of each problem is investigated.

• Korean Chemical Engineering Research
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• v.47 no.1
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• pp.31-37
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• 2009

A zwitterionic surfactant shows not only detergency but also mildness effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH variations of the aqueous solution. In this study, physical properties of betaine surfactant such as CMC, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was performed. Also dual function characteristics of betaine zwitterionic surfactant were investigated by measuring an isoelectric point using QCM(quartz crystal microbalance) and zeta potential measurement. The CMC of betaine surfactant was near $10^{-4}mol/L$ and the surface tension at CMC was about 32 mN/m. The interfacial tension between 1 wt% aqueous solution and n-decane measured by spinning drop tensiometer at pH 2~10 resulted in an increase in interfacial tension until pH 5 and a decrease with pH after 5 and equilibration time showed the similar trend with an increase in pH. The isoelectric point of betaine surfactant measured by QCM experiment was found to exist between 3.0 and 3.3, which is the same as the result determined by zeta potential measurement.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.433-439
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• 2012

In this study, a cationic surfactant BHMAS (N,N-bis-(3'-n-dodecyloxy-2'-hydroxypropyl)-N-methyl-2-hydroxyethylammonium methyl sulfate) having two lauryl and three hydroxyl groups was synthesized by the reaction of n-dodecyl glycidyl ether and 2-aminoethanol followed by the quarternization with dimethyl sulfate. The structure of the product was elucidated by $^{1}H-NMR$ and FT-IR. The CMC (critical micelle concentration) and surface tension of BHMAS at CMC condition were found to be $9.12\;{\times}\;10^{-4}$ mol/L and 28.71 mN/m respectively. Dynamic surface tension measurements using a maximum bubble pressure tensiometer indicated that a relatively long time was required to saturate the interface between air and aqueous surfactant solution. The interfacial tension measured between 1 wt% surfactant solution and n-decane reached an equilibrium value of 0.045 mN/m in 5 min. The adsorption capacity of the synthesized surfactant was observed to be excellent, which suggests that the surfactant can be used as a softening agent during a laundry process.

• Magazine of the Korea Concrete Institute
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• v.8 no.3
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• pp.187-195
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• 1996

A finite element formulation based on the CFT(Compression Field Theory), considering the effect of compression softening in cracked concrete, and macro-scopic and rotating crack models etc., was presented for the nonlinear behaviour of structural concrete. Considering the computational efficency and the ability of modelling the post-ultimate behaviour as major concerns, the Incremental displacement solution algorithm involving initial material stiffnesses and the relaxation procedure for fast convergence was adopted and formulated in a type of 8-noded quadrilateral isoparametric elements. The analysis program NASCOM(Non1inear Analysis of Structural Concrete by FEM : Monotonic Loading) developed in this way enables the predictions of strength and deformation capacities in a full range, crack patterns and their corresponding widths, and yield extents of reinforcement. As the verification purpose of NASCOM, the predictions were made for Bhide's Panel(PB21) and Leonhardt's deep beam tests. The predicted results shows somewhat stiff behaviour for the panel test, and vice versa for deep beam tests. More refining process would be necessary hereafter in terms of more accurately simulating the effects of tension-stiffening and compression softening in concrete.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.2
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• pp.125-133
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• 1988

To establish the rational design method, it is very important that predict accurately load-deformation response on reinforced concrete members. Torque-twist curves of reinforced concrete members in pure torsion were proposed recently by Collins and Hsu, etc. But, it is found that torsional strength of reinforced concrete members based on Hsu's theory is underestimated in the over-all load region except the ultimate state. In this paper, an attempt is made to present the higher-precision of torsional strength on arbitrary loading condition. For this purpose, constitutive equations are derived from which an estimate can be made of the torsional behavior of reinforced concrete members under the pure torsion. Tension stiffness of concrete in both the cracked and uncracked state have been considered. A softening effect that reduces the strength of the concrete by the diagonal cracking of concrete have been appropriately deliberated. Particularly, the experiments was done with 14 test beams to investigate the validity of theoretical analysis.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.2
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• pp.69-77
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• 1987

A finite element method has been developed to study the material nonlinear analysis of reinforced concrte structures. Concrete behavior under the biaxial state of stress is represented by a nonlinear constitutive relationship which incorporates tensile cracking, tensile stiffening effect between cracks and the strain-softening phenomenon beyond the maximum compressive strength. The concrete model used is based upon nonlinear elasticity by assuming concrete to be an orthotropic material and modeled as equivalent uniaxial stress-strain constitutive relationship using equivalent uniaxial strain. The streel reinforcement is assumed to be in a uniaxial stress state and is modeled as a bilinear, elasto-plastic material with strain hardening approximating the Bauschinger effect. In plane stress state, R.C. beams is modeled as a quadratic element that has two degrees of freedom in each node. And this results of finite element analysis are compared with the experimential results of midspan deflection, stresses and strains.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.960-968
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• 2012

In this study, the measurement of physical properties of 3 different ethylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of the zwitterionic surfactants were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of the synthesized zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that all three surfactants used during this study provide better softening effect at a pH of neutral condition than at an acidic or an alkaline condition. This result indicates that the synthesized surfactants act as a cationic surfactant at a pH of neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.9-14
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• 2009

A zwitterionic surfactant shows not only detergency but also softening effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH of the aqueous solution. In this study, the dual function characteristics of an amine oxide zwitterionic surfactant were investigated by measuring the zeta potential and the isoelectric point using quartz crystal microbalance (QCM). In addition, the physical properties of an amine oxide surfactant such as critical micelle concentration, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was also performed. The isoelectric point of an amine oxide surfactant determined by zeta potential measurement was near 7.35 and that obtained by QCM experiment was about 7.4, where both results were found to be close to the value reported in the literature.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.112-118
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• 2012

In this study, physical properties of synthesized DE7-OSA82-AO and DEP52-OSA82-AOQ82 zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle and viscosity. Phase behavior study was also performed. The dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which was attained using zeta potential measurements and QCM (quartz crystal microbalance) experiments. The isoelectric point of DE7-OSA82-AO surfactant determined by the zeta potential measurement and QCM experiment was about 7.2 and 7.4, respectively. On the other hand, the isoelectric point of DEP52-OSA82-AOQ82 surfactant determined by the zeta potential measurement and QCM experiment was about 10.9 and 11.0, respectively. The frictional property measured using an automated mildness tester showed that DE7-OSA82-AO surfactant can provide a good softening effect at an acidic or neutral condition. On the other hand, DEP52-OSA82-AOQ82 was found to provide a good softening effect to a fabric surface at a pH below its isoelectric point of 11.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.455-463
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• 2012

In this study, the measurement of physical properties of ethylene oxide-propylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of DEP-OSA82-AO zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that DEP32-OSA82-AO and DEP34-OSA82-AO surfactants provide better softening effect at a pH of acidic or neutral condition than at an alkaline condition. This result indicates that both surfactants act as a cationic surfactant at a pH of acidic or neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.