• Title/Summary/Keyword: Temperature stability time

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Prediction of Continuous Reactors Performance Based on Batch Reactor Deactivation Kinetics Data of Immobilized Lipase

  • Murty, V.Ramachandra;Bhat, Jayadev;Muniswaran, P.K.A.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.4
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    • pp.225-230
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    • 2002
  • Experiments on deactivation kinetics of immobilized lipase enzyme from Candida cyl-indracea were performed in stirred bath reactor using rice bran oil as the substrate and temperature as the deactivation parameter. The data were fitted In first order deactivation model. The effect of temperature on deactivation rate was represented by Arrhenius equation. Theoretical equations were developed based on pseudo-steady state approximation and Michaelis -Menten rate expression to predict the time course of conversion due to enzyme deactivation and apparent half-life of the immobilized enzyme activity in PFR and CSTH under constant feed rate polity for no diffusion limitation and diffusion limitation of first order. Stability of enzyme in these continuous reactors was predicted and factors affecting the stability were analyzed.

Heat transfer monitoring between quenched high-temperature superconducting coated conductors and liquid nitrogen

  • Rubeli, Thomas;Colangelo, Daniele;Dutoit, Bertrand;Vojenciak, Michal
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.1
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    • pp.10-13
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    • 2015
  • High-temperature superconducting coated conductors (HTS-CCs) are good candidates for resistive superconducting fault current limiter (RSFCL) applications. However, the high current density they can carry and their low thermal diffusivity expose them to the risk of thermal instability. In order to find the best compromise between stability and cost, it is important to study the heat transfer between HTS-CCs and the liquid nitrogen ($LN_2$) bath. This paper presents an experimental method to monitor in real-time the temperature of a quenched HTS-CC during a current pulse. The current and the associated voltage are measured, giving a precise knowledge of the amount of energy dissipated in the tape. These values are compared with an adiabatic numerical thermal model which takes into account heat capacity temperature dependence of the stabilizer and substrate. The result is a precise estimation of the heat transfer to the liquid nitrogen bath at each time step. Measurements were taken on a bare tape and have been repeated using increasing $Kapton^{(R)}$ insulation layers. The different heat exchange regimes can be clearly identified. This experimental method enables us to characterize the recooling process after a quench. Finally, suggestions are done to reduce the temperature increase of the tape, at a rated current and given limitation time, using different thermal insulation thicknesses.

Effects of Rapid Thermal Annealing on Thermal Stability of FeMn Spin Valve Sensors

  • Park, Seung-Young;Choi, Yeon-Bong;Jo, Soon-Chul
    • Journal of Magnetics
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    • v.10 no.2
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    • pp.52-57
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    • 2005
  • In this research, magnetoresistance (MR) ratio (MR), resistivity, and exchange coupling field $(H_{ex})$ behaviors for sputter deposited spin valves with FeMn antiferromagnetic layer have been extensively investigated by rapid thermal annealing (RTA) as well as conventional annealing (CA) method. 10 s of RTA revealed that interdiffusion was not significant up to $325^{\circ}C$ at the interfaces between the layers when the RTA time was short. The MR of FeMn spin valves were reduced when the spin valves were exposed to temperature of $250^{\circ}C$, even for a short time period of 10 s prior to CA. $H_{ex}$ was maintained up to $325^{\circ}C$ of CA when the specimen was subjected to 10 s of RTA at $200^{\circ}C$ prior to CA, which is $25^{\circ}C$ higher than the result obtained from the CA without prior RTA. Therefore, the stability of $H_{ex}$ could be enhanced by a prior RTA before performing CA up to annealing temperature of $325^{\circ}C$. MR and sensitivity of the specimens annealed without magnetic field up to $275^{\circ}C$ were recovered to the values prior to CA, but $H_{ex}$ was not recovered. This means that reduced MR sensitivity and MR during the device fabrication can be recovered by a field RTA.

Changes in oxidative stability of the oil extracted from perilla seed roasted at different roasting conditions (들깨의 볶음 조건에 따른 들기름의 산화 안정성 변화)

  • Kim, In-Hwan;Lee, Young-Chul;Jung, Sook-Young;Jo, Jae-Sun;Kim, Young-Eon
    • Applied Biological Chemistry
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    • v.39 no.5
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    • pp.374-378
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    • 1996
  • The oxidative stabilities of perilla oil increased as roasting temperature and time increased. Induction period of the perilla oil from unroasted perilla seed was 3.9 days, but that of the oil from perilla seed roasted at $210^{\circ}C$ for 30 min was 55 days. The electron donating ability(EDA) on DPPH by perilla oils increased as the roasting temperature and time increased. EDA of the unroasted perilla oil was 24% but that of the perilla oil roasted at $210^{\circ}C$ for 30 min was 64%. These results indicated that the reducing compounds were formed during the roasting process. The fluorescence intensity in perilla oil increased as the roasting temperature and time were increased. This result indicated that Maillard reaction has occurred during the roasting process and the reaction products seemed to provide stability to perilla oil.

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Development of the Soil Thermal Property and Temperature Measurement System for the Real-time Ampacity Estimation of Underground Power Cables (실시간 지중 전력케이블 용량 평가를 위한 토양 열 특성 및 온도 측정 시스템 개발)

  • Jeong, Seong-Hwan;Kim, Dae-Kyeong;Choi, Sang-Bong
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.22-24
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    • 2002
  • This paper introduces the real-time soil thermal property analyzer and temperature measuring system which is combined with radio telecommunication technique. To measure the thermal parameters in real-time, the radio telecommunication technique are used the personal communication service (PCS) which is in the world-wide serviced commercially firstly by CDMA. The thermal property analyzer has an ability of measuring thermal resistivity, thermal diffusivity and thermal stability. To estimate the soil thermal properties, the curve fitting algorithm by means of the least square method are used. TCP/IP protocol and MTM are used to install the real-time soil thermal property and temperature measurement system at multiple locations along routes of the underground power cables and to reduce the cost of telecommunication.

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Chemical Stability through CO2 Curing of Cement Paste Exposed to High Temperature (고온 환경에 노출된 시멘트 페이스트의 DCG 양생을 통한 화학적 안정화)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-Cheo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.73-74
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    • 2019
  • In order to examine the chemical stabilization through DCG curing of cement paste exposed to high temperature environment, we produced a sample of 40% W/C cement paste and heated it for 180 minutes under the heating temperature of $800^{\circ}C$. The DCG curing time was 6, Three time conditions were divided into 12 and 18 hours. As a result of XRD analysis, Calcite ($CaCO_3$) was found in Theta 29.4, 40, and 46.5o. As the curing time increased, the peak of Calcite also increased, which is due to the increased reaction time with DCG. Therefore, Calcite produced through DCG curing seems to have stabilized chemically by filling the pores generated by heating.

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Thermal Stability and Cure Behavior of Waterborne Phenol-Formaldehyde Resin (수용성 페놀-포름알데히드 수지의 열안정성 및 경화거동)

  • Yoon, Sung Bong;Kim, Jin Woo;Cho, Donghwan
    • Journal of Adhesion and Interface
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    • v.7 no.1
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    • pp.16-22
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    • 2006
  • In this work, the effect of cure temperature and time on the thermal stability and the exothermic cure reaction peak of a waterborne resol-type phenol-formaldehyde resin, which may be used for preparing phenolic sheet molding compounds (SMC), has been investigated using a thermogravimetric analyzer and a differential scanning calorimeter. The weight loss of waterborne phenol-formaldehyde resin was mainly occurred at three temperature stages: near $200^{\circ}C,\;400^{\circ}C$, and $500^{\circ}C$. The carbon yield at $750^{\circ}C$ for the cured resin was about 62%~65%. Their thermal stability increased with increasing cure temperature and time. Upon cure, the exothermic reaction was taken placed in the range of $120^{\circ}C{\sim}190^{\circ}C$ and the maximum peak was found in between $165^{\circ}C$ and $170^{\circ}C$. The shape and the maximum of the exothermic curves depended on the given cure temperature and time. To remove $H_2O$ and volatile components, the uncured resin needed a heat-treatment at $100^{\circ}C$ for 60 min at least prior to cure or molding. Curing at $130^{\circ}C$ for 120 min made the exothermic peak of waterborne phenol-formaldehyde resin completely disappeared. And, post-curing at $180^{\circ}C$ for 60 min further improved the thermal stability of the cured resin.

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Quality Characteristics of Angelica gigas Nakai in Response to High-Temperature-Short-Time Treatment during Storage (고온단시간 처리에 따른 저장 중 참당귀의 품질 특성)

  • Lee, Eun Suk;Jee, Yun-jeong;Lee, Ji Yeon;Choi, Su Ji;Lee, Seung Eun;Kim, Hyung Don;Choi, Jehun;Kang, Min Hye;Kim, Dong Hwi;Jang, Gwi Yeong
    • The Korean Journal of Food And Nutrition
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    • v.33 no.6
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    • pp.645-654
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    • 2020
  • Angelica gigas Nakai (A. gigas) easily changes its color during storage, and appropriate thermal treatment can improve storage stability through inactivation of enzymes such as polyphenol oxidase. Therefore, this study was performed to determine quality characteristics of dried A. gigas in response to high-temperature-short-time (HTST) treatment during storage. Dried A. gigas were treated at 120-180℃ for 10 min, the samples were stored at 4℃ and 50℃ for 10 weeks, and used for the analysis of qualities. Concerning the color values, the sample treated at 120℃ was similar to the control, and the color change was large when treated above 180℃. However, color difference (ΔE⁎ab) was lower in treated samples than in control. Browning index was similar for all the samples except for the sample treated at 180℃. Functional qualities (phenolics content, antioxidant activities, and level of major components) showed a slight difference according to storage periods in all samples without control, and nodakenin content was observed in control. The results of this study showed that HTST treatment improved storage stability such as stability of colors and browning index in dried A. gigas during storage, and the appropriate treatment temperature was 120℃ in terms of stability in color and browning index.

Nonlocal strain gradient model for thermal stability of FG nanoplates integrated with piezoelectric layers

  • Karami, Behrouz;Shahsavari, Davood
    • Smart Structures and Systems
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    • v.23 no.3
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    • pp.215-225
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    • 2019
  • In the present paper, the nonlocal strain gradient refined model is used to study the thermal stability of sandwich nanoplates integrated with piezoelectric layers for the first time. The influence of Kerr elastic foundation is also studied. The present model incorporates two small-scale coefficients to examine the size-dependent thermal stability response. Elastic properties of nanoplate made of functionally graded materials (FGMs) are supposed to vary through the thickness direction and are estimated employing a modified power-law rule in which the porosity with even type of distribution is approximated. The governing differential equations of embedded sandwich piezoelectric porous nanoplates under hygrothermal loading are derived through Hamilton's principle where the Galerkin method is applied to solve the stability problem of the nanoplates with simply-supported edges. It is indicated that the thermal stability characteristics of the porous nanoplates are obviously influenced by the porosity volume fraction and material variation, nonlocal parameter, strain gradient parameter, geometry of the nanoplate, external voltage, temperature and humidity variations, and elastic foundation parameters.

Production of Automobile Al Wheel by Low-Pressure Die Casting (I) : Flow and Solidification Simulation (저압주조에 의한 자동차 Al Wheel의 제조(I) : 유동 및 응고해석)

  • Choo, In-Ho;Yu, Sung-Kon;Choi, Jeong-Kil
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.578-585
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    • 1998
  • A multi-purpose code MAGMA was employed for mold design and process control in producing Al wheel by lowpressure die casting. Three-dimensional solid modeling was followed by mesh generation of casting and molds(top, bottom and side). The simulation of stability of casting cycle time, mold filling simulation with pressure variation from P1 to P2, solidification simulation by solidification time and feeding criteria, and temperature distribution of molds during processes were studied in this research. The thermal stability of molds was attained after 5 cycles when molds were preheated at $400^{\circ}C$. The pressure increase from P1 to P2 for mold filling was evaluated as slightly higher, and 6 seconds were taken for the mold filling. The cycle time was believed to be designed properly judged from the solidification time of casting and open/close time of molds.

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