• Title/Summary/Keyword: Temperature stability time

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Recycling Natural Rubber Vulcanizates through Mechanochemical Devulcanization

  • Jang G. K.;Das C. K.
    • Macromolecular Research
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    • v.13 no.1
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    • pp.30-38
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    • 2005
  • Sulfur-cured gum natural rubber vulcanizates were devulcanized using two different concentrations of diallyl disulfide. The devulcanization process was performed at $110^{\circ}C$ min in an open two-roll cracker-cum-mixing mill. Natural rubber vulcanizates having various sulfur/accelerator ratios were used to study the cleavage of monosulfide, disulfide, and polysulfide bonds. The properties of devulcanized natural rubber increased upon increasing the disulfide concentration and the mechanical properties of the revulcanized natural rubber increased upon decreasing the sulfur content in the original rubber vulcanizates. The scorch time and the maximum state of cure both increased when the ground vulcanizates were treated with higher amounts of disulfide. TGA and DMA were conducted to study the effects of the devulcanization on the thermal stability and the $T_g$ behavior of the vulcanizates. SEM analysis was conducted to study how the failure mechanism was affected by the devulcanization process. It was possible to recover $70-80\%$ of the original gum rubber properties by using this process. From IR spectroscopic analysis, we observed that the oxidation of the main chains did not occur during high-temperature milling.

Study on Piezoresistive Humidity Sensor using Polycrystalline Silicon with Membrane (박막구조를 가진 폴리실리콘 압저항형 습도센서의 연구)

  • Park, Sung-Il;Park, Se-Kwang
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1422-1424
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    • 1994
  • This paper deals with piezoresistive humidity sensor using polycrystalline silicon (Poly-Si ) with membrane in sensors of semiconductor. Poly-Si piezoresistors which have no temperature dependancy are deposited on silicon wafer, membrane is formed with micromachining technology, then polyimide is formed as a hygroscopic layer. Whereas the principle of conventional humidify sensors are based on the change in electrical properties of the material, the humidity induced volume change of a polyimide layer leads to a deformation of a silicon membrane in this case. This deformation is transformed into an output voltage by Poly-Si piezoresistive. Wheatstone bridge. Fabricated piezoresistive humidity sensors showed good linearity, response time, and long term stability.

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Annealing Effects of The Electrochromic $MoO_3$ Thin Films (전기변색 $MoO_3$ 박막의 열처리 효과)

  • 임동규;이진민;조봉희;김동진;김영호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.505-508
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    • 1999
  • The effect of the heat treatment on electrochromic properties of $MoO_3$ thin films is investigated by studing optical modulation, optical density, response time, and cyclic voltammetry. From the results of XRD analysis, heat-treated at $450^{\circ}C$ in air for 1 hour $MoO_3$ thin films are found to be crystalline while as-deposited film and heat-treated at low temperature (${\leq}300^{\circ}C$) are amorphous. The electrochrornic devices using as-deposited $MoO_3$ films exhibits good electrochromic properties compare to those using the heat treated $MoO_3$ films. It has shown that the heat-treatment affected the stability and the electrochromic properties of $MoO_3$ films.

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Resistive Humidity Sensor Using Phosphonium Salt-Containing Polyelectrolytes Based on the Mutually Cross-linkable Copolymers

  • Lee, Chil-Won;Gong, Myoung-Seon
    • Macromolecular Research
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    • v.11 no.5
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    • pp.322-327
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    • 2003
  • Two kinds of mutually cross-linkable copolymers were prepared to be used as humidity-sensing materials. The humidity-sensitive thin films consist of cross-linked polyelectrolytes of the following component: 4-vinylbenzyl dimethyl 2-(dimethylphosphino)ethyl phosphonium chloride (1)/ bis(2-methoxyethyl)itaconate (2)= 3/l, 2/l, 1/1 and 1/2 and 4-vinylbenzyl chloride (3)/ vinylbenzyl tributyl phosphonium chloride (4)= 3/l, 2/l, 1/1 and 1/2. The humidity sensor prepared from the reaction of 1/2= 2/l with 3/4= 2/l showed an average resistance of 723,36.2 and 2.42 ㏀ at 30, 60 and 90%RH, respectively. Temperature dependence, frequency dependence, and response time were measured and the reliability test such as water durability and long-term stability were also estimated.

Evaluation of Fire-Resistant Performance for Tunnel Lining Concrete with Heating Temperature-Time Curves (시간가열온도곡선에 따른 터널라이닝 콘크리트의 내화성능 평가)

  • Lee, Chan-Young;Shim, Jae-Won;Ahn, Tae-Song;Lim, Chae-Hyeok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.477-480
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    • 2006
  • In this study, evaluation of fire-resistant performance for polypropylene fiber-mixed mortar was performed to establish specification for stability of tunnel structure against fire afterward. In the fire-resistant performance test with mix proportion of polypropylene fiber, cracks were observed for mortar under 0.15% of fiber content, but micro-cracks were remarkably reduced for mortar more than 0.2% of fiber content. From the results, we are concluded that optimal mix proportion of polypropylene fiber is $0.20{\sim}0.25%$.

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A Study on the Formation of Reversed Field configuration stability with Radio Rotating Field (고주파 회전자계를 이용한 역전자계 배위 안정성연구)

  • Kim, Won-Sop;Hwang, Jong-Sun;Kim, Jeong-Man;Kim, Young-Min
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2187-2189
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    • 2005
  • It is widely know that one of the most important tasks is the research of plasma for the purpose o nuclear fusion, is to make a stable confinement of high ${\beta}$ value plasma. And, for making the stable confinement, pinch p1-asma produced by reversed field has been mainly studied yet. Magnetic field has been used to hold plasma at high temperature for a long time. Reverse field has shown unstable process. Using ratio frequency, the author could control the instability of the process and formed a stable erversed field. Inthe experiment let a reversed field configuration from by adding-Bias field in advance.

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Characteristics of Lightning Impulse Current of ZnO Block for Transmission Line Arrester with External Gap (송전선로에 사용되는 갭형 피뢰기 소자의 뇌임펄스 전류특성)

  • Cho, Han-Goo;Yoo, Dae-Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.458-459
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    • 2007
  • This paper describes the characteristics of lightning impulse current of ZnO block for transmission line arrester with external gap. The ageing parameters of lightning arresters are impulse current, moisture ingress, temperature ageing and so on. Especially it is important to estimate the change of electrical characteristics by impulse current. Total energy applied to the ZnO arrester each time is $4/10{\mu}s$, 30kA and $2/20{\mu}s$, 10kA impulse current. Before and After the test, the residual voltage variation of varistors passed was below 5%. According to the test, it is thought that the ZnO arrester shows good stability with impulse current test.

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Crytallization of $\alpha$-amylase and protease of ASP. oryzae from Column Chromatograph (컬럼 크로마토그라피에 의한 아스퍼질러스 계통의 $\alpha$-아미라제 및 프로테아제의 결정화 2)

  • 서항원
    • Korean Journal of Microbiology
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    • v.10 no.2
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    • pp.69-72
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    • 1972
  • The studies of neutral protease which was obtained by passing through Sephadex A-50 had been reported not long ago. Since that time the author also conducted the research to be investigated the physical properties of acid protease absorbed by Sephadex A-50. The results are summarized as follows : 1) Cultivating Aspergillus oryza SHW-131 on a wheat bran medium, the acid protease including neutral protease is very sensitive for temperature. 3) Activity of acid protease is very sensitive for temeprature. 3) This enzyme was proved, what is called, to be a sort of weak acid protease. It's optimum pH was lied in about 4.5. 4) A range of pH for stability is far more narrow than any other protease. 5) The acid protease is dropped by EDTA solution in its activity.

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Production of High Fructose Syrup by Flocculated Actinoplanes missouriensis KCTC 1780 (Actinoplanes missouriensis KCTC 1780의 응집 균체에 의한 과당생산)

  • 조정일
    • The Korean Journal of Food And Nutrition
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    • v.6 no.4
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    • pp.268-275
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    • 1993
  • The whole cells of Actinoplanes missouriensis KCTC 1780 which produce glucose isomerase was immobillized by flocculation method for the effective production of high fructose syrup using packed-bed bioreactor system. Among the flocculation methods used In this study, the glucose Isomerase activity of flocculated cells using 5% polyethylenimmine and 0.2% glutaraldehyde was the highest as 46.3 unit, and the flocculant was 10.3g(wet weight) per 100m1 of broth, and the residual activity was 92.5%. In the batch operation of glucose isomerization using the flocculated cells, the optimum pH, temperature and isomerization ratio were 7.0, 75$^{\circ}C$ and 31%, respectively. The optimum concentration of Mg2+ which was activator on the glucose isomerization of flocculated cells was 0.1M, and glucose isomerase activity was increased by about 40% compared to none of Mg2+. In the packed-bed bioreactor system with 1.2 hour of residence time at 7$0^{\circ}C$, the reaction stability maintained until 96 hour without toss of activity, and the equilibrium was kept up to 120 hours of the operation.

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The Program Development for Real-Time Monitoring And Control of RF Output

  • Shin, Gang-wook;Hong, Sung-Tak;Yang, Jae-Rheen
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.69.6-69
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    • 2001
  • The SSPA makes the power level of EIRP up to 16W, and compensates for temperature to the SSPA´s maximum stability. The up and the down converters are dually conversed like as individual synthesizers for selecting of independent transmit-receive transponder. The function of the up-converter is to convert the 70MHz IF signal modulated in the indoor unit modem into a 14.0 ∼ 14.5 GHz Ku-band up-link signal to be sent to the antenna. The down-converter converts the 12.25 ∼ 12.75 GHz Ku-band down-link signal or a trouble malfunction of SSPA may be a fatal factor to operation of the whole satellite communication network. Therefore, this study developed the remote monitoring and control program to monitor the SSPA´s status before the problem occurs for stable operation of the system. This software ...

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