• Title/Summary/Keyword: Temperature stability time

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Study on the Atomic Layer Deposition System and Process of the MgO Thin Layer for the Thin Film Encapsulation of OLED (OLED의 Thin Film Encapsulation을 위한 MgO 박막의 원자층 증착 장치 및 공정에 관한 연구)

  • Cho, Eou Sik;Kwon, Sang Jik
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.22-26
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    • 2021
  • Thin-film encapsulation (TFE) technology is most effective in preventing water vapor and oxygen permeation in the organic light emitting diodes (OLED). Of those, a laminated structure of Al2O3 and MgO were applied to provide efficient barrier performance for increasing the stability of devices in air. Atomic layer deposition (ALD) method is known as the most promising technology for making the laminated Al2O3/MgO and is used to realize a thin film encapsulation technology in organic light-emitting diodes. Atomic layer deposited inorganic films have superior barrier performance and have advantages of excellent uniformity over large scales at relatively low deposition temperatures. In this study, the control system of the MgCP2 precursor for the atomic layer deposition of MgO was established in order to deposit the MgO layer stably by the injection time of second level and the stable heating temperature. The deposition rate was obtained stably to be from 4 to 10 Å/cycle using the injection pulse times ranging from 3 to 12 sec and a substrate temperature ranging from 80 to 150 ℃.

Beam-target configurations and robustness performance of the tungsten granular flow spallation target for an Accelerator-Driven Sub-critical system

  • Cai, Han-Jie;Jia, Huan;Qi, Xin;Lin, Ping;Zhang, Sheng;Tian, Yuan;Qin, Yuanshuai;Zhang, Xunchao;Yang, Lei;He, Yuan
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2650-2659
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    • 2022
  • The dense granular flow spallation target is a new target concept proposed for an Accelerator-Driven Sub-critical (ADS) system. In this paper, the beam-target configurations of a tungsten granular flow target for the ADS with a thermal power of 1 GW is explored. The beam profile options using different scanning methods are discussed. The critical geometry parameters are adjusted to investigate the performance of the granular target from the aspects of neutron efficiency, stability and temperature distribution in target medium. To figure out how the target under accident conditions would behave, different clogging conditions are induced in the simulation. The dynamic processes are analyzed and some important parameters such as abnormal temperature rise and beam cutoff time window are obtained. The response of the sub-critical reactor to a clogging accident is also investigated. It is indicated that the monitoring of the granular flow by the neutron detectors in the sub-critical core will be effective.

Photoelectrochemical property of thermal copper oxide thin films (열성장을 통해 형성된 산화구리의 광전기화학적 특성)

  • Choi, Yongseon;Yoo, JeongEun;Lee, Kiyoung
    • Journal of Surface Science and Engineering
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    • v.55 no.4
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    • pp.215-221
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    • 2022
  • In the present work, copper oxide thin films were formed by heat-treatment method with different temperatures and atmosphere, e.g., at 200 ~ 400 ℃; in air and Ar atmosphere. The morphological, electrical and optical properties of the thermally fabricated Cu oxide films were analyzed by SEM, XRD, and UV-VIS spectrometer. Thereafter, photoelectrochemical properties of the thermal copper oxide films were analyzed under solar light (AM 1.5, 100 mW/cm2). Conclusively, the highest photocurrent was obtained with Cu2O formed under the optimum annealing condition at 300 ℃ in air atmosphere. In addition, EIS results of Cu oxide formed in air atmosphere showed relatively low resistance and long electron life-time compared with Cu Oxide fabricated in Ar atmosphere at the same temperature. This is because heat-treatment in Ar atmosphere could not form Cu2O due to lack of oxygen, and thermally formed CuO at high temperature suppressed stability and conductivity of the Cu oxide.

Sustainable coatings fabricated from inorganic wastes for indoor humidity control and degradation of formaldehyde

  • Shou-Heng Liu;Yu-Rou Lin
    • International conference on construction engineering and project management
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    • 2024.07a
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    • pp.238-241
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    • 2024
  • With the development of living standard, people spend more time indoors, and the diversified home decoration will lead to indoor hazardous gas emission. Among them, formaldehyde (HCHO) is one of the most important sources of indoor air pollution, which is commonly found in building materials as a human carcinogen. To address this issue, we developed highly efficient multifunctional green building coatings (GBC) by TiO2, enhancement silica fume (ESF) and spent fluid catalytic cracking catalysts (sFCCC). Among these prepared GBC, the GBC-0.8 exhibited HCHO removal efficiency of 85.0 % under visible light at ambient temperature, which was much higher than that of commercial coatings (30.8%). In addition, moisture adsorption-desorption carrier tests were executed by different humidity. The humidity control capacity of GBC-0.8 could reach 293.8 g/m2 and demonstrate superior stability after 3 cycles. Compared with pristine TiO2, the addition of ESF and sFCCC showed higher specific surface area and pore size distribution, which was beneficial to improve humidity control and photocatalytic degradation performance. This study provides a promising green method for designing multifunctional green building materials coatings to recycle waste into high-value products and remove HCHO at room temperature

Cure Behavior, Thermal Stability and Flexural Properties of Unsaturated Polyester/Vinyl Ester Blends (불포화 폴리에스터/비닐에스터 블렌드의 경화 거동, 열안정성 및 굴곡 특성)

  • 이종문;조동환
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.120-128
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    • 2003
  • The effects of catalyst, accelerator and blend composition on the cure behavior of unsaturated polyester resin (UPE), vinyl ester resin (VE) and their blends were studied using differential scanning calorimetry(DSC). The DSC thermograms strongly depend on each variable. The result shows that the small exothermic peak at 115$^{\circ}C$ is due mainly to the UPE component in the UPE/VE blends and the large one at 134~138 $^{\circ}C$ is due mainly to the VE component. The results also indicate that the change of the DSC thermogram measured after each blend was exposed to high temperature 18$0^{\circ}C$ and the fast curing conditions of a few tens seconds provide useful information on understanding the thermal processing of a blend at high speed. The measurements of resin flow time represent that there are three distinct stages of cure in the UPE/VE blends: induction, transition and macro-gelation stages, as similarly reported for UPE by others earlier. The thermal stability and flexural properties of the cured UPE are significantly improved by blending it with the VE, depending on the composition.

Research Trend of The Heat-Treatment of Wood for Improvement of Dimensional Stability and Resistance to Biological Degradation (목재의 치수안정성과 내후성 개선을 위한 열처리 가공에 관한 연구 동향)

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.457-476
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    • 2016
  • This was investigated on the major issues and research trends regarding the heat-treatment of woods through literature reviews. The principal heat-treatment technologies utilized for industrial purposes include the Plato-process (Netherlands), the Retification process (France), the OHT-process (Germany), and the Thermowood Process (Finland). Factors that mainly influence the heat-treatment process are the wood species, process temperature, processing time, and the heating medium (air, steam, vacuum, N2, oil, etc.). Researches on investigating the optimal conditions with these process conditions being the variables stand as the mainstream. Heat-treated woods present dimensional stability improvement, but mass loss and strength reduction, a wide variations for decaying inhibition, and insufficient resistance against mold, wood borer, and termites. For further improvement in respects of durability or resistance to biological degradation, necessity to search for more suitable heat treatment process and processing conditions fit for each wood species has been suggested. Exploiting new ways to utilize heat-treated wood and extending its range of use have been considered to be important matters that need more effort put into for the sustainable and sound environment as well as saving the wood resources.

Effects of Carbon Nitride Surface Layers and Thermal Treatment on Field-Emission and Long-Term Stability of Carbon Nanotube Micro-Tips (질화탄소 표면층 및 열처리가 탄소 나노튜브 미세팁의 전계방출 및 장시간 안정성에 미치는 영향)

  • Noh, Young-Rok;Kim, Jong-Pil;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.1
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    • pp.41-47
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    • 2010
  • The effects of thermal treatment on CNTs, which were coated with a-$CN_x$ thin film, were investigated and related to variations of chemical bonding and morphologies of CNTs and also properties of field emission induced by thermal treatment. CNTs were directly grown on nano-sized conical-type tungsten tips via the inductively coupled plasma-chemical vapor deposition (ICP-CVD) system, and a-$CN_x$ films were coated on the CNTs using an RF magnetron sputtering system. Thermal treatment on a-$CN_x$ coated CNT-emitters was performed using a rapid thermal annealing (RTA) system by varying temperature ($300-700^{\circ}C$). Morphologies and microstructures of a-$CN_x$/CNTs hetero-structured emitters were analyzed by FESEM and HRTEM. Chemical composition and atomic bonding structures were analyzed by EDX, Raman spectroscopy, and XPS. The field emission properties of the a-$CN_x$/CNTs hetero-structured emitters were measured using a high vacuum (below $10^{-7}$ Torr) field-emission measurement system. For characterization of emission stability, the fluctuation and degradation of the emission current were monitored in terms of operation time. The results were compared with a-$CN_x$ coated CNT-emitters that were not thermally heated as well as with the conventional non-coated CNT-emitters.

Studies on the Secondary Battery Application of the Surface Fluorinated Microporous PE Separator Membranes (표면 불소화된 미세다공성 PE 격리막의 이차전지 적용을 위한 연구)

  • Byun, Hong-Sik;Kim, Dae-Hoon;Cho, Hyun-Il;Lee, Byung-Seong;Hong, Byung-Pyo;Lee, Sang-Yun;Nam, Sang-Yong;Seo, Myung-Su;Rhim, Ji-Won
    • Membrane Journal
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    • v.18 no.1
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    • pp.75-83
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    • 2008
  • In this research, the research for enhancing the stability at the mechanical strength and thermal stability and high power through the Direct Fluorination of the Polyethylene (PE, Asahi) for secondary battery was conducted. The surface of according to the fluorine gas exposure time and constructional change were observed through the scanning electron microscope image, and the contact angle. The mechanical property was confirmed through the tensile strength and surface hydrophilic property experiment. Charge and discharge experiment, the lifetime property, and the overcharge test were performed in order to confirm the electrochemical characteristic of produced and we confirmed at the high power that the stability about a temperature was improved.

Effect of Fabrication Processes on the Mechanical Properties of 0.14C-6.5Mn TRIP Steels (0.14C-6.5Mn TRIP강의 기계적 성질에 미치는 제조공정의 영향)

  • Lee, O-Yeon;Ryu, Seong-Il
    • Korean Journal of Materials Research
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    • v.11 no.5
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    • pp.431-437
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    • 2001
  • This research was examined the effect of intercritical heat treatment on the mechanical Properties and retained austenite formation in 0.1C-6.5Mn steels for the development of a high strength high ductility steel. using of transformation induced plasticity due to retained austenite. The stability of retained austenite is very important for the good ductility and it depend on diffusion of carbon and manganese during reverse transformation. It is effective to heat treat at$ 645^{\circ}C$ in order to obtain over 30 vol.% of retained austenite. However, it is more desirable to heat treat at $620^{\circ}C$, considering the volume fraction and mechanical stability of retained austenite. The strength-elongation combination in cold rolled steel sheets after reverse transformed at $620^{\circ}C$ for 1hr was about 4000k9/mm7, but it decreased rapidly with increasing holding time at high temperature due to the decrease of ductility. The addition of 1.1%Si in 0.14C-6.5Mn TRIP steel does not improve the mechanical properties and retained austenite formation.

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Thermal and Electrical Properties of Poly(vinylidenefluoride-hexafluoropropylene)-based Gel-Electrolytes (Poly(vinylidenefluoride-hexafluoropropylene)계 겔-전해질의 열적, 전기적 특성)

  • 김영완;최병구;안순호
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.382-388
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    • 2000
  • Polymer electrolyte films consisting of poly(vinylidenefluoride-hexafluoropropylene) (PVdF-HFP), LiClO$_3$ and a mixture of ethylene carbonate (EC) and ${\gamma}$-butyrolactone (GBL) were examined in order to obtain the best compromise between high ionic conductivity, homogeniety, dimensional and electrochemical stability. Measurements of ionic conductivity, differential scanning calorimetry and linear sweep voltammetry have been carried out for various compositions. The highest conductivity of 3.8$\times$10$^{-3}$ S$cm^{-1}$ / at 3$0^{\circ}C$ were obtained for a film of 30(PVdF-HFP)+7.8LiClO$_4$+62.2EC/GBL. From the DSC study, it has been found that the PVdF-HFP gels are stable up to 10$0^{\circ}C$, and the salt lowers the melting temperature of crystalline part of PVdF by interacting sensitively with polymer segments. When Lithium metal is in contact with the gel films, it tends to undergo corrosion and the reaction products accumulate resulting in the formation of a passive film on Li electrode. As the aging time progresses, the interfacial resistance increases continuously. Anodic stability is measured to extend up to about 4.5 V vs. Li.

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