• Polymer(Korea)
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• v.25 no.1
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• pp.78-89
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• 2001

Morphological changes of unsaturated polyester/polyvinylacetate semi-IPN were studied while the phase separation and the cure reaction occurred in a competing fashion. The light scattering and thermal analysis techniques were used to investigate the phase separation rates and mechanical properties resultantly induced by molecular diffusion of thermoplastic polymer during the curing process of thermosetting polymer. The reaction activation energy was calculated by using Flynn-Wall method and the semi-IPN structure exhibited various phase-separation morphological characteristics. When PVAc composition was 10 wt%, the phase separation was not observed during the curing reaction, but the phase separation occurred in a similar fashion to nucleation and growth(NG) mechanism at room temperature. On the other hand, when PVAc composition was over 11.65 wt%, the phase separation was generated in the middle of the curing process. Consequently, the phase separation seemed to influence the curing reaction rate, which was also supported by the changing activation energy with conversion and PVAc composition. Finally, the total scattered intensity was measured at various temperature, and subsequently the diffusion rates of phase separation R(${\beta}m$) were evaluated.

• Journal of the Semiconductor & Display Technology
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• v.5 no.3 s.16
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• pp.29-32
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• 2006

Because of new requirements related to the employment of SMT(Surface Mounting Technology) manufacturing and the diversity of components on high density PCB(Printed Circuit Boards), Thermal control of the reflow process is required in order to achieve acceptable yields and reliability of SMT assemblies. Accurate control of the temperature distribution during the reflow process is one of the major requirements, especially in lead-free assembly. This study has been performed for reflow process using the commercial CFD(Computational Fluid Dynamics) tool for predicting flow and temperature distributions. Porous plate was installed to prevent leakage flow which was one of the major problem of temperature uniformity in the reflow process. There is a separation region where the flow is turned. Outside wall made of porous plate is to prevent and minimize separation region for acquiring uniform temperature during operation. This paper provided design concept from CFD results of the steady state temperature distribution and flow field inside a reflow oven.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.689-696
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• 1996

A comparison is made of the heat loss from a hollow cylinder, computed using an one-dimensional analytic method and a two-dimensional separation of variables scheme. For a two-dimensional analysis, the temperature of the inner surface as a boundary condition can be varied along the length of the cylinder by varing the temperature variation factor, b. Comparisons of the heat loss from the hollow cylinder using these two methods are given as a function of non-dimensional cylinder length, the ratio of the outer radius to the inner radius, temperature variation factor and Biot number. The result shows that the value of the heat loss from the hollow cylinder obtained using the one-dimensional analytic method becomes close to the value given by the two-dimensional separation of variables scheme as the value of Biot number and the non-dimensional hollow cylinder length increase and as the ratio of the outer radius to the inner radius decreases.

• KSBB Journal
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• v.6 no.4
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• pp.425-429
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• 1991

Porous glasses were prepared from $TiO_2$ containing borosilicate glass by the phase separation. Pore distribution and surface area of porous glasses were invesigated by SEM and porosimeter. As temperature and heating time increase. The pore size and volume increased, but the specific surface area decreased above the critical temperature. The specific surface area and pore size showed more sensitive change on the variation of heating temperature than of heating time.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.86-89
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• 2004

The present study reports the preparation of a compact ZSM-5 membrane showing high thermal stability and high separation factors, especially n-/i-butane isomers at high temperatures. ZSM-5 membrane was prepared on a porous $\alpha$-Al$_2$O$_3$ tube (an average pore diameter, ca. 100 nm) at 18$0^{\circ}C$ by the seed-assisted crystallization method. The XRD and SEM results showed that a thin zeolite layer (ca. 1 ${\mu}{\textrm}{m}$) was formed on the support surface. The single gas permeances of $N_2$, H$_2$, SF$_{6}$, n-butane, and i-butane were taken at 27$0^{\circ}C$. i-Butane permeance hardly changed after repeated thermal treatments up to 40$0^{\circ}C$, indicating the membrane is thermally stable. On the other hand, other single gas permeances increased when the membrane was further dried at 40$0^{\circ}C$, indicating thermal pretreatment at 27$0^{\circ}C$ could not remove all the adsorbed species in the membrane. i-Butane and SF$_{6}$ permeances were significantly lower than the permeances of smaller molecules, indicating that the membrane has a low concentration of defects. The ideal selectivities at 27$0^{\circ}C$ were 61 for $H_2$/i-butane and 47 for $H_2$/SF$_{6}$. The temperature dependency of n/i-butane ideal selectivities and separation factors for an equimolar n/i-butane mixture was studied. The ideal selectivity showed a maximum of 36 at 30$0^{\circ}C$. The separation factors increased with temperature and reached around 12 at 300-40$0^{\circ}C$, which were much higher than those reported in the literature.ature.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.1457-1459
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• 2003

This study reports the surface temperature pattern of the Tokyo Metropolitan area using the ASTER surface temperature product. The product is an image processed by applying temperature-emissivity separation to atmospheric corrected infrared thermal radiance of the land surface, then converted to surface temperature by using Planck's function. Daytime and nighttime observation in a cold season and a warm season were used in this study. As a result, 1) contrast between urban and suburban, 2) extraction of heating area in urban, 3) measurement of cooling effect of green space were achieved.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.1
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• pp.108-116
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• 2001

The vortex tube is a simple device which separates fluid stream into a cold stream and a hot stream without any chemical reaction. The process of energy separation in the vortex tube has caused a great deal of interest. Although many studies on energy separation in the vortex tube using air as the working fluid have been made so far, few experimental studies treated energy separation for incompressible fluid. So, an experimental study for the energy separation in the vortex tube using the water which is essentially an incompressible fluid is presented. When working fluid is the water, the best geometric values of nozzle area ratio and number of nozzle holes are 0.155, 6 respectively. These geometric values are showed by the similar values which are presented by compressible fluid as working fluid. But hot side mass fraction of which maximum temperature drop is happened are different from compressible fluid.

• Journal of the Korean Applied Science and Technology
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• v.28 no.3
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• pp.306-312
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• 2011

In this study, we are crystallized to the low density polyethylene (LDPE) micro-particles in $n$-dodecanol solution by thermally induced phase separation(TIPS) method. The Low density polyethylene micro-particles is used in a wide variety of polymer coatings and industrial application. The utility of that for a particular application depends on a number of factors such as the particle size and distribution, and chemical composition of the materials. However, there are still needs for new methods of preparation which will provide the structure with unique sizes. The widely used processes for micro-size particles are crystallization method and thermally induced phase separation. TIPS process based on the phase separation mechanism was performed for the LDPE system which undergoes liquid-solid phase separation. Effects of various operating parameters were examined on the structure variation of the particles. Professionality, take-up speed and crystallization rate depended on temperature and concentration of polymer in solution.

• Membrane Journal
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• v.13 no.3
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• pp.154-161
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• 2003

We measured the permeation characteristics of water with the hydrophobic PTFE membranes dependent on water temperature to confirm the separation of oxygen isotopes using Air Gap Membrane Distillation (AGMD) and Vacuum Enhanced Membrane Distillation (VEMD). Isotopic concentrations of $H_2^{16}O$ and $H_2^{18}O$ of the permeated water vapor were measured by Diode Laser Absorption Spectroscopy. Concentrations of the heavy oxygen isotopes in the permeated water vapor were decreased. Isotope separation coefficients for the hydrophobic PTFE membranes were 1.004∼1.01 depending on the experimental conditions. We observed the effects of air in membrane pores on the oxygen isotope separation. Isotope separation coefficients for the hydrophobic PTFE membranes without air in pores are higher than those for the membrane with air in pores.

• Current Applied Physics
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• v.18 no.12
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• pp.1558-1563
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• 2018

We demonstrate improved surface pit and phase separation in thick InGaN grown on a GaN/Si (111) substrate, using plasma-assisted molecular beam epitaxy with an indium modulation technique. The formation of surface pit and compositional inhomogeneity in the InGaN epilayer are investigated using atomic force microscopy, scanning electron microscopy and temperature-dependent photoluminescence. Indium elemental mapping directly reveals that poor compositional homogeneity occurs near the pits. The indium-modulation epitaxy of InGaN minimizes the surface indium segregation, leading to the reduction in pit density and size. The phase separation in InGaN with a higher pit density is significantly suppressed, suggesting that the pit formation and the phase separation are correlated. We propose an indium migration model for the correlation between surface pit and phase separation in InGaN.