• Title/Summary/Keyword: Temperature activation

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Thickness Dependent Temperature Accelerated Dielectric Break-down Strength of On-wafer Low Dielectric Constant Polymer Films

  • Kim, H. K.;Lee, S. W.;F. G. Shi;B. Zhao
    • KIEE International Transactions on Electrophysics and Applications
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    • v.2C no.6
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    • pp.281-286
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    • 2002
  • The temperature accelerated dielectric breakdown strength of on-wafer low-k dielectric polymer films with thicknesses ranging from 94 nm to 1141 nm is investigated by using the current-voltage characteristic measurements with MIS structures. The temperature dependence of dielectric strength is demonstrated to be Arrhenious for all thicknesses. However, the activation energy is found to be strongly thickness dependent. It follows an exponential relationship rather than being a single value, i.e., the activation energy increase significantly as film thickness increases for the thickness below 500 nm, but it is almost constant for the thickness above 500 nm. This relationship suggests that the change of the activation energy corresponding to different film thickness is closely related to the temperature dependence of the electron trapping/detrapping process in polymer thin films, and is determined by both the trapping rate and the detrapping rate. Thinner films need less energy to form a conduction path compared to thicker films. Hence, it leads to smaller activation energy in thinner films, and the activation energy increases with the increase in film thickness. However, a nearly constant value of the activation energy is achieved above a certain range of film thickness, indicating that the trapping rate and detrapping rate is almost equal and eventually the activation energy approaches the value of bulk material.

An Experimental Study on the Relation of Compressive Strength and the Equivalent Age according to the Kind of Cement (시멘트종류에 따른 압축강도와 등가재령 관계에 관한 실험적 연구)

  • Na, Chul-Sung;Jang, Jong-Ho;Khil, Bae-Su;Kim, Jung-II;Nam, Jae-Hyun;Kim, Moo-Han
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.11a
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    • pp.13-16
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    • 2003
  • There is no study that application of the maturity using H.B.C and H.S.C. Also activation energy has different values according to the cement, admixture and water-cement ratio. Therefore to make accurate explanation for the effect of temperature on concrete strength development properties, it is necessary that activation energy value according to the kind of cement is reviewed. This study compares and estimates equivalent age using activation energy value obtained by this experiment and Freiesleben activation energy value with compressive strength of concrete. As the result of this study, activation energy value obtained by this study has more accurate explanation of temperature's influence on concrete strength development than Freiesleben activation energy value.

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An Experimental Study on the Relation of Compressive Strength and the Equivalent Age according to the Kind of Cement (시멘트종류에 따른 압축강도와 등가재령 관계에 관한 실험적 연구)

  • 나철성;장종호;길배수;김정일;남재현;김무한
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.13.1-16
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    • 2003
  • There is no study that application of the maturity using H.S.C and H.S.C. Also activation energy has different values according to the cement, admixture and water-cement ratio. Therefore to make accurate explanation for the effect of temperature on concrete strength development properties, it is necessary that activation energy value according to the kind of cement is reviewed. This study compares and estimates equivalent age using activation energy value obtained by this experiment and Freiesleben activation energy value with compressive strength of concrete. As the result of this study, activation energy value obtained by this study has more accurate explanation of temperature's influence on concrete strength development than Freiesleben activation energy value.

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Study on the measurement of activation temperature of Non-Evaporable Getter (비증발형 게터의 활성화 온도 측정방법에 관한 연구)

  • Lee D. J.;Kim K. B.;In S. R.;Lim J. Y,;Kim W. B.
    • Journal of the Korean Vacuum Society
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    • v.14 no.1
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    • pp.1-6
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    • 2005
  • Getters are invariably covered with thin layers of oxides even in air. For the getter to function properly it is necessary to activate them by heating in vacuum during which the oxide layer is removed exposing clean surface. The so-called activation temperature is an important parameter along with gas sorption capacity since it determines the maximum temperature of a device in which a getter can be installed. Nevertheless, no standard method to measure activation temperature has been documented yet. In this study, a relatively simple method to measure the activation temperature based on the ultimate pressure measurement was suggested. The activation temperature of TiZrV alloy measured by the method was between 100℃~200℃.

Performance Analysis of Polymer Electrolyte Membrane Fuel Cell by AC Impedance Measurement (교류 임피던스 측정법을 이용한 고분자 전해질 연료전지의 성능특성 분석)

  • Seo, Sang-Hern;Lee, Chang-Sik
    • Journal of Hydrogen and New Energy
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    • v.20 no.4
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    • pp.283-290
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    • 2009
  • This study focuses on the performance characteristics of polymer electrolyte membrane fuel cell (PEMFC) using the AC impedance technique. The experiment was carried out to investigate the optimal operating conditions of PEMFC such as cell temperature, flow rate, humidified temperature and back-pressure. The fuel cell performance was analyzed by DC electronic-loader with constant voltage mode and expressed by voltage-current density. Additionally, AC impedance was measured to analysis of ohmic and activation loss and expressed by Nyquist plot. The results showed that the cell performance increased with increase of cell temperature, air flow rate, humidified temperature and backpressure. Also, the activation loss decreased as the increase of cell temperature, air flow rate, humidified temperature and backpressure.

High Temperature Deformation Behavior of Rapid-Solidification Processed Al-18Si Alloy (급냉응고된 과공정 Al-Si합금의 고온변형특성에 관한 연구)

  • 김성일
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2000.04a
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    • pp.183-186
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    • 2000
  • The high temperature deformation behavior of spray-formed Al-19wt%Si-1.87wt%Mg-0.085wt.%Fe alloy was studied by torsion testing in the strain rate range of 0.001-1 sec-1 and in the temperature range of 300-500 $^{\circ}C$. The relationship between stress temperature and strain rate is expressed using the Power law. the behavior of dynamic recrystallization is showed in 300-35$0^{\circ}C$, 1-0.1sec-1 and the behavior of dynamic recovery is showed in 450-50$0^{\circ}C$, 0.01-0.001sec-1 The size of Si particles is mall when the temperature is low and the strain rate is high. The strain rate sensitivity(m) and the apparent activation energy(Q) indicate the dependence on strain rate and temperature for flow stress respectively. The hot ductility is high when m is high and Q is low. The maps of strain rate sensitivity and apparent activation energy suggest the optimum processing conditions.

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Experimental Investigation on the Flow Characteristics of ER Fluids II (2nd Report, Viscosity-Temperature Characteristics of Dispersive ER Fluids) (ER 유체의 유동특성에 관한 실험적 연구 II (분산계 ER 유체의 점도-온도 특성))

  • 김도태
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1999.10a
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    • pp.393-398
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    • 1999
  • The temperature dependence of the viscosity was determined for an electrorheological(ER) fluid consisting of 35 weight% zeolite particles in hydraulic oil 46cSt. Thermal activation analysis were performed by changing the ER fluid's temperature from -1$0^{\circ}C$ to 5$0^{\circ}C$ at fixed electric field. According to the analysis, the activation energy for flow was about 79.64kJ/mole at E=0kV/mm. Generally, the hydraulic oil 46cSt will be operated at the temperature of about 4$0^{\circ}C$, the ER fluid's electric field dependence of viscosities were investigated at this temperature. also, the influence of adding the dispersant(Carbopl 940) on electrorheological effect of the ER fluid was discussed.

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Tooth bleaching effect by light activation on the tooth surface and intra-pulpal temperature: an in vitro study (광활성 유무가 치아미백과 치아표면 및 치수 내 온도에 미치는 영향)

  • Shim, Youn-Soo;Woo, Hee-Sun
    • Journal of Korean society of Dental Hygiene
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    • v.14 no.4
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    • pp.585-591
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    • 2014
  • Objectives : The purpose of this study was to investigate of the color change, tooth surface and intra-pulpal temperature of tooth bleaching by light activation Methods : Forty-eight extracted bovine teeth were immersed into a tea solution for 24 hours. The specimens were randomly divided into four groups(n=15):(G1) 15% HP + without light activation, (G2) 15% HP + light activation, (G3) 25% HP + without light activation, (G4) 25% HP + light activation. All specimens were bleached for 15 minutes three times. The spectrophotometer (CM-2600d, Konica Minolta, Osaka, Japan) was used including before bleaching, immediately after bleaching, 1 week, 1 and 3 months after the end of bleaching. The temperature rise were measured in the pulpal chamber and tooth surface with a digital thermocouple thermometer(Termopar Digital Multimeter, Tektronix DMM916, USA). Between the tested time points, the specimens were stored in distilled water. The data were analyzed by ANOVA, t-test and Tukey's post hoc test set at 0.05. Results : There was no significant color change by the use of light after the bleaching treatment(p>0.05). The dental bleaching treatments of teeth with 15% HP and 25% HP did not seem to be more effective when light source was used. There was no difference in color stability between groups within three month(p>0.05). There was an increase in tooth surface and pulp temperature, but it was not sufficient to cause damage to the pulp. Conclusions :The use of light activation has no obvious effective impact on the tooth bleaching effect.

Oxidation of Chloroethenes by Heat-Activated Persulfate (과황산의 열적활성화 및 염소계용제의 산화분해)

  • Zhang, Hailong;Kwon, Hee-Won;Choi, Jeong-Hak;Kim, Young-Hun
    • Journal of Environmental Science International
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    • v.26 no.11
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    • pp.1201-1208
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    • 2017
  • Oxidative degradation of chlorinated ethenes was carried out using heat-activated persulfate. The activation rate of persulfate was dependent on the temperature and the activation reaction rate could be explained based on the Arrhenius equation. The activation energy of persulfate was 19.3 kcal/mol under the assumption that the reaction between the sulfate radical and tricholoroethene (TCE) is very fast. Activation could be achieved at a moderate temperature, so that the adverse effects due to high temperature in the soil environment were mitigated. The reaction rate of TCE was directly proportional to the concentration of persulfate, indicating that the remediation rate can be controlled by the concentration of the injected persulfate. The solution was acidized after the oxidation, and this was dependent on the oxidation temperature. The consumption rate of persulfate was high in the presence of the target organic, but the self-decomposition rate became very low as the target was completely removed.

The Properties of carbonized and activated RDF (탄화 및 활성화된 RDF의 특성 연구)

  • Choi, Yeong-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.87-90
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    • 2006
  • The experimental study has been done for two kinds of pelletized RDFs to Investigate the carbonization effect to the chlorine concentrations, the heating value and the yield of Produced char in variable conditions of the carbonizing temperature and reaction time. One(RDF-1) is made of 100% wasted plastics and the other(RDF-2) is made of 60% wasted paper with 40% wasted plastics. The screw type carbonizer heated Indirectly by oil burner was used for the experiment and RDF feeding rate was 3kg/hr. The carbonizing temperature was 300, 350 400 and $45^{\circ}C$ and the reaction tine was 5, 10 and 15 minutes respectively. As the increase of carbonizing reaction time and temperature, the chlorine reduction rate was increased and oppositely the yield of char was decreased At the temperature of $400^{\circ}C$ and reaction time of 10 minutes the chlorine reduction rate was 60% and the char yield rate was 80% for the RDF-1 and those of RDF-2 were 80% and 75%, respectively. Additional activation experiment to the char produced from RDF-2 was done in the activation reactor by hot steam supply. As the increase of activation time the iodine number was increased. At the activation time of 20 minutes the iodine number was 552mg/g and the yield of activated carbon was 16%.

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