• 제목/요약/키워드: Temperature Reduction

검색결과 4,563건 처리시간 0.04초

텅스텐-니켈-망간 합금의 액상소결에 관한연구 (A Study on the Liquid Phase Sintering of Tungsten-Nickel-Manganese alloy)

  • 홍문희;이성;노준웅;백운형
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 1995년도 추계학술강연 및 발표대회 강연 및 발표논문 초록집
    • /
    • pp.25-25
    • /
    • 1995
  • Liquid phase sintering of 90W-6Ni-4Mn alloy has been investigated as functions of sintering atmosphere, heating rate, and reduction temperature. The present work accounts for the thermodynamic oxidatiodreduction reactions of constituent powders of W, Ni and Mn. By discounting these reactions, the previous investigations would obtain only the alloy with large pores and the lowered relative sintered density, by the liquid phase sintering under a dry hydrogen atmosphere. the sintering cycle consisted of a rapid heating to reduction temperatures under high purity nitrogen atmosphere, and holding for 4 hours and sintering at $1260^{\circ}C$ for 1 hour under a dry hydrogen gas. The relative density of the sintered alloy increased with increasing heating rate. As the reduction temperature increased, the relative density increased to the lm theotical density at the duction temture above $1150^{\circ}C$. The mimsturcatre of sintered alloys has been analysed by a scanning election microscope. The sintered density was compared with those obtained from the other investigators. It was found that the reduction $1150^{\circ}C$ results in the lowered densification of 90W-6Ni-4Mn alloy. This is caused by the fact that reducing reactions of W and Ni oxides contained in W an Ni powders concomitantly leads to oxidizing reaction of Mn powder the oxidized Mn is hardly reduced at sintering temperature and thereby remains large pores in the alloy. It is concluded that the W-Ni-Mn alloy with full density can be obtained by the precise control of atmosphere, heating rate, and sintering temperature.

  • PDF

대형주강의 고온파단형태에 미치는 [Mn/S]비의 영향 (The Influence of [Mn/S] Ratios on the Fracture Morphology of a Heavy-section Steel Castings at Elevated Temperature)

  • 김성규;김지태;박봉규;박흥일
    • 한국주조공학회지
    • /
    • 제34권5호
    • /
    • pp.170-178
    • /
    • 2014
  • Using the Gleeble test, the effects of [Mn/S] ratios and the presence of sulfides on the high-temperature fracture morphology of heavy-section steel castings were analysed via the observations of the microstructures. The specimens for which the [Mn/S] ratio was in the range of 60~80 showed a ductile fracture morphology with an area reduction of more than 60%, while some specimens with similar [Mn/S] ratios showed a brittle fracture morphology with an area reduction of 0.0% due to the liquidation of sulfides at the grain boundary. The fracture morphology was classified into three types in the Gleeble high-temperature tensile test specimens. The first type showed dimple formation at the grain boundary, the formation of globular MnS sulfides, and plastic deformation of sulfides at an elevated temperature, indicating a needle-point type of ductile fracture with area reductions of 96.0~97.8%. The second type was a knife-edge type brittle fracture with an area reduction of 0.0% due to the film-type liquidation of sulfides at the grain boundary, band-type liquidation, and the liquidation of a terraced nipple pattern. The third type was the typical ductile fracture with an area reduction of 31.3~81.0%, in accordance with the mixture of dimples with in the grains and terraced nipple pattern at the grain boundary.

Hydrogen Reduction of NiO Particles in a Single-Stage Fluidized-Bed Reactor without Sticking

  • Oh, Chang-Sup;Kim, Hang Goo;Kim, Yong Ha
    • 한국재료학회지
    • /
    • 제26권2호
    • /
    • pp.79-83
    • /
    • 2016
  • A commercial NiO (green nickel oxide, 86 wt% Ni) powder was reduced using a batch-type fluidized-bed reactor in a temperature range of 500 to $600^{\circ}C$ and in a residence time range of 5 to 90 min. The reduction rate increased with increases in temperature; however, agglomeration and sintering (sticking) of Ni particles noticeably took place at high temperatures above $600^{\circ}C$. An increasing tendency toward sticking was also observed at long residence times. In order to reduce the oxygen content in the powder to a level below 1% without any sticking problems, which can lead to defluidization, proper temperature and residence time for a stable fluidized-bed operation should be established. In this study, these values were found to be $550^{\circ}C$ and 60 min, respectively. Another important condition is the specific gas consumption rate, i.e. the volume amount ($Nm^3$) of hydrogen gas used to reduce 1 ton of Green NiO ore. The optimum gas consumption rate was found to be $5,000Nm^3/ton$-NiO for the complete reduction. The Avrami model was applied to this study; experimental data are most closely fitted with an exponent (m) of $0.6{\pm}0.01$ and with an overall rate constant (k) in the range of 0.35~0.45, depending on the temperature.

한방병원에 요통, 하지방사통으로 내원한 환자 236명에서 MRI상 추간판 탈출증과 적외선 체열 검사(DITI)와의 연관성 분석 (Correlation Analysis between HIVD of L-spine MRI and Digital Infrared Thermal Image (DITI) on the Patients of LBP Who Visit Korean Medicine Hospital)

  • 김길환;권옥준;주영국;송승배;김두리;최영준;신수지
    • 한방재활의학과학회지
    • /
    • 제27권3호
    • /
    • pp.107-115
    • /
    • 2017
  • Objectives This study is planned to classify correlation between HIVD of L-spine MRI and Digital Infrared Thermal Image (DITI). Methods We measured the temperature of both leg whose 120 men and 116 women patients with lumbar pain in Bucheon Jaseng Korean Medicine Hospital. And We use Magnetic Resonance Imaging (MRI) for classifying the patients who has lumbar intervertebral disc or not. Results 1) There was no statistical relation between difference of both leg's temperature and gender (p>0.05). 2) There was meaningful statistical relation between difference of both leg's temperature and age (p<0.05). 3) There was meaningful statistical relation between direction of HIVD of L-spine and direction of temperature reduction. 4) There was meaningful statistical relation between the severity of HIVD of L5/S1 and degree of temperature reduction. But there was no statistical relation between the severity of HIVD of L3/4, L4/5 and degree of temperature reduction. Conclusions We can use Digital Infrared thermal image (DITI) on low back pain patients for diagnosis. But we should not use DITI alone. DITI has limit in diagnosis.

MTV를 적용한 아스팔트 포설에서 열분리 저감 효과 (Effect of Thermal Segregation Reduction in Asphalt Paving with MTV)

  • 권기철
    • 한국도로학회논문집
    • /
    • 제20권4호
    • /
    • pp.1-6
    • /
    • 2018
  • PURPOSES : The objective of this study is to evaluate of the effect of thermal segregation reduction in asphalt paving using material transfer vehicles (MTVs). METHODS : Asphalt paving using MTVs was carried out, and the paved surface temperature was measured using an infrared camera. The amount of thermal segregation was estimated from temperature variations. RESULTS : The transportation of hot mix asphalt (HMA) using dump trucks caused temperature segregation that persisted in the paving surface if an MTV was not used. The average temperature variation was 8.58% in paved surfaces where an MTV was not used. However, the temperature variation was 3.10%, 2.86%, and 4.53% for the base layer, inter-layer, and surface layer, respectively, when an MTV was used. CONCLUSIONS : The use of an MTV in asphalt paving reduces thermal segregation approximately 2.3 times in an asphalt mat via a remixing process and also allows for a smoother work process because the paver never needs to stop to receive HMA. However, MTV equipment without pre-heating devices requires careful temperature control during the warm up process at the MTV during construction in the winter.

옥상녹화조성에 따른 온도저감효과에 관한 연구 -서울대학교 실험구를 중심으로- (The Effect of Temperature Reduction as Influenced by Rooftop Greening)

  • 이동근;윤소원;오승환;장성완
    • 한국환경복원기술학회지
    • /
    • 제8권6호
    • /
    • pp.34-44
    • /
    • 2005
  • The objective of this study is to analyze the thermal properties of various green roof type. The experimental districts, have different soil thickness, soil type, the existence of module and the different kinds of vegetation, had installed. A measurement was conducted in Seoul University to investigate the thermal impacts of rooftop greening. The measurement point of temperature were 30, located in soil surface, middle of the soil layer, under the module, hard surface and soffit surface of each experimental district. The experimental investigation lasted from 6th August to 29th August, a total of 24 days. The results showed that green roof can contribute thermal benefits by soil and vegetation and reduce building energy consumption by a role of insulation. It's also better to make soil thickness over 20cm and various vegetation that should be more effective. The district installed only soil also could be effective for reducing the temperature of roof surface. Therefore, the increase of soil thickness and various vegetation could reduce more temperature of roof surface and building energy consumption. Also, it's helpful to reduce temperature that plant coverage rate be raised.

전기저항 분석을 통한 은나노 입자 합성 시의 입자거동 연구 (Particle Behavior of Silver Nanoparticles Synthesized by Electrical Resistance Analysis)

  • 윤영우;유시홍;양성주;이성의
    • 한국전기전자재료학회논문지
    • /
    • 제28권8호
    • /
    • pp.531-538
    • /
    • 2015
  • This study examined the size and shape of the nano-silver particle through the analysis of electrical resistance when synthesizing nano-sized silver by using the chemical liquid reduction. Changes in particle behaviors formed according to the changes in electronic characteristics by electric resistance in each time period in the beginning of reduction reaction in a course of synthesizing the nano-silver particle formation were studied. In addition, analysis was conducted on particle behaviors according to the changes in concentration of $AgNO_3$ and in temperature at the time of reduction and nucleation and growth course when synthesizing the particles based on the particle behaviors were also examined. As the concentration of $AgNO_3$ increased, the same amount of resistance of approximately $5{\Omega}$ was increased in terms of initial electronic resistance. Furthermore, according to the result of formation of nuclear growth graph and estimation of slope based on estimated resistance, slops of $6.25{\times}10^{-3}$, $2.89{\times}10^{-3}$, and $1.85{\times}10^{-3}$ were derived from the concentrations of 0.01 M, 0.05 M, and 0.1 M, respectively. As the concentration of $AgNO_3$ increased, the more it was dominantly influenced by the nuclear growth areas in the initial phase of reduction leading to increase the size and cohesion of particles. At the time of reduction of nano-silver particle, the increases of initial resistance were $4{\Omega}$, $4.2{\Omega}$, $5{\Omega}$, and $5.3{\Omega}$, respectively as the temperature increased. As the temperature was increased into $23^{\circ}C$, $40^{\circ}C$, $60^{\circ}C$, and $80^{\circ}C$, slopes were formed as $4.54{\times}10^{-3}$, $4.65{\times}10^{-3}$, $5.13{\times}10^{-3}$, and $5.42{\times}10^{-3}$ respectively. As the temperature increased, the particles became minute due to the increase of nuclear growth area in the particle in initial period of reduction.

스크린 필터 구조 Partial Metal DPF의 PM 저감 특성 (PM Reduction Characteristics of Partial Metal DPF with Screen Mesh Filter Structure)

  • 김충희;김현철;이기수;최정황;전문수;신석신;서현규
    • 한국자동차공학회논문집
    • /
    • 제21권3호
    • /
    • pp.82-87
    • /
    • 2013
  • In this work, the 1L grade integrated metal DOC/DPF filter that can install in engine manifold position was developed to investigate the effect of platinum-coating amount of filter on the improvement of filter activation temperature and reduction of particulate matter (PM). This filter was installed in 2.9L CI engine which meets the EURO-4 emission regulation. Tests for PM reduction efficiency of filter were conducted under ND-13 mode with full-load test condition. It was revealed that the time to reach the activation temperature of metal filter ($280^{\circ}C$) was shorter as the amount of platinum-coating increased. This short activation time can be helpful for the reduction of CO and HC emissions during cold start condition. At the same time, PM reduced as the coating amount increased. The reduction percentage of $DOC_{40}$, $DOC_{20}$, and $DOC_0$ were 96.7% (2.34 mg/kW'h), 95.1% (3.47 mg/kW'h), and 94.5% (3.69 mg/kW'h) compared to previous result (71.4 mg/kW'h), respectively.

Hydrogen Reduction of a Black Nickel Oxide Ore in a Fluidized-Bed Reactor without Sticking

  • Oh, Chang Sup;Hong, Seung-Hun;Lee, Dong-Kyu;Kim, Hang Goo;Kim, Yong Ha
    • 한국재료학회지
    • /
    • 제27권2호
    • /
    • pp.63-68
    • /
    • 2017
  • A black nickel oxide powder, one of the commercial nickel oxide ores, was reduced by hydrogen gas in a batch-type fluidized-bed reactor in a temperature range of 350 to $500^{\circ}C$ and in a residence time range of 5 to 120 min. The hydrogen reduction behavior of the black nickel oxide was found to be somewhat different from that of green nickel oxide ore. For the black nickel oxide, the maximum temperature (below which nickel oxide particles can be reduced without any agglomeration) was significantly lower than that observed for the green nickel oxide. In addition, the best curve fittings of the Avrami model were obtained at higher values of the overall rate constant "k" and at lower values of the exponent "m", compared to those values for the green nickel oxide. It may be inferred from these results that the hydrogen reduction rate of the black nickel oxide is faster than that of the green nickel oxide in the early stages, but the situation reverses in the later stages. For the black nickel oxide ore, in spite of the low temperature sintering, it was possible to achieve a high degree fluidized-bed reduction at lower temperatures and at lower gas consumption rates than was possible for the green nickel oxide. In this regard, the use of black nickel oxide is expected to yield a benefit if its ore price is sufficiently lower than that of the green nickel oxide.

일산화탄소탈수소화효소를 이용한 이산화탄소의 전기화학적 환원에 미치는 pH와 온도의 영향 (Effect of pH and Temperature on the Electrochemical Reduction of Carbon Dioxide by Carbon Monoxide Dehydrogenase)

  • 신준원;김유성;이상희;이상필;이호준;임미란;송지은;신운섭
    • 전기화학회지
    • /
    • 제10권4호
    • /
    • pp.265-269
    • /
    • 2007
  • 일산화탄소탈수소화효소를 이용한 이산화탄소의 전기화학적 환원 반응의 최적화를 위해 pH와 온도의 영향을 살펴보았다. pH는 이산화탄소의 환원반응 용이성과 효소의 안정도 효과가 함께 반영되는 6.3에서 최적의 조건을 보였고, 온도는 이산화탄소의 용해도가 적어지더라도 효소의 활성이 가장 좋은 60도에서 최적 조건을 보였다. 일산화탄소탈수소화효소의 안정성 및 활성이 가장 중요한 조건임을 알 수 있었다.