• Title/Summary/Keyword: Temperature Jump

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Microstructure and PTCR Behavior of Semiconducting (1-x)$BaTiO_3$ - x$(Bi_{1/2}K_{1/2})TiO_3$ Ceramics ($BaTiO_3$ - $(Bi_{0.5}Ko_{0.5})TiO_3$계 세라믹의 PTC효과와 미세구조)

  • Park, Yong-Jun;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo;Kim, Dae-Joon;Lee, Woo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.336-336
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    • 2008
  • A positive temperature coefficient of electrical resistivity (PTCR) was investigated in a ferroelectric lead-free perovskite-type compound $(Bi_{0.5}K_{0.5})TiO_3$ within $BaTiO_3$-based solid solution ceramics. The electrical properties and the microstructure of (1-x) $BaTiO_3$ - x $(Bi_{0.5}K_{0.5})TiO_3$ (BBKT) ceramics made using a conventional mixed and have been synthesized by an ordinary sintering technique. The Curie temperature was obviously increased with increasing of $(Bi_{0.5}K_{0.5})TiO_3$ content. The BKT ceramics (x=0.05) sintered at $1400^{\circ}C$ for 4h display low resistivity values of $10^1-10^2$ ohm cm at room temperature, PTCR effect(jump) of 1.05*$10^3$, and the Curie temperature of $T_c=141^{\circ}C$.

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Effect of Re-oxidation on the Electrical Properties of Mutilayered PTC Thermistors (적층 PTC 써미스터의 전기적 특성에 대한 재산화의 영향)

  • Chun, Myoung-Pyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.2
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    • pp.98-103
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    • 2013
  • The alumina substrates that Ni electrode was printed on and the multi-layered PTCR thermistors of which composition is $(Ba_{0.998}Ce_{0.002})TiO_3+0.001MnCO_3+0.05BN$ were fabricated by a thick film process, and the effect of re-oxidation temperature on their resistivities and resistance jumps were investigated, respectively. Ni electroded alumina substrate and the multi-layered PTC thermistor were sintered at $1150^{\circ}C$ for 2 h under $PO_2=10^{-6}$ Pa and then re-oxidized at $600{\sim}850^{\circ}C$ for 20 min. With increasing the re-oxidation temperature, the room temperature resistivity increased and the resistance jump ($LogR_{290}/R_{25}$) decreased, which seems to be related to the oxidation of Ni electrode. The small sized chip PTC thermistor such as 2012 and 3216 exhibits a nonlinear and rectifying behavior in I-V curve but the large sized chip PTC thermistor such as 4532 and 6532 shows a linear and ohmic behavior. Also, the small sized chip PTC thermistor such as 2012 and 3216 is more dependent on the re-oxidation temperature and easy to be oxidized in comparison with the large sized chip PTC thermistor such as 4532 and 6532. So, the re-oxidation conditions of chip PTC thermistor may be determined by considering the chip size.

Thermographic Inspection of Fatigue Crack by Using Contact Thermal Resistance (접촉 열저항 효과를 이용한 피로균열의 적외선검사)

  • Yang, Seungyong;Kim, Nohyu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.187-192
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    • 2013
  • Fatigue crack was detected from a temperature change around surface crack using the thermographic technique. Thermal gradient across the crack decreased very much due to thermal resistance of contact surface in the crack. Heat diffusion flow passing through the discontinuity was visualized in temperature by infrared camera to find and locate the crack. A fatigue crack specimen(SM-45C), which was prepared according to KS specification and notched in its center to initiate fatigue crack from the notch tip, was heated by halogen lamp at the end of one side to generate a heat diffusion flow in lateral direction. A abrupt jump in temperature across the fatigue crack was observed in thermographic image, by which the crack could be located and sized from temperature distribution.

The Electrical Properties of the Laminated PTC Thermistor for Micro Circuit Protection as a Function of Starting Material and Sr Addition (초소형 회로보호용 적층 PTC 써미스터의 출발원료 및 Sr 첨가에 따른 전기적 특성)

  • Lee, Mi-Jai;Kim, Bit-Nan;Hwang, Jong-Hee;Kim, Jin-Ho;Park, Seong-Chul;Song, Jun-Baek
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.525-530
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    • 2011
  • We investigated the electrical properties the starting material and sintering condition on the laminated PTC thermistor for micro circuit protection. The influences of $BaTiO_3$ powder with the 0.3 and 0.45 ${\mu}m$ size and the electrical characteristics (Ba,Sr)$TiO_3$ sintered at 1350~1400$^{\circ}C$ for 2 h in a reducing atmosphere (1% $H_2/N_2$). The sintered (Ba,Sr)$TiO_3$ was increased pore and the grain size was decreased according to increasing Sr additions. In relative permittivity, the phase transition temperature of (Ba,Sr)$TiO_3$ was decreased for 2.5$^{\circ}C$ according to increasing 0.01 mole Sr additions, and the phase transition dose not appeared about 0.3 mole Sr addition. The (Ba,Sr)$TiO_3$ was show the low resistance from 0.01 mole to 0.05 mole by Sr addition, regardless of sintering temperature. The (Ba,Sr)$TiO_3$ was show $10^2$ jump order at 0.1 and 0.2 mole Sr addition, and PTCR of the sintered $(Ba_{0.7}Sr_{0.3})TiO_3$ does not appeared about 0.3 mole Sr addition, regardless of the sintering temperature and starting material size.

Mossbauer Studies of $Cu_{0.95}Ge_{0.95}Fe_{0.1}O_3$ (Mossbauer 분광법에 의한 $Cu_{0.95}Ge_{0.95}Fe_{0.1}O_3$의 연구)

  • 채광표;권우현;이영배
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.16-21
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    • 2000
  • Magnetic properties and crystallographic properties of $Cu_{0.95}Ge_{0.95}Fe_{0.1}O_3$ were studied by using x-ray diffraction, superconducting quantum interference device (SQUID) and Mossbauer spectroscopy. Our sample has orthorhombic structure and the lattice constants are a = 4.795 $\AA$, b = 8.472 $\AA$, c = 2.932 $\AA$. The spin-Peierls (SP) transition temperatures of our sample is 13 K. The Mossbauer spectra consisted with two Zeeman sextets and one doublet due to $Fe^{3+}$ions. The Zeeman sextets come from tetrahedral $Fe^{3+}$ions and the doublets come from octahedral $Fe^{3+}$ions. The jump up of magnetic hyperfine field of 2nd Zeeman sextet and the increasing of the values of quadrupole splitting and isomer shift of doublet below SP transition temperature could be interpreted related with the atomic displacements. The N el temperature is 715 K, the Debye temperature are 540 K for octahedral site and 380 K for tetrahedral site, respectively.

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Aerodynamic Measurement over a Protuberance in Hypersonic Flows Using Coaxial Thermocouple and TSP (동축열전대 및 TSP를 이용한 극초음속 유동 내 돌출물 주위 공력가열 계측)

  • Lee, Hyoung-Jin;Lee, Bok-Jik;Jeung, In-Seuck;Kim, Seong-Lyong;Kim, In-Sun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.10
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    • pp.967-974
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    • 2009
  • Experiments were conducted to measure the heat flux and temperature over a protuberance, using an impulse hypersonic shock tunnel-coaxial thermocouples and a blowdown hypersonic wind tunnel-temperature sensitive paints(TSP). Experimental data were compared with the heat flux data using a blowdown hypersonic wind tunnel-heat flux gauges and it was confirmed data sets agreed well. The measured heat flux is large when the height of the protuberance is large. Also, the heat flux measurements at the upper positions are larger than at the lower positions. For high protuberances, a severe jump in the heat flux is observed, from about 0.6~0.7 of the height of the protuberances. However, when the protuberance is sufficiently short, a rise in the heat flux is rarely observed as the protuberance is submerged totally under the separation region.

Anti-depressant Effect of the Extracts of Aconitum carmichaeli (부자(附子)의 우울증 억제효과에 관한 연구)

  • Chang, Moon-Kyoo;Kim, Geun-Woo;Koo, Byung-Soo
    • Journal of Oriental Neuropsychiatry
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    • v.20 no.3
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    • pp.49-64
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    • 2009
  • Objectives : The water and methanol extracts of Aconitum carmichaeli(Aconiti Tuber Preparat) were investigated for their anti-depressant effects. Methods : In this study, reserpine-induced hypothermia test, tail suspension test and hot plate test. Additionally, the brain monoamine oxidase activity was determined in vivo. Results: In the reserpine-induced hypothermia test, both extracts suppressed the fall of body temperature compared to the control group in a dose-dependent manner, suggesting the inhibition on hypothermia. In the tail suspension test, the methanol extract dose-dependently reduced the duration of immobility by 28.4% at a dose of 1 g/kg compared to control group, which is more effective than the water extract. In the hot plate test, the water extract and methanol extract increased the jump latency time compared to the control group, showing the inhibition rate of 198% and 182%, respectively, at a dose of 1 g/kg. Methanol extracts potently inhibited the brain monoamine oxidase activity in an in vivo assay compared to the control group, showing 84.6% inhibition, but the water extract revealed very weak activity. Conclusions : Above results suggested that the extract of Aconitum carmichaeli can be useful for the prevention and treatment of depression.

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Numerical computation of pulsed laser ablation phenomena by thermal mechanisms (열적 메커니즘에 의한 펄스레이저 어블레이션 현상의 수치계산)

  • Oh, Bu-Kuk;Kim, Dong-Sik
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1572-1577
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    • 2003
  • High-power pulsed laser ablation under atmospheric pressure is studied utilizing numerical and experimental methods with emphasis on recondensation ratio, and the dynamics of the laser induced vapor flow. In the numerical calculation, the temperature pressure, density and vaporization flux on a solid substrate are first obtained by a heat-transfer computation code based on the enthalpy method, and then the plume dynamics is calculated by using a commercial CFD package. To confirm the computation results, the probe beam deflection technique was utilized for measuring the propagation of a laser induced shock wave. Discontinuities of properties and velocity over the Knudsen layer were investigated. Related with the analysis of the jump condition, the effect of the recondesation ratio on the plume dynamics was examined by comparing the pressure, density, and mass fraction of ablated aluminum vapor. To consider the effect of mass transfer between the ablation plume and air, unlike the most previous investigations, the equation of species conservation is simultaneously solved with the Euler equations. Therefore the numerical model computes not only the propagation of the shock front but also the distribution of the aluminum vapor. To our knowledge, this is the first work that employed a commercial CFD code in the calculation of pulsed ablation phenomena.

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Nonlinear Behaviors of a Gas-filled Bubble Oscillator with Large Amplitude of Excitation (큰 압력 진폭에 의해 구동되는 기포진동체의 비선형 거동 특성)

  • 김동혁
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.116-124
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    • 2002
  • The bubble model by Keller and Prosperetti is adapted to solve the nonlinear oscillation of a gas bubble. This formulation leads to accurate results since it introduces the energy equation instead of the polytropic assumption for the bubble interior. The numerical method used in this study is stable enough to handle large amplitude of bubble oscillation. The numerical results show some interesting nonlinear phenomena fur the bubble oscillator. The excitation changes the natural frequency of the bubble and makes some harmonic resonances at $f/f_0=1/2, 1/3$ and so on. The natural frequency of a bubble oscillator decreases compared with the linear case result, which means that the nonlinear bubble oscillation system is a "softening"system. In addition, the frequency response curve jumps up or down at a certain frequency. It is also found that there exist multi-valued regions in the frequency response curve depending on the initial conditions of bubble. The dependency of the bubble motion on the initial condition can generate extremely large pressure and temperature which might be the cause of the acoustic cavitation and the sonoluminescence.inescence.

Effect of milling on the electrical properties of Ba(Fe1/2Ta1/2)O3 ceramic

  • Mahto, Uttam K.;Roy, Sumit K.;Chaudhuri, S.;Prasad, K.
    • Advances in materials Research
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    • v.5 no.3
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    • pp.181-192
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    • 2016
  • In this work effect of high energy milling on the structural and electrical properties of $Ba(Fe_{1/2}Ta_{1/2})O_3$ (BFT) ceramic synthesized using standard solid-state reaction method were investigated. X-ray diffraction studies indicated that the unit cell structure for all the samples to be hexagonal (space group: P3m1). FTIR spectra also confirmed the formation of BFT without any new phase. The milled (10 h) BFT ceramic showed the formation of small grain sizes (<$2{\mu}m$) which is beneficial for dielectric applications in high density integrated devices. Besides, the milled (10 h) BFT ceramic sample exhibited superior dielectric properties (enhancement in ${\varepsilon}^{\prime}-value$ and reduction in $tg{\delta}-value$) compared to un-milled one. Impedance analysis indicated the negative temperature coefficient of resistance (NTCR) character. The correlated barrier hopping model (jump relaxation type) is found to successfully explain the mechanism of charge transport in present ceramic samples.