• 제목/요약/키워드: Tape Casting

검색결과 226건 처리시간 0.024초

열전지용 FeS2 박막전극의 전기화학적 특성 (Electrochemical Properties of FeS2 Thin Film Electrodes for Thermal Batteries)

  • 임채남
    • 한국전기전자재료학회논문지
    • /
    • 제30권5호
    • /
    • pp.318-324
    • /
    • 2017
  • Powder compaction technology is widely used to prepare thermal battery components. This method, however, is limited by the size, thickness, and geometry of the battery components. This limitation leads to excessive cell capacity, overweight, and higher cost of the pellets, which decreases the specific capacities and delays the activation time of thermal batteries. $FeS_2$ thin-film cathodes were fabricated by tape-casting technology and analyzed by SEM and EDS in this paper. The residual organic binder of the $FeS_2$ thin-film cathodes decreased with the temperature of the heat treatment, which improved the specific capacity because of the lower resistance. Specific capacities of the $FeS_2$ thin-film cathodes decreased because of the higher residual binder and the restrictive reaction of active materials with molten salts as the thickness increased. $FeS_2$ thin-film cathodes showed much higher specific capacity (1,212.2 As/g) than pellet cathodes (860.7 As/g) at the optimal heat-treatment temperature ($230^{\circ}C$).

용융탄산염 연료전지의 양극 대체재료의 개발에 관한 연구 (A Study on the Development of Anode Material for Molten Carbonate Fuel Cell)

  • 황응림;김선지;강성군
    • 에너지공학
    • /
    • 제2권3호
    • /
    • pp.293-299
    • /
    • 1993
  • 용융탄산염연료전지(MCFC)용 다공성 Ni 양극에 3~10 wt% Al를 첨가하여 tape casting 법으로 제조된 Ni-Al 양극의 전기화학적성능 및 구조적안정성이 조사되었다. 본 연구에서 제조된 양극의 전기화학적 성능이 $650^{\circ}C$, MCFC 양극분위기(80% H$_2$+20% $CO_2$)를 모사한 half-cell 에서 양분극 특성으로 평가되었는데, 전류밀도 150 ㎃/$\textrm{cm}^2$ 에서의 분극전압은 약 100 ㎷로 실용전지의 양극으로서 가능성을 보였다. Ni-Al 양극의 소결과 creep에 대한 저항성은 Ni 양극에 비해 증가되었는데, 이는 Ni 입자 표면에 형성된 $Al_2$O$_3$의 영향으로 판단되었다.

  • PDF

PZT/Metal로 구성된 음향변환기의 음향특성에 관한 연구 (A Study on the Acoustic Properties of Acoustic Treansducer with PZT/Metal)

  • 김진수;강대하;김소정;김호기;이덕출
    • 한국음향학회지
    • /
    • 제11권2호
    • /
    • pp.28-37
    • /
    • 1992
  • 본 연구에서는 압전 특성이 우수한 PZT계 압전세라믹스를 원판상으로 박판화하여 금속 진동판에 부착시킨 PZT/Metal음향변환기를 제작하였다. 이 때 압전 세라믹스를 박판화하기 위해 'tape casting 방법‘을 사용했으며, 제작된 PZT/Metal 음향 변환기를 압전 부자, 압전 스피커등의 소자에 응용 시키기 위해 음향특성을 연구하였다. 연구 결과, 세라믹스의 압전 계수($d_{31}$)이 증가함에 따라 레벨(dB)이 -6dB에서 - 14dB로 증가된다. 음향 변환기의 직경비 ${\eta}$가 0.7-08이고, 두꺼비 (${\beta}$)가 1일 때 최적 음압 특성을 나타냈으며, 음압은 -15~-16dB정도이었다.

  • PDF

Slurr법에 의한 $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$계 미분말의 성형과 소결성 (Shaping and Sintering of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ System powders by Slurry Process)

  • 김복희;최석홍
    • 한국세라믹학회지
    • /
    • 제33권11호
    • /
    • pp.1267-1275
    • /
    • 1996
  • Green sheet was prepared by tape casting in the composition of (1-x)Pb(Mg1/3Nb2/3)O3-PbTiO3 system using Pb(Mg1/3Nb2/3)O3 and PbTiO3 synthesized with PbO, Nb2O5 MgO and TiO2 The densest green sheet was obtained in the weight ratio 70:30 of powder to binder. Green sheet wasmultilayered in metal mould and formed into lamination at 7$0^{\circ}C$, 300kg/cm2 The lamination was sintered at 110$0^{\circ}C$ 2hr, Dielectric constant and Curie temperature of disc type sintered body was highered with increasing the amount of PbTiO3 and was in the range of 19000-21000, -7~45$^{\circ}C$ respectively. Green and sintered relative density of lamination was 61% and 95% respectively.

  • PDF

세라믹 그린 쉬트의 두께제어를 위한 유기물 첨가제 조성에 관한 연구 (Study on the Composition of Organic Additives for Thickness Control of Ceramic Green Sheets)

  • 김준영;유명재;박종철
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
    • /
    • pp.184-184
    • /
    • 2008
  • 저온 동시 소성 세라믹(LTCC, Low Temperature Co-firing) 기술 중에서 테이프 캐스팅(tape casting)은 얇고 균일한 세라믹 그린 쉬트를 연속 성형할 수 있으며 성형된 쉬트의 밀도, 표면상태, 두께제어 등이 매우 중요하다. 얇고 균일한 세라믹 그린 쉬트를 제작하기 위해서 슬러리의 분산성과 레오로지 특성은 매우 중요한 요소이며 첨가되는 유기물 첨가제들의 종류와 함량비는 슬러리의 분산성과 점도에 큰 영향을 미친다. 본 연구에서는 유기물 첨가제의 종류와 함량에 따른 슬러리의 점도와 그린 쉬트의 밀도 및 두께 제어에 미치는 영향을 고찰하였다. 바인더로는 acryl, polyvinyl 계를 사용하였으며, 가소제는 glycol, phatalate 계를 사용하였다. 각각 2 종류의 바인더와 가소제의 함량에 따른 레올로지 거동과 그런 쉬트의 밀도를 측정하였다. 각 조성별로 준비된 슬러리를 사용하여 테이프 캐스팅 방법으로 제작된 그린 쉬트의 두께를 측정하여 유기물 첨가제 조성이 그린 쉬트의 두께제어에 미치는 영향을 평가하였다.

  • PDF

Pb(Mg1/3Nb2/3)O3-PbTiO3계의 조성변화에 의한 다층 콘덴서 물성 (Properties of Multilyer Condensor with Composition Change in the System of Pb(Mg1/3Nb2/3)O3-PbTiO3)

  • 김복희
    • 한국세라믹학회지
    • /
    • 제35권2호
    • /
    • pp.123-128
    • /
    • 1998
  • Multilayer ceramic capacitors(MLCC) were prepared by laminating the layer of composition with dif-ferent Curie temperature to improve temperature coefficient in the Pb(Mg1/3Nb2/3)O3-PbTiO3 binary system. Green sheet was formed by tape casting using Pb(Mg1/3Nb2/3)O3-PbTiO3 and PbTiO3 synthesized with solid state reaction of PBO. Nb2O5 MgO and TiO2. Green sheet with electrode of 70Ag-30Pd was laminated under 300 kg/cm2 at 70$^{\circ}C$ and sintered at 1100$^{\circ}C$ for 2hr. Curie temperatues for MLCC with 10 layers of pure PMN and 0.9PMN-0.1PT were lowered to -22$^{\circ}C$ and 36$^{\circ}C$ respectively. MLCC with 7 layers of PMN and 3 layers of 0.9PMN-0.1PT showed nearly zero temperature coefficient of capacitance in the range of -20∼30$^{\circ}C$ and sum of dissipation factor of each layer.

  • PDF

첨가물에 따른 $(Ba_{0.6}Sr_{0.4})TiO_3$의 저온소결 및 유전특성 (Low Temperature Sintering and Dielectrics Properties of $(Ba_{1-x}Sr_x)TiO_3$ Ceramics by Addition)

  • 전소현;김인성;송재성;민복기;윤존도
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
    • /
    • pp.202-203
    • /
    • 2005
  • To recognize whether admixture affects some $(Ba_{0.6}Sr_{0.4})TiO_3$, powder in this research $Li_2CO_3$, MgO, $MnO_2$ adding each 3 wt % by Tape casting method thick film make. Sitering temperature lowered 1300$^{\circ}C$ adding $Li_2CO_3$, and density is 5.942g/$cm^3$, and specific inductive capacity increases about decuple and displayed 4000. Climbed sitering temperature 1400$^{\circ}C$ adding MgO, specific inductive capacity reduced 1/2 times. Lowered sintering temperature 1325$^{\circ}C$ low adding $MnO_2$.

  • PDF

PDP 무연 투명유전체 후막의 형성 및 특성 (The Fabrication and Properties of Lead-tree Transparent Dielectric Thick Films for PDP)

  • 허성철;최덕균;오영제
    • 한국전기전자재료학회논문지
    • /
    • 제17권10호
    • /
    • pp.1107-1113
    • /
    • 2004
  • Dry film method for large size of PDP(Plasma Display Panel) module has been actively investigated. This method for lead-free transparent dielectric formation depends on green sheet technology. By adjusting the composition of transparent dielectric powders and organics, uniformly dispersed slurry was fabricated, Viscosity of the slurry exhibited pseudoplastic behavior for tape casting, Cast green sheets were tested under tensile condition at room temperature. It was found that the increase in transparent dielectric powder and binder ratio leads to decrease in strain to failure of green sheets from 120 % to 34 % and from 255 % to 4 %, respectively. Tensile strength of green sheets decreased abruptly with increase of transparent dielectric powder ratio, with minimum at 0.13 MPa. On the other hand, tensile strength increased continuously from 0.1 MPa to 2.4 MPa with increase of binder ratio. The green sheets were attached on the glass substrate and heated by following firing schedule. As a result, the best result was obtained when fired at 580 $^{\circ}C$ for 15 min and had transmittance of 78 % in visible range 550 nm.

나노 탄화규소(SiC) 슬러리로 코팅된 메타-아라미드 직물의 특성 (Characteristics of Meta-aramid Fabrics Coated with Slurry of Nanoscale SiC Particles)

  • 박종현;이선영;원종성;이응보;김의화;이승구
    • 한국염색가공학회지
    • /
    • 제29권3호
    • /
    • pp.131-138
    • /
    • 2017
  • Most of high performance fabrics for the car racing protective clothing have been developed to have thermal resistance, flame retardant property, impact resistance and anti-frictional properties to protect the racer from the crucial accident. In this study, the meta-aramid fabric, which has inherent flame retardant, was coated with nanoparticles of SiC to enhance the impact resistance and anti-friction properties. Uniform coating of the nanoparticles onto the fabrics was obtained by using tape casting method. As the experimental parameters, size and content of the SiC nanoparticle were varied with the coating conditions of the fabric surface. The effects of the nanoparticle coating on the properties of meta-aramid fabric were examined with various instrumental analyses such as SEM, tensile strength and abrasion test.

의료용 폴리우레탄 Pre-polymer의 중합공정 최적화 (Process Optimization of Polyurethane Pre-polymer for Medical Application)

  • 허광태;구양;하만경;곽재섭
    • 한국금형공학회:학술대회논문집
    • /
    • 한국금형공학회 2008년도 하계 학술대회
    • /
    • pp.203-208
    • /
    • 2008
  • Recently, the modern society in development and industrial growth is investing a lot of time and much effort to improvement and environment of life quality. Thus, the casting tape which uses environmentally friendly and human body friendly water hardening process Polymer is rapidly substituted for the gypsum cast product which has been plentifully used in medical treatment. Until currently, prior researches have a tendency to focusing the analysis about chemical creation expense and reaction quality rather than the issue about optimization of the process for this polymerization. In the polymerization process which has been accomplished with actual same chemical creation expense, there has been a problem which is the possibility of getting a different result. This is because the optimization of respectively control factors is not accomplished which affect at polymerization process. Therefore, this research sees the chemical qualities of casting tape Polymer, consequently selects the polymerization process which is suitable. And, by using a experimental design, this research will evaluate the affects which the respective factors have on remaining NCO and viscosity. futhermore, this research will carry out the process optimization which can get the above results.

  • PDF