• 한국대기환경학회지
• /
• 제10권3호
• /
• pp.191-196
• /
• 1994

Concentration of particulate nitrate originated from sea salt in ambient air was determined from February to October 1993. Sampling was carried out using a two-stage Anderson air sampler at the top of a five-story building located at Kon-Kuk University in Seoul. Concentration of NaNO$_3$, which originated from sea salt was highest in spring time and lowest in summer the and the concentration range was between 0.10 and 0.66 $\mu\textrm{g}$/㎥. NaNO$_3$/TSP ratio was very low 0.05~0.39%) indicating that the portion of NaNO$_3$ in TSP was negligible.

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2001년도 추계학술대회 논문집
• /
• pp.245-246
• /
• 2001

우리나라에서는 지금까지 대기 오염과 관련하여 환경기준 달성을 위한 정책수립에 있어서 대상물질은 주로 이산화황(SO$_2$)과 먼지(TSP) 등으로 경제개발과 산업발전과정 등에서 발생되는 오염물질이었다. 그러나 최근 몇 년사이 급격한 자동차의 증가로 인한 이산화질소(NO$_2$)와 휘발성유기화합물(VOCs)의 배출이 증가하고 있어 환경규제정책도 점차 변하고 있는 실정이다. 이러한 오염물질들이 대기중에서 태양복사에너지에 의해 광화학 반응을 일으켜 오존(ozone), PAN(peroxyacethyl nitrate), PBN(peroxy benzoyl nitrate), 아크로레인(carolein), 포름알데히드(HCHO, formaldehyde) 등 광화학 산화제를 생성하여 인체, 동ㆍ식물 및 재산상의 피해를 유발하고 있다. (중략)

• 한국환경보건학회지
• /
• 제22권4호
• /
• pp.55-61
• /
• 1996

Measurements of the seasonal variations of concentration and size distribution of TSP, $SO_4^{2-}, NO_3^-, Cl^-, NH_4^+, Na^+, K^+, Ca^{2+}$ and $Mg^{2+}$ were made by Andersen air sampler from May 1995 to April 1996 in Seoul. The size distribution of these ions was divided into four patterns. 1) Distribution was concentrated on fine particles over a year such as $NO_3^-$ component, 2) Distribution was predominated in coarse particles fraction over a year such as $Mg^{2+}$ and $Ca^{2+}$ components, 3) Distribution was differerent from various seasons such as $NH_4^+, SO_4^{2-}, Cl^-$ and $K^+$ components, 4) Distribution was bi-modal such as $Na^+$.

• 한국대기환경학회지
• /
• 제12권3호
• /
• pp.289-296
• /
• 1996

Effects of crustal species on the characteristics of ambient particles were studied by applying a gas-particle equilibrium model, SCAPE, to the measurements at Kosan, Cheju Island during the spring and summer, 1994. Two cases were simulated; the measured composition was used without any modification (case 1), and the metal ion concentrations originated from crust were subtracted from the measured particle composition (case 2). Total suspended particles (TSPs) were collected by an automatic high volume tape sampler during spring period and by high volume samplers during summer period. The fine particles, PM 2.5, and gaseous volatile species were collected using a filter pack smapler during summer period. The water soluble ion concentrations were analyzed from all the particle samples. According to the simulation results, the effect of crustal elements on the chemical composition of particles is negligible for both TSP particles and PM 2.5 particles. Acidity of particles measured at Kosan, however, is affected by the change of the concentrations of crustal species, stronger effects for TSP particles than for PM 2.5 particles during summer, and stronger effects during summer than spring for TSP particle. The average pH decrease due to the absence of crustal species was about 0.10 for PM 2.5 particle during summer and 1.51 and 0.85 for TSP particles during summer spring, respectively. Water contents of PM 2.5 particles for both cases are comparable to each other. Estimated water content of TSP particles for case 2 is higher than that for case 1 by about 4 $\sim 6 \mum/m^3$ because salts of metal ions are not hygroscopic.

• 한국지구과학회지
• /
• 제24권4호
• /
• pp.315-324
• /
• 2003

서울시에서 설치하여 운영중인 대기질 측정소의 입자상물질을 대표하는 PM$_{2.5}$, PM$_{10}$, TSP와 황사기간 중 고용량고기포집기로 채취한 먼지성분을 분석, 평가하였다. 1990년도부터 2002년 11월까지 서울에서 관측된 황사일수는 2000년 이후 발생빈도가 증가하였으며 황사지속시간도 길어지는 경향을 보였다. PM$_{10}$/TSP 비율은 황사시 2000년, 2001년도에 각각 52.9%, 59.4%로 비황사시에 비해 PM$_{10}$의 비율이 약 10% 정도 낮은 것으로 미루어 황사시 10 ${\mu}$m이상의 입경이 큰 입자 영향이 컸던 반면에 2002년 황사시에는 PM$_{10}$의 영향이 오히려 크게 나타나 PM$_{10}$이 TSP 중의 71.4%에 달하였다. 황사가 전체 먼지농도에 미치는 기여율은 2002년도에 PM$_{2.5}$ 11.9%, PM$_{10}$ 23.1%, TSP 19%로 가장 높은 기여도를 보여 황사가 전체 면지농도에 미치는 영향이 매우 크다는 것을 알 수 있었다.

• 한국산학기술학회논문지
• /
• 제9권5호
• /
• pp.1349-1353
• /
• 2008

충청남도, 천안시 대기 에어로졸의 입경별 농도 및 이온성분 특성을 분석하고자, 2006년 3월부터 2007년 4월까지 천안시 상명대학교에서 Cascade Impactor를 장착한 High Volume Air Sampler를 이용하여 대기 시료를 채취 분석하였다. 입경별 에어로졸의 일평균농도는 TSP, PM10, PM2.5, PM1이 각각 61.7, 55.2, 43.7, $33.2{\mu}g/m^3$였으며, 직경이 $1{\sim}3{\mu}m$인 영역을 경계로 조대영역과 미세영역으로 나누어지는 전형적인 도심지 특성을 나타냈다. 이 중 미세영역입자인 PM2.5이 전체 에어로졸의 70.8%를 차지하였다. 이들 에어로졸 입자의 성분 분석 결과 양이온은 ${NH_{4}}^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$이, 음이온은 ${SO_{4}}^{2-}$, ${NO_{3}}^-$, $Cl^-$가 주요 성분이었으며, 이들 수용성 이온이 차지하는 비율은 조대입자에서 37.4%, 미세입자에서 46.2%였다.

• 한국환경과학회지
• /
• 제5권4호
• /
• pp.453-462
• /
• 1996

This study was conducted to evaluate the level of atmospheric heavy metals and the relationship of that concentration with weather conditions. This research monitored the concentration of Total Suspended Particulates (TSP) at every three hours by using High Volume Air Sampler from December 24th, of 1995 to Febuary 20th, 1996 in Kimhae area, which recently became a rapidly growing residential and industrial sitc. The items such as air-temperature, relative humidity, radition, wind speed, and wind direction were monitored by using Atmospheric Weather System at the same time. From the collected TSP, the concentration of heavy metals were analyzed by using the Atomic Absorption Spcetrophotometry. The mean concentration of TSP was 110.4 $\mu\textrm{g}$/$m^3$, and the mean concentration of lead (Pb), copper(Cu), chromium (Cr), manganese (Mn), cadmium (Cd), were 0.837 $\mu\textrm{g}$/$m^3$, 0486 $\mu\textrm{g}$/$m^3$, 0.264$\mu\textrm{g}$/$m^3$). The concentration of Pb and Mn was higher in the moring and that of Cu, Cr and Cd was higher in the afternoon and the evening. Regarding the relationship between the concentration of pollutants and weather condition, the-concentration TSP revealed positive correlation with temperature, humidity, wind speed, but negative correlation with tradition (p<0.01). The concentration of Mn revealed positive correlation with temperature and humidity, but negative correlation with wind speed (p<0.01). And the the concentration of pollutants and weather condition revealed higher correlation within the same time period. In summary, the paralleled mornitoring of air conditions and weather condition should be recommended to. get the correct informations concerning the pollution and to prevent the deterioration of air conditions.

• 한국대기환경학회지
• /
• 제34권2호
• /
• pp.233-243
• /
• 2018

This study was carried out to characterize the ambient levels of PAH concentrations in Pohang city, where steel industry has been intensively developed. A large amount of PAH emissions from steel production and related industries in Pohang are concerned about the environmental health hazards of nearby residents. TSP samples were seasonally collected during 10 days at four sites in Pohang from April to December 2010. Each sample was collected for 24 hours using high-volume air sampler. All samples were extracted by $soxtec^{TM}$ before concentration of 1.0 mL. The concentrates were analyzed by GC/MS. The prevailing wind direction was southwest and west-southwest in Pohang during the measurement period. Variations of TSP concentrations appeared to be similar between four sites. The highest TSP concentration was found in fall, while the lowest in summer. The highest PAH concentration was found at an industrial site, while the lowest at a residential/commercial site. In the case of BaP, the average concentration at the industrial site was $0.63{\pm}0.66ng/m^3$, which was approximately 2 times of the residential/commercial site. The paired t-test (p<0.05) showed significant differences between industrial and residential area. Particulate PAH concentrations were higher in the winter and lower in the summer. The concentrations of BaP in winter were 2~10 times higher than those in the other three seasons. This study clearly demonstrated the impact of steel industry on the elevated levels of PAH in Pohang city.

• 한국대기환경학회지
• /
• 제4권1호
• /
• pp.79-83
• /
• 1988

To improve working environment for the toll workers who were working at Kyungbu expressway in outskirts of Seoul and Suwon, the status of air pollution surrounding toll booth were measured from March 28 through June 14, 1986. The results were as follows: 1. The amount of TSP (total suspended particle) surrounding toll booth was directly proportional to the traffic load. The ratio of traffic load at Seoul and Suwon toll was 3.2:1 and of TSP was 2.6:1. 2. The proportion of particle larger than 5$\mum$ was 24.8 $\sim$ 34.9% of TSP at Seoul toll and 19.2 $\sim$ 32.7% at Suwon. The proportion of particle less than 2$\mum$ was 38.7 $\sim$ 51.8% of TSP at Seoul toll and 34.8 $\sim$ 54.8% at Suwon. 3. The concentration of respirable particle les than 7$\mum$ measured by personal air sampler was higher in Seoul toll booth than that of Suwon and it seems to be influenced by the exhausion of diesel engine. Especially the concentration of respirable particle of reformed toll booth with air curtain was 20% lower than unreformed one. 4. Concentration of Pb among suspended particles around Seoul toll was 5 times higher than Pb of Suwon toll. So it is considered that there were other possible pollution source of Pb beyond heavy traffic in Seoul toll area. The amount of Pb inside toll booth was extremely small but the concentration of benzo(a)pyrene showed a trend of increase according to traffic stagnation. 5. The concentration of $SO_2$ arround toll showed no difference between weekday and weekend and also showed no relation with traffic load. But the concentration of $NO_2$ was affected by traffic load.

• 한국대기환경학회지
• /
• 제11권1호
• /
• pp.37-44
• /
• 1995

Concentration of particulate nitrate classified by formation mechanism and particle diameter in ambient air was determined from Feb. to Oct. 1993. Sampling was carried out using a two-stage Andersen air sampler at the top of a five-story building located at Kon-Kuk University in seoul. Concentration of N $H_{4}$N $O_{3}$ in TSP was measured by pyrolysis of sample filters at 160.deg.C for 1hr. concentration of N $H_{4}$N $O_{3}$ was higher in winter time compared with that in summmer time. Also, concentration of N $H_{4}$N $O_{3}$ was higher in fine particles compared with that in coarse particle. The range of N $H_{4}$N $O_{3}$ concentration was between 2.9 and 9.9.mu.g/ $m^{3}$. Weight fraction of N $H_{4}$N $O_{3}$ in total particulate nitrate was 31.1 .sim. 59.5%, and weight fraction of N $H_{4}$N $O_{3}$ in TSP was 2.1 .sim. 11.2%. Concentration of NaN $O_{3}$, which originated from sea salt, was highest in spring time and lowest in summer time,and the concentration range was between 0.1 and 0.7.mu.g/ $m^{3}$. NaN $O_{3}$/TSP ratio was very low (0.1 .sim. 0.4%) indicating that the portion of NaN $O_{3}$in TSP was negligible. Concentration of particulate nitrate originated from soil was 2.4 .sim. 2.9.mu.g/ $m^{3}$. Weight fraction of that in total particulate nitrate was 14.0 .sim. 37.1%.