• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.24 no.4
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• pp.535-547
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• 2019

In this study, the heavy metal analysis in sediments (surface sediments, sediments cores and settling particles) from Shihwa Lake has been carried out to evaluate the changes of metal pollution levels in sediments after the operation of Tidal Power Plant (TPP). The average concentrations of metals in surface sediments sampled in 2015 were 8% (Cd)~31% (Zn, Hg) lower than in 2009 before TPP operation. Results of calculating the pollution load index (PLI) with 8 metals, the PLI value in 2015 showed a 18% decrease compared to 2009. However, Cu, Zn, Pb concentrations of surface sediments in 2015 at the upper region around industrial complex still exceeded the TEL (threshold effect level) values for sediment quality guideline in Korea. After the operation of TPP, the metal contaminated depths were increasing from 15 cm to 30 cm at S6 site and from 8 cm to 20 cm at S7 site, respectively. Our data showed that the mean concentration of heavy metals in core samples decreased but the contaminated depth increased. The average of the total sedimentation flux for particulate matter increased by 3.2 times from 32.5 g/㎡/d in 2009 to 103.5 g/㎡/d in 2015. This showed that the bottom sediments were resuspended by the operation of TPP, resulting in an increase of particulate matter in the water column. These results suggest that the sediments contaminated with heavy metals seem to be resuspended and relocated due to the water current caused by the operation of TPP. Cr, Cu, Zn, Pb and Cd were highly exceeding the TEL values in the upstream region and accumulated more than 40 cm of sediment depth, indicating that heavy metal contamination through industrial activity were still a serious environmental problem of Shihwa Lake. Although the metal pollution of Shihwa Lake has been slightly reduced, the contaminated sediments with heavy metals inside of Shihwa Lake might be discharged to outer sea after the resuspension by TPP operation. It is necessary for the advanced scientific approach and political decision to drastically reduce the heavy metal pollution of the study region.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.836-842
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• 2013

In this paper, the 20 kW Ocean Thermal Energy Conversion(OTEC) is newly proposed in order to select the refrigerant that makes the cycle performance be optimized and the performance of 20 kW OTEC applying 15 pure refrigerants and 16 mixed refrigerants is analyzed. The efficiency of system, the mass flow of working fluids and TPP, which is new concepts, are analyzed. In view of cycle efficiency, R32/R152a (87:13) is the highest efficiency among the refrigerants. At the mass flow of working fluid to make the 20 kW electricity, R717 is shown as the lowest value. And in view of TPP in this study, R32/R134a 70:30 is the most optimized refrigerant. The analysis can confirm that the refrigerant is different along with the part of the system, so it is necessary to select the optimized refrigerant for 20 kW OTEC.

• Fire Science and Engineering
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• v.32 no.1
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• pp.81-88
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• 2018

Air and ultra lightweight aerogels were used to lighten the weight of the firefighters' protective clothing. In order to lighten the firefighters' protective clothing composed of 3 layers (outer shell, mid-layer, lining), it was most effective to replace the lining which occupied the largest weight in the total weight with the new materials. Thermal protective performance tests were carried out on flame (ASTM D 4108), radiant heat (KS K ISO 6942) and mixing heat (KS K ISO 17492) of flame and radiation. When the lining felt was replaced with an air layer, the air layer must be at least 3 mm to meet the KFI and ISO standards for the thermal protective performance. However, even if the thickness of the air layer increased to 10 mm, the thermal protective performance was lower than that of the existing products. When the felt was replaced with aerogels, the TPP rating (ASTM D 4108) satisfied the KFI standard at the 2 mm thickness of the aerogels. When the thickness of the aerogels was 3 mm, the TPP rating was improved about 140% compared to the existing products. It was confirmed that not only weight reduction but also thermal protective performance was improved by use of aerogels. However, due to the fragile nature of aerogels, a method of fixing them to a constant thickness between layers constituting a firefighters' protective clothing should be considered in the future.

• Polymer(Korea)
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• v.29 no.6
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• pp.571-574
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• 2005

The aromatic hyperbranched polyamide was synthesized from 5-aminoisophthalic acid by direct polycondensation with triphenylphosphite (TPP) catalyst as a condensing agent. The modification of end-groups in the resulting hyperbranched polymer (HBP) with various alkyl alcohols were conducted. The modification of end-groups of HBP by alkyl groups resulted in an improved solubility in the THF comparing to that of the carboxylic acid-terminated aromatic HBP, Also, 10 wt$\%$ weight loss temperature decreased by increasing the length of alkyl group.

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.801-806
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• 2003

Pseudomonas sp. BCNU 106 accumulated approximately 4.12 mM trehalose after cultivation of 12 hr probably by the arising action of trehalose-6-phosphate synthase/phosphatase. The cDNA clones of trehalose-6-phosphate synthase/ phosphatase were isolated from Pseudomonas sp. BCNU 106, and named as PsTPS and PsTPP(Pseudomonas sp. BCNU 106 trehalose-6-phosphate synthase/phosphatase). The two mRNA levels of trehalose-6-phosphate synthase/ phosphatase peaked at 12 hr after exposure to toluene, and thereafter were declined slightly These results support an important role of trehalose accumulation by expressions of PsTPS and PsTPP in toluene-tolerance of Pseudomonas sp. BCNU 106.

• Journal of the Korean Society for Precision Engineering
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• v.24 no.12
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• pp.136-142
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• 2007

Precise fabrication of three-dimensional (3D) self-standing microstructures on thin glass plates via two-photon induced polymerization (TPP) has been an important issue for innovative 3D nanodevices and microdevices. However, there are still issues remaining to be solved, such as building 3D microstructures on opaque materials via TPP and being able to implant them as functional parts onto practical systems. To settle these issues simply and effectively, we propose a contact print lithography (CPL) method using an ultraviolet (UV)-curable polymer layer. We report some of the possibilities and potential of CPL by presenting our results for transplanting 3D microstructures onto large-area substrates and also our examination of some of the effects of the process parameters on successful transplantation.

• East Asian Economic Review
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• v.21 no.4
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• pp.343-384
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• 2017

We assess the outcomes for the negotiating parties in the Trans-Pacific Partnership if the remaining eleven parties go ahead with the agreement as negotiated without the United States, as compared to the outcomes under the original twelve-member agreement signed in October 2016. We find that the eleven-party agreement, now renamed as the Comprehensive and Progressive Agreement for Trans-Pacific Partnership (CPTPP), is a much smaller deal than the twelve-party one, but that some parties do better without the United States in the deal, in particular those in the Western Hemisphere - Canada, Mexico, Chile, and Peru. For the politically relevant medium term, the United States stands to be less well-off outside the TPP than inside. Since provisional deals can be in place for a long time, the results of this study suggest that the eleven parties are better off to implement the CPTPP, leaving aside the controversial governance elements, the implications of which for national interests are unclear and which, in any event, may be substantially affected by parallel bilateral negotiations between individual CPTPP parties and the United States.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.2
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• pp.95-101
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• 2010

For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

• Earthquakes and Structures
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• v.18 no.5
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• pp.581-598
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• 2020

This paper aims to investigate the seismic behavior and influence parameters of the large-scaled thin-walled reinforced concrete (RC) tubular columns in air-cooled supporting structures of thermal power plants (TPPs). Cyclic loading tests and finite element analysis were performed on 1/8-scaled specimens considering the influence of wall diameter ratio, axial compression ratio, longitudinal reinforcement ratio, stirrup reinforcement ratio and adding steel diagonal braces (SDBs). The research results showed that the cracks mainly occurred on the lower half part of RC tubular columns during the cyclic loading test; the specimen with the minimum wall diameter ratio presented the earlier cracking and had the most cracks; the failure mode of RC tubular columns was large bias compression failure; increasing the axial compression ratio could increase the lateral bearing capacity and energy dissipation capacity, but also weaken the ductility and aggravate the lateral stiffness deterioration; increasing the longitudinal reinforcement ratio could efficiently enhance the seismic behavior; increasing the stirrup reinforcement ratio was favorable to the ductility; RC tubular columns with SDBs had a much higher bearing capacity and lateral stiffness than those without SDBs, and with the decrease of the angle between columns and SDBs, both bearing capacity and lateral stiffness increased significantly.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2656-2664
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• 2010

We have synthesized a series of push-pull porphyrins containing both donor and acceptor substituents at the mesopositions and have examined their spectral and biological properties. The push-pull porphyrins containing both strong donor $NH_2$ and acceptor $NO_2$ at meso-positions, in which donor group condensed with the ligand, (2,6-bis(4-methylpiperazine-1-yl-methyl)-4-formlyphenol (L) to form imine linkages with porphyrin. The Schiff base ligand 5-[4-(2,6-bis(4-methylpiperazine-1-yl-methyl)-4-iminomethylphenol)phenyl]-10,15,20-tris(4-nitrophenyl) porphyrin [$an_3$(TPP)L] can be synthesized from 2,6-bis(4-methylpiperazine-1-yl-methyl)-4-formylphenol (L) and 5-(4-aminophenyl)-10, 15,20-tris(4-nitrophenyl)porphyrin. The push-pull porphyrin [$an_3$(TPP)L] was metallated to get copper, nickel and zinc complexes. The spectral, electrochemical, antibacterial, antifungal and cytotoxicity properties of all the donor- acceptor push-pull porphyrins and their complexes were characterized and studied.