• Title/Summary/Keyword: TMSP

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High Voltage Performance of the Electrical Double Layer Capacitor with Various Electrolytes (다양한 전해액을 적용한 전기이중층 커패시터의 고전압 특성 연구)

  • Kim, Jung Wook;Choi, Seung-Hyun;Kim, Jeom-Soo
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.34-40
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    • 2017
  • Electric double layer capacitors (EDLC: electric double layer capacitors) have drew attention as an energy storage device for the next generation because of their outstanding power capability and durability. But their usage is somewhat limited due to low energy density over secondary batteries. One of methods to improve the energy of EDLC is expanding the voltage window of cell operation by increasing the charge cut-off voltage. In this study, $SBP-BF_4$ (spirobipyrrolidinium tetrafluoroborate), $TEA-BF_4$ (tetraethylammonium tetraflouroborate) and $EMI-BF_4$ (1-ethyl-3-methylimidazolium tetrafluoroborate) in AN (acetonitrile) were selected to evaluate the possibility of application at high voltage environment. The LSV (linear sweep voltammetry) measurements showed that the 1.5M SBP-BF4/AN electrolyte was stable over a wide potential window and showed the best electrochemical performance compared to other combinations of electrolytes at high voltage environments (over 3.0 V). Furthermore, TMSP (tris(trimethylsilyl) phosphite) was applied to 1.5M SBP-BF4/AN in order to maintain stable performance at high voltage for the long period of time. The electrolyte with TMSP additive showed the capacity retention of 93% after 10,000 cycles at 3.3 V.

Development of Pressure Sensitive Paint(PSP) technique for low-speed flows and its application (아음속 저속 유동용 Pressure Sensitive Paint의 개발과 응용)

  • Kang, Jong-Hoon;Lee, Sang-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.4
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    • pp.12-17
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    • 2004
  • The PSP technique has been used to measure pressure distribution on model surfaces ins high-speed flows. The objective of this study is to develop a PSP technique which can be applied to low-speed aerodynamic flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was evaluated. In a static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The developed PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

Electromagnetic Analysis of ACPD Method Using Eddy Current Induction (와전류를 이용한 교류전위강하법의 전자기적 해석)

  • Lim, Geon-Gyu;Lee, Hyang-Beom;Lee, Dal-Ho
    • 한국정보통신설비학회:학술대회논문집
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    • 2007.08a
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    • pp.231-234
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    • 2007
  • 와전류를 이용한 전위강하법은 시험체에 와전류를 비 접촉식으로 발생 시킬 수 있어 기존의 방식에 비해 결함 검출시 발생하는 오차를 줄일 수 있고 물체의 결함 검출신호의 신뢰성을 향상 시킬 수 있다. 본 논문에서는 와전류를 이용한 전위강하법의 전자기 유한요소해석을 수행하였다. 3차원 유한요소해석과정에서 해석시간을 단축시키기 위해 각 영역별로 MVP, ESP, RMSP, TMSP의 미지수 변수를 부여하여 유한요소해석을 수행하였다. 기존의 전위강하법에 와전류의 개념을 적용하기 위해서 주파수에 대한 결함 깊이의 영향과 결함에 대한 주파수에 대한 영향을 검토해본 결과 결함의 깊이가 깊어질수록 또한 높은 주파수에서 신호의 크기가 선형적으로 증가하는 패턴을 보였다. 연구결과 와전류를 이용하여 ACPD법을 시행할 경우 데이터 처리 과정과 실험 장비를 단순화 시킬 수 있어 결함 검사를 손쉽게 할 수 있을 것이라 예상된다.

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Dependence of Growth Temperature on MFI Zeolite Membrane Growth (성장온도의 변화에 따른 MFI Zeolite Membrane의 성장 특성 분석)

  • Kim, Duk-Eun;Ko, Chang-Hyun;Oh, Weon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.4
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    • pp.355-359
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    • 2009
  • Si wafer, which was treated with TMSP-TBA (N-trimethoxysilylpropyl-n,n,n-tri-n-butylammonium bromide), was used foF a substrate to grow a MFI membrane. Growth of membranes was conducted in various conditions such as temperature and gravity, and their structures were in detail studied with field emission scanning electron microscope and x-ray diffractometer. The structures of membranes grown on substrates were strongly dependent on growing temperature and gravity.

Development of Pressure Sensitive Paint (PSP) Technique for Low-speed Flows and Its Application (저속 유동용 Pressure Sensitive Paint 기술개발과 응용)

  • Kang, Jong-Hun;Lee, Sang-Joon
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.688-693
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    • 2003
  • The PSP technique has been used to measure pressure distribution on a model surface quantitatively. The objective of this study is to develop PSP technique which can be applied to low-speed flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was checked. In the static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

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Electromagnetic Analysis of ACPD Method Using Eddy Current Induction (와전류를 이용한 교류전위강하법의 전자기적 해석)

  • Lim, Geon-Gyu;Lee, Hyang-Beom
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.888-889
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    • 2007
  • 와전류를 이용한 전위강하법은 시험체에 와전류를 비접촉식으로 발생 시킬 수 있어 기존의 방식에 비해 결함 검출시 발생하는 오차를 줄일 수 있고 물체의 결함 검출신호의 신뢰성을 향상 시킬 수 있다. 본 논문에서는 와전류를 이용한 전위강하법의 전자기 유한요소해석을 수행하였다. 3차원 유한요소해석과정에서 해석시간을 단축시키기 위해 각 영역별로 MVP, ESP, RMSP, TMSP의 미지수 변수를 부여하여 유한요소해석을 수행하였다. 기존의 전위강하법에 와전류의 개념을 적용하기 위해서 결함의 깊이와 주파수에 대한 영향을 검토하였다. 정확한 결함검출을 위해 검사과정을 초기검사와 정밀검사로 나누어서 실시하여 결함의 위치를 $\pm$2[mm]까지 도출해 낼 수 있었으며 결함의 폭과 크기도 어느 정도 추측해 낼 수 있었다.

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