• 제목/요약/키워드: THERMAL AGING

검색결과 622건 처리시간 0.03초

TGA를 이용한 Chlorinated Poly Vinyl Chloride(CPVC)의 활성화 에너지 평가 (Evaluation of the Activation Energy of Chlorinated Poly Vinyl Chloride (CPVC) Using Thermogravimetric Analysis)

  • 박형주
    • 한국화재소방학회논문지
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    • 제33권1호
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    • pp.1-6
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    • 2019
  • 열중량 분석법(TGA)을 이용하여 소방용 합성수지 배관으로 사용되는 CPVC의 활성화 에너지를 측정하였다. 열중량 분석법을 이용한 활성화 에너지는 Kissinger method와 Flynn-Wall-Ozawa method를 이용하여 계산하였다. 활성화 에너지를 계산한 결과 Kissinger method에 의해 128.07 kJ/mol, Flynn-Wall-Ozawa method에 의해 145.60 kJ/mol로 나타났다. Kissinger method와 Flynn-Wall-Ozawa method에 의해 계산된 활성화 에너지의 차이는 해석 방법이 다르다는 점을 감안했을 때 큰 차이가 없다고 판단된다. 향후 가속열화을 이용한 열적 열화평가 및 공기오븐노화시험을 통한 CPVC의 연소특성을 시험하고, 수명을 예측하고자 한다.

Evaluation of Static Spring Constant and Accelerated Life Prediction for Compression Set of Polyurethane Resilient Pad in Rail Fastening System

  • Lee, Seung-Won;Park, Jun-Young;Park, Eun-Young;Ryu, Sung-Hwan;Bae, Seok-Hu;Kim, Nam-Il;Yun, Ju-Ho;Yoon, Jeong-Hwan
    • Elastomers and Composites
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    • 제53권4호
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    • pp.220-225
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    • 2018
  • Resilient pads play a major role in reducing the impact of loads on a rail in a rail-fastening system, which is essentially used for a concrete track. Although a compression set test is commonly used to measure the durability of a resilient pad, the static spring constant is often observed to be different from the fatigue test. In this study, a modified compression set test method was proposed to monitor the variations in the compression set and static spring constant of a resilient pad with respect to temperature and time. In addition, the life of the resilient pad was predicted by performing an acceleration test based on the Arrhenius equation.

316계 스테인리스강과 소듐 냉각재와의 양립성 연구 (Compatibility Study between 316-series Stainless Steel and Sodium Coolant)

  • 김준환;김종만;차재은;김성호;이찬복
    • 대한금속재료학회지
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    • 제48권5호
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    • pp.410-416
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    • 2010
  • Studies were carried out to establish the technology for sodium-clad compatibility and to analyze the compatibility behavior of the Sodium-cooled Fast Reactor (SFR) cladding material under a flowing sodium environment. The natural circulation facility caused by the thermal convection of the liquid sodium was constructed and the 316-series stainless steels were exposed at $650{^{\circ}C}$ liquid sodium for 1458 hours. The weight change and related microstructural change were analyzed. The results showed that the quasi-dynamic facility represented by the natural convection exhibited similar results compared to the conventional dynamic facility. Selective leaching and local depletion of the chromium, re-distribution of the carbide, and the decarburization process took place in the 316-series stainless steel under a flowing sodium environment. This process decreased as the sodium flowed along the channel, which was caused by the change in the dissolved oxygen and carbon activity in the liquid sodium.

Effect of surface treatment and luting agent type on shear bond strength of titanium to ceramic materials

  • Karaokutan, Isil;Ozel, Gulsum Sayin
    • The Journal of Advanced Prosthodontics
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    • 제14권2호
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    • pp.78-87
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    • 2022
  • PURPOSE. This study aimed to compare the effect of different surface treatments and luting agent types on the shear bond strength of two ceramics to commercially pure titanium (Cp Ti). MATERIALS AND METHODS. A total of 160 Cp Ti specimens were divided into 4 subgroups (n = 40) according to surface treatments received (control, 50 ㎛ airborne-particle abrasion, 110 ㎛ airborne-particle abrasion, and tribochemical coating). The cementation surfaces of titanium and all-ceramic specimens were treated with a universal primer. Two cubic all-ceramic discs (lithium disilicate ceramic (LDC) and zirconia-reinforced lithium silicate ceramic (ZLC)) were cemented to titanium using two types of resin-based luting agents: self-cure and dual-cure (n = 10). After cementation, all specimens were subjected to 5000 cycles of thermal aging. A shear bond strength (SBS) test was conducted, and the failure mode was determined using a scanning electron microscope. Data were analyzed using three-way ANOVA, and the Tukey-HSD test was used for post hoc comparisons (P < .05). RESULTS. Significant differences were found among the groups based on surface treatment, resin-based luting agent, and ceramic type (P < .05). Among the surface treatments, 50 ㎛ air-abrasion showed the highest SBS, while the control group showed the lowest. SBS was higher for dual-cure resin-based luting agent than self-cure luting agent. ZLC showed better SBS values than LDC. CONCLUSION. The cementation of ZLC with dual-cure resin-based luting agent showed better bonding effectiveness to commercially pure titanium treated with 50 ㎛ airborne-particle abrasion.

프라이머 가공 방법이 열융착 필름 라미네이팅으로 제조한 고충격 대응 에어쿠션 소재의 물성에 미치는 영향 연구 (A Study on the Effect of Primer Processing Method on the Mechanical Properties of Impact Relief Air Cushion Materials Prepared through Thermal Film Laminating)

  • 김지연;김훈민;민문홍
    • 한국염색가공학회지
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    • 제34권3호
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    • pp.173-184
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    • 2022
  • In this study, the TPU film was laminated on an aramid fabric or circular knits in order to implement an air cushion material that can respond to high impact forces in case of a fall and is easy to expand. To increase the bonding strength between the fabric layer and the film layer, a primer layer was formed in two ways: one for thermally bonding and laminating PET film and two for coating and aging hot melt type PUR adhesive. The tensile strength of the aramid air cushion was 2.5 times higher than that of the circular knits, but the tensile elongation of the aramid air cushion was very low compared to that of the circular knits. The tear strength of the aramid air cushion was about twice or more superior to that of the circular knits, the primer treatment method was good at A, and the peel strength was excellent at method A. The aramid air cushion was the lightest in weight. Summarizing the above results, it was best to combine the air cushion material with aramid woven fabric and primer treatment method A to cope with the high impact force applied when falling.

Full-scale bridge expansion joint monitoring using a real-time wireless network

  • Pierredens Fils;Shinae Jang;Daisy Ren;Jiachen Wang;Song Han;Ramesh Malla
    • Structural Monitoring and Maintenance
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    • 제9권4호
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    • pp.359-371
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    • 2022
  • Bridges are critical to the civil engineering infrastructure network as they facilitate movement of people, the transportation of goods and services. Given the aging of bridge infrastructure, federal officials mandate visual inspections biennially to identify necessary repair actions which are time, cost, and labor-intensive. Additionally, the expansion joints of bridges are rarely monitored due to cost. However, expansion joints are critical as they absorb movement from thermal effects, loadings strains, impact, abutment settlement, and vehicle motion movement. Thus, the need to monitor bridge expansion joints efficiently, at a low cost, and wirelessly is desired. This paper addresses bridge joint monitoring needs to develop a cost-effective, real-time wireless system that can be validated in a full-scale bridge structure. To this end, a wireless expansion joint monitoring was developed using commercial-off-the-shelf (COTS) sensors. An in-service bridge was selected as a testbed to validate the performance of the developed system compared with traditional displacement sensor, LVDT, temperature and humidity sensors. The short-term monitoring campaign with the wireless sensor system with the internet protocol version 6 over the time slotted channel hopping mode of IEEE 802.15.4e (6TiSCH) network showed reliable results, providing high potential of the developed system for effective joint monitoring at a low cost.

Prediction of the Vase Life of Cut Lily Flowers Using Thermography

  • Lee, Ja Hee;Choi, So Young;Park, Hye Min;Oh, Sang Im;Lee, Ae Kyung
    • 인간식물환경학회지
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    • 제22권3호
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    • pp.233-239
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    • 2019
  • This study was conducted in order to predict the vase life of cut lily 'Woori Tower' flowers using a non-destructive thermal imaging technique. It was found that the temperature of cut lily flowers was maintained at 20℃ and was slightly lower than the air temperature until they bloomed. On the 11th day, when flowers bloomed, the temperature of leaves and flowers was measured to be 18.75±0.38℃ and 19.23±0.32℃ respectively, and their difference with ambient temperature was over 3℃. The flower temperature increased slightly when the vase life of cut lily flowers ended, and the temperature difference between the air and leaf temperature (1.77℃) and between the air and flower temperature (1.39℃) got smaller. No visible aging symptom was observed, but it was found that the temperature had risen due to water losses and less functional stomata. The vase life of cut lily flowers can be predicted based on changes in temperature and it will be also possible to predict the potential quality and vase life of cut flowers before harvesting them in greenhouses.

해상풍력단지 J-Tube 내부 해저케이블의 절연 특성 평가 (Insulation Characteristics Evaluation of Submarine Cables Inside the J-Tube of Offshore Wind Farms)

  • 이승원;최진욱;김해종
    • 한국전기전자재료학회논문지
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    • 제36권6호
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    • pp.570-575
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    • 2023
  • Demand and necessity for eco-friendly offshore wind farms have been increasing. Research on submarine cables is constantly being considered for a reliable and stable power transmission. This study aimed to evaluate the thermal aging characteristic of submarine cables inside the J-tube of offshore wind farms. In this study, a submarine cable was set in three sections: The first is the part exposed to the air above the sea level at high temperature. The second is the section exposed to repeated temperature fluctuation as the sea level rises and falls. The third is the part submerged at low temperature below the sea level. Aged samples were tested by using the method of electrical evaluation to obtain insulation characteristics. The experimental results show that the dielectric breakdown of the sample with temperature fluctuation was 7% lower than the sample with a constant temperature; thereby, demonstrating that the section where the temperature fluctuation occurred in the submarine cables was weaker than the other. The sections of submarine cable with temperature fluctuations are believed as a weak point during operation; therefore, this part should be monitored preferentially.

산화철 나노입자의 형성 메커니즘에 대한 연구 (Study on Formation Mechanism of Iron Oxide Nanoparticles)

  • 김동영;윤석수;미가쿠 다까하시
    • 한국자기학회지
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    • 제22권5호
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    • pp.167-172
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    • 2012
  • 본 연구에서는 $Fe(OL)_3$ 전구체가 고온에서 열분해 한 후 산화철 나노입자를 형성하는 메커니즘을 분석하기 위하여 전구체의 온도에 따른 열유속을 측정하였으며, 반응 과정에서 순차적으로 채취한 반응 원액의 TEM 및 교류 자화율을 측정 하였다. $Fe(OL)_3$는 고온에서 OL-chain 두 개가 순차적으로 분리되어 Fe-OL 단량체(monomer)가 되고, 이들이 산화철 나노입자 형성에 기여하게 된다. 또한 산화철 나노입자는 초기 성장 과정에서 ${\gamma}-Fe_2O_3$ 구조를 갖는 나노입자를 형성하지만, 나노 입자들이 급격히 성장할 때는 공급되는 산소량의 부족으로 인하여 FeO가 형성되어 ${\gamma}-Fe_2O_3$-FeO의 core-shell 구조를 갖는 나노입자들이 합성된다. 이러한 산화철 나노입자들을 고온에서 장시간 유지시키면 부족한 산소를 점차적으로 보충하여 $Fe_3O_4$ 구조를 갖는 나노입자로 변화한다. 따라서 포화자화량이 높고 공기 중에서 안정한 $Fe_3O_4$ 나노입자는 고온 열분해법을 이용하여 쉽게 제조할 수 있다.

FURA 코드 개발과 부하 추종 운전에 대한 적용 (Development of FURA Code and Application for Load Follow Operation)

  • Park, Young-Seob;Lee, Byong-Whi
    • Nuclear Engineering and Technology
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    • 제20권2호
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    • pp.88-104
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    • 1988
  • 이차원의 유한요소법을 이용하여 axisymmetric R-$\theta$system으로 나누어서 정상과 부하추종 운전시에 핵연료 페렛트와 피복관의 열역학적 거동을 분석하기 위해서 FURA전산코드를 개발하였다. 온도분포와 내부압력을 정확히 계산하기 위해서 페렛트와 피복관의 변형과 핵분열의 기체방출을 전체 핵연료봉 길이로 고려하였다. 열역학적 평 형방정식을 얻기 위해서 Galerkin's Technique과 가상일의 원리를 사용하였고 역학적 해석을 위해서 탄성-소성, 크리프뿐만아니라 스엘링, 재배열, 고밀화 현상등을 고려하였다. 기하학적 모델에서는 4-결점 요소라 페레트 길이의 1/2만을 택하였다. 비선형식을 안정하게 해석하기 위해서 음해법을 도입하여 뉴튼-랩손 반복법을 적용하였다 이 코드의 검증은 해석해와 실험데이타로 비교하였다. 핵연료봉의 일반적인 거동은 axisymmetry system으로 계산하였고 균열된 페레트에 접촉하는 피복관의 거동은 R-$\theta$system을 사용하였다. 부하추종에 의한 피복관의 변형시효의 민감도는 출력율, 진동수, 진폭등으로 비교하였다.

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