• Title/Summary/Keyword: TFA

Search Result 206, Processing Time 0.024 seconds

Fabrication of high-$J_c$ $YBa_2Cu_3O_{7-{\delta}}$ thin films on (100) $SrTiO_3$ single crystal substrates by a modified TFA-MOD method (수정된 TFA-MOD법에 의한 (100) $SrTiO_3$ 단결정 기판 위 고 임계전류 밀도 $YBa_2Cu_3O_{7-{\delta}}$ 박막 제조)

  • Wee, Sung-Hun;Shin, Keo-Myung;Song, Kyu-Jung;Hong, Gye-Won;Moon, Seung-Hyun;Park, Chan;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
    • /
    • v.6 no.1
    • /
    • pp.12-17
    • /
    • 2004
  • High critical current density. $J_c$ over $1MA/cm^2$ at 77 K in a self field was successfully achieved from the YBCO film prepared on (100) $SrTiO_3$ single-crystal substrates by the TFA-MOD process. Unlike a normal TFA-MOD process, we prepared the TFA precursor solution by dissolving YBCO powder into the trifluoroacetic acid. A significant amount of the second phases, including $BaF_2$, was observed in the films fired at $700-725^{\circ}C$ for 2 h under $P(O_2)=10^{-3}$ atm and $P(H_2O)=4.2%$, most probably due to an insufficient reaction time, and hence $T_c$ was greatly degraded. However the films fired at $750-800^{\circ}C$ for 2 h were composed of strongly c-axis oriented YBCO grams without any second phases. and exhibited the $T_c$ values of 89.5 ~ 91 K with a sharp transition. With increasing the firing temperature from 750 to $800^{\circ}C$ average grain size of YBCO was increased and grain connectivity was enhanced. The highest $J_c$ value of $1.1MA/cm^2$ was obtained from the YBCO film fired at $800^{\circ}C$.

Studies on Analytical Methods for N-Methylcarbamate Residues in Crops by Spectrophotometry and Gas Liquid Chromatography (작물체중(作物體中) N-Methylcarbamate계(系) 농약(農藥)의 잔류분석법(殘留分析法)에 관(關)한 연구(硏究))

  • Oh, Byung-Youl;Jeong, Young-Ho;Park, Young-Sun
    • Korean Journal of Environmental Agriculture
    • /
    • v.1 no.1
    • /
    • pp.14-21
    • /
    • 1982
  • Analytical methods for residues of six N-methylcarbamate insecticides were investigated to compare the minimum detectability, recovery from several crops and feasibility of multiple residue analysis. Those methods studied in this work included spectrophotometry by diazotization and gas chromatography by N-trifluoroacetylation(TFA), pentafluorobenzylether(PFB) and dinitrophenylether (DNP) derivatization. Maximum absorbed wavelength of the diazotized MIPC, XMC, BPMC, propoxur and carbofu ran was around 460 ㎚, while that of carbaryl recorded 510 ㎚. Recovery from brown rice and apple by diazotization method ranged from 80 to 120% and minimum detectable limits were 0.03 to 0.05 ppm in 50 g of the sample. Minimum detectability of PFB derivatives by gas chromatography was superior to TFA and DNP derivatives. DNP derivatives showed the longest retention time among the given derivatives. Recovery from crops by gas chromatographic met hod ranged 74 to 94%, 78 to 93%, and 85 to 99% in brown rice, rice straw and apple, respectively. Limit of detection was 0.01 ppm for TFA, 0.005 ppm for PFB and 0.02 ppm for DNP derivatives in 50 g of the crop samples.

  • PDF

Development of TFA-MOD Coated Conductors

  • Fuji, H.;Teranishi, R.;Tokunaga, Y.;Matuda, J.;Nakaoka, K.;Aoki, Y.;Nomoto, S.;Izumi, T.;Yamada, Y.;Shiohara, Y.;Yajima, A.;Saitoh, T.
    • 한국초전도학회:학술대회논문집
    • /
    • v.14
    • /
    • pp.14-14
    • /
    • 2004
  • PDF

Application of Texture Feature Analysis Algorithm used the Statistical Characteristics in the Computed Tomography (CT): A base on the Hepatocellular Carcinoma (HCC) (전산화단층촬영 영상에서 통계적 특징을 이용한 질감특징분석 알고리즘의 적용: 간세포암 중심으로)

  • Yoo, Jueun;Jun, Taesung;Kwon, Jina;Jeong, Juyoung;Im, Inchul;Lee, Jaeseung;Park, Hyonghu;Kwak, Byungjoon;Yu, Yunsik
    • Journal of the Korean Society of Radiology
    • /
    • v.7 no.1
    • /
    • pp.9-15
    • /
    • 2013
  • In this study, texture feature analysis (TFA) algorithm to automatic recognition of liver disease suggests by utilizing computed tomography (CT), by applying the algorithm computer-aided diagnosis (CAD) of hepatocellular carcinoma (HCC) design. Proposed the performance of each algorithm was to comparison and evaluation. In the HCC image, set up region of analysis (ROA, window size was $40{\times}40$ pixels) and by calculating the figures for TFA algorithm of the six parameters (average gray level, average contrast, measure of smoothness, skewness, measure of uniformity, entropy) HCC recognition rate were calculated. As a result, TFA was found to be significant as a measure of HCC recognition rate. Measure of uniformity was the most recognition. Average contrast, measure of smoothness, and skewness were relatively high, and average gray level, entropy showed a relatively low recognition rate of the parameters. In this regard, showed high recognition algorithms (a maximum of 97.14%, a minimum of 82.86%) use the determining HCC imaging lesions and assist early diagnosis of clinic. If this use to therapy, the diagnostic efficiency of clinical early diagnosis better than before. Later, after add the effective and quantitative analysis, criteria research for generalized of disease recognition is needed to be considered.

Educational Support Activities of Private Organizations to Alleviate the Educational Gap: Focusing on Teach For America in USA and Dream Touch For All in Korea (교육 격차 해소를 위한 민간단체의 교육지원 활동: 미국의 Teach For America와 한국의 Dream Touch For All을 중심으로)

  • Min, Yunkyung;Park, Keunah;Lee, Hae-Nee
    • Korean Journal of Comparative Education
    • /
    • v.28 no.6
    • /
    • pp.85-109
    • /
    • 2018
  • This paper aims to compare the two groups of TFA in U.S. and Dream Touch For All in Korea established with the same goals: 1) goal and core value, 2) qualification and training of teachers, and 3) educational performance. As a result of the analysis, the two groups showed that they focused on the role of teachers to improve the academic achievement of the underprivileged under the goal of solving the inequality of education. However, while TFA in the United States was able to function within public education, Korea's Dream Touch For All played a complementary role in public education. In the case of the United States, it appears to be a 'quasi-open' teacher training system that allows teachers from alternative teacher groups such as TFA to be accepted, while in Korea it shows the character of 'closed teacher training system' to be. For this reason, the two groups showed differences in core value, teacher training, and operating program, and as a result, they also set different educational models.

Correlation between Pelvic Angle and the Tibiofemoral Angle in the Genu Varum (내반슬로 인한 대퇴경골각의 변화가 골반경사각에 미치는 영향)

  • Kim, Kyoung-Seok;Ryu, Ji-Mi;Kim, Koh-Woon;Kim, Gwi-Hyun;Jeong, Won-Seok;Lee, Jong-Soo
    • The Journal of Churna Manual Medicine for Spine and Nerves
    • /
    • v.4 no.2
    • /
    • pp.13-20
    • /
    • 2009
  • Objectives : The purpose of this study was to investigate the Correlation between Pelvic angle and the Tibiofemoral angle in the Genu varum. Method : Age of All subjects were 20-37 years. 33(male 10, female 23) subjects were assessed by whole spine x-ray and orthogram. The collected data consisted of items on general characteristics, Pelvic Incidence(PI), Pelvic Tilt(PT), Sacral Slope(SS) and Tibiofemoral Angle(TFA) of the subjects. Results : The PI, PT and TFA had a relationship significantly. However, there was no relationship between SS and TFA. Conclusion : The results suggest that TFA is related to PI, PT. Internal rotation due to genu varum of femoral at hip influence that PI and PT increase.

  • PDF

Effect of nano size $Y_2O_3$ addition on the superconducting properties and microstructure of YBCO thin film prepared by TFA-MOD method. (TFA-MOD 방법에 의한 YBCO 박막제조에서 nano size $Y_2O_3$ 첨가효과)

  • Park Jin-A;Kim Byung-Joo;Hong Gye-Won;Lee Hee-Gyoun;Yoo Jai-Moo;Kim Young-Kuk
    • Progress in Superconductivity and Cryogenics
    • /
    • v.8 no.3
    • /
    • pp.13-17
    • /
    • 2006
  • The effect of the addition of the nano size $Y_2O_3$ powder on the microstructurte and superconducting properties of YBCO thin film deposited on LAO single crystalline substrate by TFA-MOD method was studied. Nano size $Y_2O_3$ powder was added to the stoichiometric precursor solution with a cation ratio of Y : Ba . Cu = 1 : 2 : 3 prepared using TFA as chelating agent. Precursor solutions with and without $Y_2O_3$ addition were coated on $LaAlO_3(100)$ single crystalline substrates by dip coating method. Calcination and conversion heat treatments were performed in controlled atmosphere containing moisture Current carrying capacity(Jc) of YBCO film was enhanced about 50% by $Y_2O_3$ doping and it is thought to be due to the better connectivity of YBCO grains and/or the flux pinning by the $Y_2O_3$ particles embedded in YBCO grains.

Effects of Excess Yttrium Addition on YBCO Thin Films Prepared by TFA-MOD Process (MOD-TFA 공정에 의한 YBCO박막제조시 과잉 yttrium첨가 효과에 관한 연구)

  • Lee Seung-Yi;Song Seul-A;Kim Byeong-Joo;Park Jin-A;Kim Ho-Jin;Lee Hee-Gyoun;Hong Gye-Won;Jang Seog Heon;Joo Jinho;Yoo Jai-Moo;Pradeep Halder
    • Progress in Superconductivity
    • /
    • v.7 no.1
    • /
    • pp.87-91
    • /
    • 2005
  • [ $YBa_{2}Cu_{3}O_{7-x}$ ] thin films were fabricated on $LaAlO_3$(100) substrate by TFA-MOD process. Yttrium-excess (0, 2.5, 5, 10, 15, 20 $at\%$) coating solution was prepared by adding extra amount of yttrium into a stoichiometric(Y:Ba:Cu=1:2:3) TFA precursor solution. Results are presented concerning the influence of excess yttrium additions on the microstructure development and superconducting properties of $YBa_{2}Cu_{3}O_{7-x}$ film. Large sized CuO particles was observed by SEM EDS investigation. The addition of excess yttrium affected little on $T_c$ of $YBa_{2}Cu_{3}O_{7-x}$ film. $J_c$ of YBCO film was enhanced with excess yttrium addition. Jc maximum of $2.21\;MA/cm^2$ (77 K, self field) appeared with the $15\;at\%$ addition of excess yttrium. With further yttrium addition up to $20\;at\%$, Jc decreased down to $0.9\;MA/cm^2$.

  • PDF

Effect of Cerium Doping on Superconducting Properties of YBCO Film Prepared by TFA-MOD Method (MOD-TFA공정에 의한 YBCO박막 제조 시 cerium첨가효과에 관한 연구)

  • Yi, Keum-Young;Kwon, Youn-Kyung;Kim, Byeong-Joo;Ahn, Ji-Hyun;Lee, Jong-Beom;Kim, Hye-Jin;Lee, Hee-Gyoun;Hong, Gye-Won;Yoo, Jai-Moo;Ri, Hyung-Chul
    • Progress in Superconductivity
    • /
    • v.8 no.1
    • /
    • pp.87-92
    • /
    • 2006
  • The effects of Ba and Ce addition has been investigated in YBCO prepared by trifluoroacetate(TFA) metalorganic depostition(MOD) method. Precursor solutions with cation ratios of Y:Ba:Cu:Ce=1:2+x:3:x(x=0, 0.05, 0.1 and 1.5) have been prepared by adding an excess amount of cerium and barium. Coated film was calcined at lower temperature under a moisture-containing oxygen atmosphere. Superconducting YBCO films have been obtained by performing conversion heat treatment at temperature of $780{\sim}810^{\circ}C$ under a moisture-containing Ar(1,000 ppm oxygen) atmosphere. It has been shown that the critical current($I_c$) of YBCO film was degraded by doping of Ba and Ce atoms. But $I_c$ was increased as the amount of doped Ba and Ce content increased from 5% to 15 %. It was observed that there was little increase of a flux pinning force with Ba and Ce addition in YBCO film prepared by TFA-MOD process.

  • PDF

Design and Implementation of a Fifthly Expanded Triangular Fractal Antenna (5차 확장 삼각형 프랙털 안테나 설계 및 구현)

  • 최재연
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.6 no.4
    • /
    • pp.616-623
    • /
    • 2002
  • The fractal expanded antenna with the configuration of a triangular microstrip patch antenna is presented and analyzed. In the fundamental and higher mode of TFA(Triangular Fractal Antenna), resonant frequencies are controlled by changing the scaling factor. It is observed that increasing scaling factor makes the resonant frequency be spread, and decreasing scaling factor makes it be concentrated. The scaling factor is varied as the expansion and concentration of resonant frequencies. The resonant frequency in each fractal patch element is observed log -periodically. The TFA can be applied to the multiband system.