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Inclusion Selectivity of the Cyanocadmate Host Complex with Piperazine Ligand for Aromatic Guest Molecules; Benzene, Toluene, Ethylbenzene and Xylene Isomers (Piperazine 리간드를 가진 시아노카드뮴 호스트 착물의 방향족 게스트 분자에 대한 포접선택성)

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.333-338
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    • 2003
  • Inclusion selectivity of a three-dimensional piperazine-ligated cyanocadmate host complex, $[Cd_x(CN)_{2x}\{HN(CH_2CH_2)_2NH\}_y]{\cdot}zG$, has been investigated for benzene (B), toluene (T), ethylbenzene (E), o- (O), m- (M), and p-xylene (P) isomers as the aromatic guest molecules. From the binary, ternary and quarternary guest mixtures of E and xylene isomer (X), the order of inclusion selectivity in the host complex is O>E>P>M. From the binary to quinary BTX mixtures, the order of preference in the complex is seen to be B>T>O${\gg}$P>M.

압전소자의 소성과 특성에 관하여

  • 박창엽;송동범
    • 전기의세계
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    • v.28 no.2
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    • pp.23-28
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    • 1979
  • 압전 세라믹 소자는 강유전성 세라믹에 높은 직류전압을 가한 후에 나타나는 압전효과를 이용하는 것으로 전압을 제거한 후에도 압전효과가 존재하는 것이 강유 전체의 특징이다. 압전효과를 나타내는 것은 천연으로 존재하는 수정이 있고, 인조품으로서는 BaTiO$_{3}$가 2차 대전후 W.P Mason에 의해 연구되어 압전재료로서 사용되었지만 BaTiO$_{3}$는 공진주파수의 온도안정성이 문제가 된다. 그후 B.Jaffe et al.은 P$_{b}$(Z$_{r}$, T$_{i}$)O$_{3}$등 몇가지 복합 Perovskite 산화물 중에서 P$_{b}$(Z$_{r}$, T$_{i}$)O$_{3}$$P^{2+}$$_{b}$ 이온을 다른 이온으로 치환하면 큐리 온도가 변하고 실온에서의 유전율도 크게 변화한다는 것이 밝혀졌다. 여기서 논하고저 하는 것은 압전소자의 제법과 성질 또 이의 특성을 좁은 범위 내에서 소개코저 한다.

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Effects of Bath Temperature on Electrodeposited Permanent Magnetic Co-Pt-W(P) Films

  • Ge, Hongliang;Wu, Qiong;Wei, Guoying;Wang, Xinyan;Zhou, Qiaoying
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2214-2218
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    • 2007
  • The effects of bath temperature on electrochemical behavior, alloy composition, crystallographic structure, morphology and the magnetic properties of electrodeposited Co-Pt-W(P) films were investigated. Electrochemical studies show that alloy electrodeposition has been shifted to more positive potentials and the critical time for nucleation decreased as electrolyte temperature increased. As the temperature increased from 40 oC to 80 oC, tungsten content in the deposit increased, while phosphorus content decreased. The films deposited at T = 40 oC exhibited soft magnetic properties. However, electrodeposited at T = 70 oC, the films exhibited hard magnetic properties. It is also demonstrated that higher temperature more than 70 oC could weaken hard magnetic properties. XRD results indicated that the deposits obtained at 50 oC-70 oC showed enhancement of [00.1] P.O. (preferred orientation) with the bath temperature, which resulted in the stronger perpendicular magnetic anisotropy.

Dielectric and Piezoelectric Properties of [Li0.04(Na0.5K0.5)0.96](Nb0.86Ta0.10Sb0.04)O3 Ceramics Doped with SrO (SrO의 첨가에 따른 [Li0.04(Na0.5K0.5)0.96](Nb0.86Ta0.10Sb0.04)O3세라믹스의 유전 및 압전 특성)

  • Park, Min-Ho;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.3
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    • pp.198-203
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    • 2012
  • In this study, $[Li_{0.04}(Na_{0.5}K_{0.5})_{0.96}](Nb_{0.86}Ta_{0.10}Sb_{0.04})O_3+xSrO$ (x=0, 0.0025, 0.005, 0.0075) ceramics were synthesized by the conventional mixed oxide method. The X-ray diffraction patterns demonstrated that ceramics possessed single perovskite structure. The SEM images indicate that microstructure can be obviously affected by a small amount of added SrO. The phase transition temperature tetragonal-cubic($T_c$) and orthorhombic-tetragonal($T_{o-t}$) shifts downward and upward with the increase of Sr addition, respectively. The excellent piezoelectric properties of $d_{33}=170[pC/N]$, $k_p=0.37$, $Q_m=64.12$, $T_{o-t}=153^{\circ}C$ and $T_c=370^{\circ}C$ were obtained from the 0.25 mol% Sr added ceramics sintered at $1,120^{\circ}C$ for 1 h.

일본의 과학 및 학술 정보 정책의 수립 과정과 실시 체제의 분석

  • 현규섭
    • Journal of the Korean Society for information Management
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    • v.5 no.1
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    • pp.31-52
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    • 1988
  • The information policy in Japan have bccir growing rapldlr 111 recent vttars. \'arioi~s level of govc~riimerital organrzatlons, ir~bt~tution arid agrircics have undt~rtak~~rr iriforrnatiori polrcy 111 order to i r l - crease information flow toward tlie society in Japan. At tlie same trme, computerized library systems also h a w uridergoirc rapid expansion. NACSIS(National Ceriter for- Science Informat~on System) wl~icl~ was cstablisl~ed bv Mirristr> of Etlr~c~arion, Sc~ence arid Culture haw witnessed dramatic adv;rnces i r i promoting for corrstructiori of database so as to provide their 11rf'3r.mat1orr nu nationwide scale. T l r i h articlr inrroduccs tlie actr\rtle> and ~mplcmeritat~o~~ of it format in^^ pol~cy wl~i(~li taktas a place hy goverrirnrlit of Japar~ aid arraly~c,.; thi~ ~ I . O I . P S I of deciiioii maltiiig iri polit~cal procedures. So far as b:ast-A\~ari riatioris art, ~ . n r i v t ~ r ~ ~ , e.;pc,ciall\. Kr,rc.an a~rd Japair !rave ,imilar cultural and liistorical backjir. ourii1, ard could t)t. tliif most a p p r o p r i a t ~ ~ caac stlldh for political ~nq~lerncritat~orr. Thus the topic of this artrclc will be useful to r t ~ a l l ~ t . Ore, trail ur~d c r r o r prorex, iri iiiior.matior~ pnlic\ulcorner.

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Related Factors of Suicide Ideation in Elderly People with Diabetes Mellitus Living Alone in Rural Area (농촌지역에 거주하는 독거 당뇨병 노인의 자살사고 관련 요인)

  • Gang, Moonhee;Ahn, Yujin
    • Journal of Industrial Convergence
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    • v.20 no.10
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    • pp.79-86
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    • 2022
  • The purpose of this study was to identify suicidal ideation and related factors of elderly people with diabetes mellitus living alone in rural area. A descriptive study design was used. The participants were 466 elderly people, aged 65 years and over, and diagnosed with diabetes mellitus living at O province in South Korea. Collected data were analyzed using descriptive statistics, t-test, χ2-test, and logistic regression analysis with SPSS statistics 26.0 program. The results of the analysis showed that the suicidal ideation rate of the subjects was 27.3%, and the subjects showed significant differences in suicidal ideation as Cognitive function was lower (t=-4.23, p<.001), Depression(t=9.56, p<.001) and Loneliness (t=4.88, p<.001) were higher. Related Factors of suicidal ideation were Cognitive function (OR=0.86, p<.001), Depression (OR=1.18, p<.001) and Loneliness (OR=1.17, p=.001). These variables explained 32.2% of suicidal ideation. Therefore, in order to reduce suicide ideation of the elderly with diabetes mellitus living alone in rural areas, intervention that can improve Cognitive function, Depression, and Loneliness is needed.

$Pb_{2}Sr_{2}(Y_{1-x}Ca_{x})Cu_{3}O_{8+{\delta}}$ 계 화합물의 상평형과 제조 공정

  • 정동운
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1994.11a
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    • pp.118-118
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    • 1994
  • Processings of the P $b_2$S $r_2$( $Y_{1-x}$ C $a_{x}$) C $u_3$ $O_{8+{\delta}}$ (2213)system for x=0.4-0.6 to control deleterious oxidative decomposition have been studied. Our results show that comounds are stable at both low p $O_2$ and high p $O_2$ if they are suitably oxidized. Various oxidation and deoxidation procedures have been investigated in order tp determine the optimum hole concentration in the Cu $O_2$layers for the maximum $T_{c}$. In cases x=0.5 and x=0.6, the optimum hole concentration in the 2213-phase is achieved, but with accelerated oxidative decomposition. Destite this, the maximum $T_{c}$~80-83K for the 2213-phase can be deduced when x=0.5 to 0.6 to 0.6

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Analysis of Thermodynamics in BiSrCaCuO Thin Films Fabricated by Using the i-beam sputtering method (i-beam 스퍼터링 법으로 제작한 BiSrCaCuO 박막의 열역학분석)

  • Kim, Tae-Gon;Park, yong-Pil
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.11 no.1
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    • pp.89-94
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    • 2007
  • High duality BiSrCaCuO thin films fabricated by using the i-beam sputtering method at various substrate temperatures, $T_{sub}$ and oxidation gas pressures, $pO_3$. The correlation diagrams of the BiSrCaCuO phases with Tsub and $pO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on $T_{sub}$ and $pO_3$. From these results, the thermodynamic evaluation of ${\Delta}H$ and${\Delta}S$, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed.

Effects of Eucalyptus Crude Oils Supplementation on Rumen Fermentation, Microorganism and Nutrient Digestibility in Swamp Buffaloes

  • Thao, N.T.;Wanapat, M.;Cherdthong, A.;Kang, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.1
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    • pp.46-54
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    • 2014
  • This study was conducted to investigate the effects of eucalyptus (E. Camaldulensis) crude oils (EuO) supplementation on voluntary feed intake and rumen fermentation characteristics in swamp buffaloes. Four rumen fistulated swamp buffaloes, body weight (BW) of $420{\pm}15.0$ kg, were randomly assigned according to a $2{\times}2$ factorial arrangement in a $4{\times}4$ Latin square design. The dietary treatments were untreated rice straw (RS) without EuO (T1) and with EuO (T2) supplementation, and 3% urea-treated rice straw (UTRS) without EuO (T3) and with EuO (T4) supplementation. The EuO was supplemented at 2 mL/h/d in respective treatment. Experimental animals were kept in individual pens and concentrate mixture was offered at 3 g/kg BW while roughage was fed ad libitum. Total dry matter and roughage intake, and apparent digestibilites of organic matter and neutral detergent fiber were improved (p<0.01) by UTRS. There was no effect of EuO supplementation on feed intake and nutrient digestibility. Ruminal pH and temperature were not (p>0.05) affected by either roughage sources or EuO supplementation. However, buffaloes fed UTRS had higher ruminal ammonia nitrogen and blood urea nitrogen as compared with RS. Total volatile fatty acid and butyrate proportion were similar among treatments, whereas acetate was decreased and propionate molar proportion was increased by EuO supplementation. Feeding UTRS resulted in lower acetate and higher propionate concentration compared to RS. Moreover, supplementation of EuO reduced methane production especially in UTRS treatment. Protozoa populations were reduced by EuO supplementation while fungi zoospores remained the same. Total, amylolytic and cellulolytic bacterial populations were increased (p<0.01) by UTRS; However, EuO supplementation did not affect viable bacteria. Nitrogen intake and in feces were found higher in buffaloes fed UTRS. A positive nitrogen balance (absorption and retention) was in buffaloes fed UTRS. Supplementation of EuO did not affect nitrogen utilization. Both allantoin excretion and absorption and microbial nitrogen supply were increased by UTRS whereas efficiency of microbial protein synthesis was similar in all treatments. Findings of present study suggested that EuO could be used as a feed additive to modify the rumen fermentation in reducing methane production both in RS and UTRS. Feeding UTRS could improve feed intake and efficiency of rumen fermentation in swamp buffaloes. However, more research is warranted to determine the effect of EuO supplementation in production animals.

Influence of Water Temperature on the Changes of Soil and Plant Nutrient of Paddy Rice (관개수온(灌漑水溫)의 차이(差異)가 토양(土壤) 및 수도체내(水稻體內) 양분변동(養分變動)에 미치는 영향(影響))

  • Kim, L.Y.;Min, K.B.;Jo, I.S.;Ju, N.S.;Um, K.T.
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.3
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    • pp.247-253
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    • 1985
  • In order to investigate the effects of water temperature on chemical properties of soil and nutrient uptake of rice plant, four varieties of rice were cultivated in a field where water temperature range was $17.3-23.0^{\circ}C$ and plant samples were taken at three growing stages and were analyzed in detail. The results were summarized as follows: 1. Organic matter content and pH of surface soil were showed no differences while the contents of $P_2O_5$ and $SiO_2$ were increased and potassium was decreased as the water temperature increased. 2. The amounts of nutrient uptake were related to the water temperature and the total nutrient contents of rice plants at harvesting stage were in order of $SiO_2$ > $K_2O$ > T-N > $P_2O_5$ > MgO. The rate of $SiO_2$/N and $K_2O$/N of rice plants grown at water temperature $23.0^{\circ}C$ were over two times to those of the water temperature $17.3^{\circ}C$. 3. Nutrient contents of rice plants showed a increasing tendency as increasing the water temperature. However, nutrient contents such as T-N at whole period, $P_2O_5$ at heading and harvesting stage, and $K_2O$ at heading stage were higher at low water temperature than those of high water temperature. 4. Most of nitrogen was translocated and accumulated in grain, potassium in straw respectively. All nutrients translocated to grain more easily as the water temperature increased.

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