• 제목/요약/키워드: T-gap

검색결과 990건 처리시간 0.027초

$Zn_{4}SnSe_{6}$$Zn_{4}SnSe_{6}:Co^{2+}$ 단결정에서 광학적 에너지 띠 및 열역학적 함수의 온도의존성 연구 (Temperature dependence of optical energy gaps and thermodynamic function of $Zn_{4}SnSe_{6}$ and $Zn_{4}SnSe_{6}:Co^{2+}$ single crystals)

  • 김덕태;김남오;최영일;김병철;김형곤;현승철;김병인;송찬일
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 제4회 영호남학술대회 논문집
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    • pp.25-30
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    • 2002
  • The ternary semiconducting compounds of the $A_{4}BX_{6}$(A=Cd, Zn, Hg; B=Si, Sn, Ge; X=S, Se, Te) type exhibit strong fluorescence and high photosensitivity in the visible and near infrared ranges, so these are supposed to be materials applicable to photoelectrical devices. These materials were synthesized and single crystals were first grown by Nitsche, who identified the crystal structure of the single crystals. In this paper. author describe the undoped and $Co^{2+}$-doped $Zn_{4}SnSe_{6}$ single crystals were grown by the chemical transport reaction(CTR) method using iodine of $6mg/cm^{3}$ as a transport agent. For the crystal. growth, the temperature gradient of the CTR furnace was kep at $700^{\circ}C$ for the source aone and at $820^{\circ}C$ for the growth zone for 7-days. It was found from the analysis of x-ray diffraction that undoped and $Co^{2+}$-doped $Zn_{4}SnSe_{6}$ compounds have a monoclinic structure. The optical absorption spectra obtained near the fundamental absorption edge showed that these compounds have a direct energy gaps. These temperature dependence of the optical energy gap were closely investigated over the temperature range 10[K]~300[K]

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Optical emission analysis of hybrid air-water discharges

  • Pavel, Kostyuk;Park, J.Y.;Han, S.B.;Koh, H.S.;Gou, B.K.;Lee, H.W.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.521-522
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    • 2006
  • In this paper, hybrid air-water discharges were used to develop an optimal condition for providing a high level of water decomposition for hydrogen yield. Electrical and optical phenomena accompanying the discharges were investigated along with feeding gases, flow rates, and point-to-plane electrode gap distance. The primary focus of this experiment was put on the optical emission of the near UV range, with the energy threshold sufficient for water dissociation and excitation. The $OH(A^{2+},'=0\;X^2,"=0$) band's optical emission intensity indicated the presence of plasma chemical reactions involving hydrogen formation. In the gaseous atmosphere saturated with water vapor the OH(A-X) band intensity was relatively high compared to the liquid and transient phases although the optical emission strongly depended on the flow rate and type of feeding gas. In the gaseous phase discharge phenomenon for Ar carrier gas transformed into a gliding arc via the flow rate growth. OH(A-X) band's intensity increased according to the flow rate or residence time of He feeding gas. Reciprocal tendency was acquired for $N_2$ and Ar carrier gases. The peak value of OH(A-X) intensity was observed in the proximity of the water surface, however in the cases of Ar and $N_2$ with 0.5 SLM flow rate peaks shifted to the region below the water surface. Rotational temperature ($T_{rot}$) was estimated to be in the range of 900-3600 K, according to the carrier gas and flow rate, which corresponds to the arc-like-streamer discharge.

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디페닐렌비닐렌 치환기를 가진 카바졸계 청색발광 공중합체 합성 (Synthesis of Novel Carbazole-based Blue Light-emitting Copolymers Containing (Diphenylene)vinylene Pendants)

  • 김우연;윤근병
    • 폴리머
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    • 제37권6호
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    • pp.736-743
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    • 2013
  • 공액구조 고분자의 밴드갭을 줄이기 위하여 청색의 디페닐렌비닐렌을 치환기를 갖는 카바졸 단량체와 용해도 향상을 위해 옥틸기를 도입한 카바졸 공단량체를 합성하여 신규 공중합체를 제조하였다. Suzuki 커플링 중합으로 공중합체를 제조하고, 공중합체의 열적, 분광학적, 전기광학적 특성을 조사하여 고분자 유기발광 다이오드(PLED)의 발광층에의 사용가능성을 조사하였다. 용액상태에서 공중합체의 UV 최대 흡수 파장은 333~340 nm, PL 최대방출 파장은 409~464 nm를 보였으며, 상대양자효율은 최대 25.8%의 값을 보였다. 열중량분석 결과 $350^{\circ}C$까지 열안정성을 보이고, 필름형성이 용이하였으며, 공중합체를 발광층으로 사용한 PLED 소자에서 4.0 V에서 청색광을 나타내었다.

중앙버스전용차로 버스전용신호 도입시 신호 최적화에 관한 연구 (Development of Determining Technique of Optimum Signal Time of Intersections On Median Exclusive Bus Lane using Bus-only Signal)

  • 김보겸;김승일;김영찬;김진태
    • 대한교통학회지
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    • 제24권5호
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    • pp.123-133
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    • 2006
  • 서울시를 포함한 수도권 각 도시는 중앙버스전용차로의 적극적인 도입으로 버스속도 및 정시성 향상을 통해 대중교통우선 처리 전략을 적극 추진 중에 있다. 그러나 이로 인해 중앙부 $1{\sim}2$개 차로를 버스전용차로가 차지함으로써 기존 신호운영체계에 큰 변화를 가져오게 되었다 좌회전 차량과 중앙버스전용차로를 이용해 직진하는 버스간에 새로운 상충이 발생하게 되어 동시신호 기법 등 교차로 신호운영대안이 줄어들게 된 것이다 이 해결방안으로서 버스전용신호를 도입하여 중첩현시 및 동시신호 등 Dual-Ring방식의 다양한 신호 운영을 가능케 하는 방안이 모색되고 있다. 본 연구에서는 이러한 버스전용신호 도입 시 교차로 정체를 최소화할 수 있는 신호설계방법을 제시하였고, 중앙버스전용차로가 운영 중인 양재역사거리에 동 기법을 이용한 최적신호 설계를 적용, 시뮬레이션을 통해 그 효과를 검증하였다.

Isoindigo Based Small Molecules for High-Performance Solution-Processed Organic Photovoltaic Devices

  • Elsawy, W.;Lee, C.L.;Cho, S.;Oh, S.H.;Moon, S.H.;Elbarbary, A.;Lee, Jae-Suk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.245.2-245.2
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    • 2013
  • Solution processed organic photovoltaic devices have relatively less attention compared to polymer photovoltaic devices even though they have high possibility to be developed because they have both advantages of polymer and organic, such as solution processable, no synthetic batch dependence of photovoltaic performance, high purity and high charge carrier mobility as well as relatively high efficiency (~7%). In addition, solution processed organic photovoltaic devices have an advantage of easiness to study the relationship between the molecular structure and photovoltaic performance due to its simple structure. In this work, five isoindigo based low band gap donor-acceptor-donor (D-A-D) small molecules with different electron donating strength were synthesized for investigating the relationship between the molecular structure and photovoltaic performance, especially, investigating the effects of different electron donating effect of donor group in isoindigo backbone to photovoltaic device performance. The variation of electron donating strength of donor group strongly affected the optical, thermal, electrochemical and photovoltaic device performances of isoindigo organic materials. The highest power conversion efficiency of ~3.2% was realized in bulk heterojuction photovoltaic device consisted of the ID3T as donor and PC70BM as acceptor. This work demonstrates the great potential of isoindigo moieties as electron deficient units as well as guideline for synthesis of donor-acceptor-donor (D-A-D) small molecules for realizing highly efficient solution processed organic photovoltaic devices.

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A review on deep learning-based structural health monitoring of civil infrastructures

  • Ye, X.W.;Jin, T.;Yun, C.B.
    • Smart Structures and Systems
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    • 제24권5호
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    • pp.567-585
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    • 2019
  • In the past two decades, structural health monitoring (SHM) systems have been widely installed on various civil infrastructures for the tracking of the state of their structural health and the detection of structural damage or abnormality, through long-term monitoring of environmental conditions as well as structural loadings and responses. In an SHM system, there are plenty of sensors to acquire a huge number of monitoring data, which can factually reflect the in-service condition of the target structure. In order to bridge the gap between SHM and structural maintenance and management (SMM), it is necessary to employ advanced data processing methods to convert the original multi-source heterogeneous field monitoring data into different types of specific physical indicators in order to make effective decisions regarding inspection, maintenance and management. Conventional approaches to data analysis are confronted with challenges from environmental noise, the volume of measurement data, the complexity of computation, etc., and they severely constrain the pervasive application of SHM technology. In recent years, with the rapid progress of computing hardware and image acquisition equipment, the deep learning-based data processing approach offers a new channel for excavating the massive data from an SHM system, towards autonomous, accurate and robust processing of the monitoring data. Many researchers from the SHM community have made efforts to explore the applications of deep learning-based approaches for structural damage detection and structural condition assessment. This paper gives a review on the deep learning-based SHM of civil infrastructures with the main content, including a brief summary of the history of the development of deep learning, the applications of deep learning-based data processing approaches in the SHM of many kinds of civil infrastructures, and the key challenges and future trends of the strategy of deep learning-based SHM.

실측 실험을 통한 단열문의 열성능 평가 (Thermal Performance Assessment of Insulated door by experiment.)

  • 장철용;김치훈;안병립;홍원화
    • 한국태양에너지학회 논문집
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    • 제31권2호
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    • pp.47-52
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    • 2011
  • Currently, Exterior wall's U-value about building envelope is 0.36 W/$m^2K$(Central Region), but window's one is 2.1 W/$m^2K$ according to air gap of glazing, filling gas, coating and type of windows. The door"s one is 1.6~5.5 W/$m^2{\cdot}K$ depending on material and configuration of door. As such, energy loss per unit of door is considerably larger like windows. The door for the recognition was relatively low because energy loss through the door is relatively small compared to window area. In this paper, thermal performance was analyzed through simulation targeting the door which has thermal break that can improve the insulation performance and doesn't have one. As a results of simulations, case1 was calculated as the average of 1.63 w/m2k and case 2 was calculated as the average of 4.14 w/m2k. The thermal performance of door depends on the type and condition of insulations. As a results of final simulations, Case1 was calculated as 1.06 w/m2k and Case2 was calculated as 1.27 w/m2k. As a results of the experiments, thermal performance of case 1 was measured as 1.28 w/m2k. Error between experiments and simulations is considered problems encountered when creating the samples. The effect of door frame on the overall thermal performance is slight because it's a small proportion of the door frame.

𝛑-공액계 분자의 삼중항 여기 상태에 대한 Density Functional Theory (DFT)에 기반한 계산 방법들의 비교: 시간-의존 DFT (TD-DFT), Tamm-Dancoff 근사법을 적용한 DFT (TDA-DFT), 스핀-비제한 DFT (UDFT) (A Comparison of the Density Functional Theory Based Methodologies for the Triplet Excited State of 𝛑-Conjugated Molecules: Time-Dependent DFT (TD-DFT), TD-DFT within Tamm-Dancoff Approximation (TDA-DFT), and Spin-Unrestricted DFT (UDFT))

  • 안창환;김동욱
    • 대한화학회지
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    • 제63권2호
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    • pp.73-77
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    • 2019
  • ${\pi}$-공액계 분자에 대해, density functional theory (DFT) 방법에 기반한 일반적인 삼중항 구조 최적화 방법들, 즉, 시간 의존적 DFT (TD-DFT), Tamm-Dancoff 근사법에 기반한 TD-DFT (TDA-DFT), 그리고 스핀-비제한 DFT (UDFT)에 대한 점검을 수행하였다. 모델 분자로서 1,2,3,4,5-pentacyano-6-phenyl-benzene가 이용되었고, 6-31G(d) 기저 함수와 더불어 여기 상태 계산에 최근 자주 사용되는 에너지 차 조정 영역 분리 functional인 ${\omega}B97X$ functional이 사용되었다. 계산 결과 평형 구조 근처에서, UDFT 최적화된 구조는 TD-DFT 및 TDA-DFT 계산 구조와는 다른 차이점을 보인다. 즉, 보다 안정한 바닥 상태 에너지와 보다 높은 삼중항 여기 에너지가 UDFT 최적화 구조에서 보인다. 본 논문에서는 이러한 차이에 대해 보다 자세히 토의된다.

PRAM용 Cu-도핑된 Ge8Sb2Te11 박막의 특성 (Characteristics of Cu-Doped Ge8Sb2Te11 Thin Films for PRAM)

  • 김영미;공헌;김병철;이현용
    • 한국전기전자재료학회논문지
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    • 제32권5호
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    • pp.376-381
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    • 2019
  • In this work, we evaluated the structural, electrical and optical properties of $Ge_8Sb_2Te_{11}$ and Cu-doped $Ge_8Sb_2Te_{11}$ thin films prepared by rf-magnetron reactive sputtering. The 200-nm-thick deposited films were annealed in a range of $100{\sim}400^{\circ}C$ using a furnace in an $N_2$ atmosphere. The amorphous-to-crystalline phase changes of the thin films were investigated by X-ray diffraction (XRD), UV-Vis-IR spectrophotometry, a 4-point probe, and a source meter. A one-step phase transformation from amorphous to face-centered-cubic (fcc) and an increase of the crystallization temperature ($T_c$) was observed in the Cu-doped film, which indicates an enhanced thermal stability in the amorphous state. The difference in the optical energy band gap ($E_{op}$) between the amorphous and crystalline phases was relatively large, approximately 0.38~0.41 eV, which is beneficial for reducing the noise in the memory devices. The sheet resistance($R_s$) of the amorphous phase in the Cu-doped film was about 1.5 orders larger than that in undoped film. A large $R_s$ in the amorphous phase will reduce the programming current in the memory device. An increase of threshold voltage ($V_{th}$) was seen in the Cu-doped film, which implied a high thermal efficiency. This suggests that the Cu-doped $Ge_8Sb_2Te_{11}$ thin film is a good candidate for PRAM.

Species diversity and distribution of the genus Colpomenia (Scytosiphonaceae, Phaeophyceae) along the coast of China

  • Song, Xiao-Han;Hu, Zi-Min;Sun, Zhong-Min;Draisma, Stefano G.A.;Fresia, Pablo;Duan, De-Lin
    • ALGAE
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    • 제34권3호
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    • pp.217-228
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    • 2019
  • The marine brown algal genus Colpomenia has a worldwide distribution, with five species reported in Korea and Japan. However, no studies to date attempted to identify the number of species and geographical distribution of Colpomenia along Chinese coast. To fill the biodiversity knowledge gap, we analyzed 63 mitochondrial cox3 and 62 mitochondrial atp6 sequences of Colpomenia specimens collected from 30 localities along the Chinese coast. Maximum likelihood and Bayesian inference trees suggest the presence of at least three Colpomenia species (i.e., C. peregrina, C. claytoniae, and C. sinuosa) in China. C. peregrina and C. claytoniae are documented for the first time. C. sinuosa was only found in the South China Sea and its distribution didn't overlap with that of C. peregrina which was found in the Yellow-Bohai Sea and the East China Sea. C. claytoniae appears to be confined to three isolated islands in the East and the South China Sea, where it occurs in sympatry with, respectively, C. peregrina and C. sinuosa. Future study can focus on comparing eco-physiological differences of Colpomenia species in response to environmental variables and exploring possible genetic hybridization / introgression at inter-specific contact zones.