• Title/Summary/Keyword: T-H-M behavior

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Growth of Zn0.4Fe2.6O4 Thin Films using Pulsed Laser Deposition and their Crystal Structural and Magnetic Properties (Pulsed Laser Deposition을 이용한 Zn0.4Fe2.6O4 박막의 합성과 그 결정성 및 자기적 특성의 연구)

  • Jang, A.N.;Song, J.H.;Park, C.Y.
    • Journal of the Korean Magnetics Society
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    • v.21 no.3
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    • pp.88-92
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    • 2011
  • We grew $Zn_{0.4}Fe_{2.6}O_4$ thin films using Pulsed Laser Deposition and studied their crystal structure and magnetical characteristics as a function of growth temperature ($T_g$). For the film with $T_g=300^{\circ}C$, X-ray reflections from ${\alpha}-Fe_2O_3$ and ZnO were observed. However, when $T_g$ was increased from 300 to $500^{\circ}C$, crystal structure of inverse spinel was stabilized with the crystal orientation of $Zn_{0.4}Fe_{2.6}O_4(111)/Al_2O_3(0001)$ without any detection of ${\alpha}-Fe_2O_3$ and ZnO phases. The surface morphology shows flattening behavior with increasing $T_g$ from 300 to $500^{\circ}C$. These observations indicate that Zn is substituted into tetrahedron A-site of the inverse-spinel $Fe_3O_4$. M-H curves exhibit clear ferromagnetism for the sample with $T_g=500^{\circ}C$ whereas no ferromagnetism is observed for the film with $T_g=300^{\circ}C$.

Enhanced Magnetic Properties of BiFe1-$_xNi_xO_3$

  • Yoo, Y.J.;Hwang, J.S.;Park, J.S.;Kang, J.H.;Lee, B.W.;Lee, S.J.;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.183-183
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    • 2011
  • Multiferroic materials have been widely studied in recent years, because of their abundant physics and potential applications in the sensors, data storage, and spintronics. $BiFeO_3$ is one of the well-known single-phase multiferroic materials with $ABO_3$ structure and G-type antiferromagnetic behavior below the Neel temperature $T_N$ ~ 643 K, but the ferroelectric behavior below the Curie temperature $T_c$~1,103 K. In this study, the $BiFe_{1-x}Ni_xO_3$ (x=0 and 0.05) bulk ceramics were prepared by solid-state reaction and rapid sintering with high-purity $Bi_2O_32$, $Fe_3O_4$ and NiO powders. The powders of stoichiometric proportions were mixed, as in the previous investigations, and calcined at 450$^{\circ}C$ for $BiFe_{1-x}Ni_xO_3$ for 24 h. The obtained powders were grinded, and pressed into 5-mm-thick disks of 1/2-inch diameter. The disks were directly put into the oven, which has been heated up to 800$^{\circ}C$ and sintered in air for 20 min. The sintered disks were taken out from the oven and cooled to room temperature within several min. The phase of samples was checked at room temperature by powder x-ray diffraction using a Rigaku Miniflex diffractometer with Cu K${\alpha}$ radiation. The Raman measurements were carried out by employing a hand-made Raman spectrometer with 514.5-nm-excitation $Ar^+$ laser source under air ambient condition on a focused area of 1-${\mu}m$ diameter. The field-dependent magnetization measurements were performed with a superconducting quantum-interference-device magnetometer.

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Kinetic behavior of sophoricoside by gas chromatography/mass spectrometry in rats

  • Jeon, Hee-Kyung;Park, Hae-Yeon;Kim, Youn-Jung;Kim, Youngsoo;Kim, Mi-Kyung;Lee, Seung-Ho;Jung, Sang-Hun;Ryu, Jae-Chun
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.189-189
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    • 2003
  • Sophoricoside was isolated as the inhibitor of IL-5 bioactivity from Sophora japonica (Leguminosae). To develope as novel anti-allergic drug, kinetic study was performed in rats. Serum concentration of sophoricoside was measured by gas chromatography-mass spectrometry (GC/MS) in male Sprague-Dawley rat (250${\pm}$10g, n=5) after oral administration of sophoricoside (100mg/kg). The recovery of sophoricoside after extraction and concentration was above 95 % from rat serum. Between-day precision(relative standard deviation 2.2-2.8%) and within-day precision(2.0-12.1%) were determined from replicate analysis of a spiked control and incurred serum sample. The detection limits of sophoricoside in this serum was approximately 0.1 ng/mL. The Pharmacokinetic parameters were derived from the noncompartmental analysis. The C$\_$max/(3.56${\pm}$0.34 $\mu\textrm{g}$/mL) value for sophoricoside in male rat was observed at 7.6 h. The elimination half-life(t$\_$1/2/) of sophoricoside was approximately 4.47 h, the mean residence time (MRT) averaged 10.75 h, the total body clearance (Cl) averaged 0.0042 mL/min/kg. and the area under the serum concentration-time curve (AUC$\_$0-$\infty$/) was 24.93 $\mu\textrm{g}$$.$hr/mL.

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An experimental study on the Behaviour of Concrete-Filled Square Steel Tubular Column·H-Beam End-plate Connections with Penetrated HT-Bolts (관통형 고력볼트를 사용한 엔드플레이트형식 콘크리트 충전 각형강관 기둥-H형강 보 접합부의 거동에 관한 실험적연구)

  • Kim, Jae Keon;Lee, Myong Jae;Lee, Seung Joon;Moon, Tae Sup
    • Journal of Korean Society of Steel Construction
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    • v.10 no.2 s.35
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    • pp.211-219
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    • 1998
  • The objective of this study is to investigate the structural behavior of Concrete-Filled Tubular Column H-Beam End-Plate Connections with Penetrated HT-Bolts under monotonic load. Simple bending tests are carried out with 5 kinds of specimens including beam specimen. The parameters of these tests are the thickness (T=22, 26. 30mm) of End-plates and the diameter (M=20, 22mm) of bolts. From the tests, the increasing values of yielding strength and initial stiffness of each specimen were gained as the thickness of End-plates and diameter of bolts are increasing. And the application of Bjorhovde et al and Eurocode 3 classification method by non-dimensional moment-rotation curves to the connections showed that all of them are included in rigid region as far as initial stiffness is concerned and all of them are also rigid as far as ultimate strength.

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A RANDOM DISPERSION SCHRÖDINGER EQUATION WITH NONLINEAR TIME-DEPENDENT LOSS/GAIN

  • Jian, Hui;Liu, Bin
    • Bulletin of the Korean Mathematical Society
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    • v.54 no.4
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    • pp.1195-1219
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    • 2017
  • In this paper, the limit behavior of solution for the $Schr{\ddot{o}}dinger$ equation with random dispersion and time-dependent nonlinear loss/gain: $idu+{\frac{1}{{\varepsilon}}}m({\frac{t}{{\varepsilon}^2}}){\partial}_{xx}udt+{\mid}u{\mid}^{2{\sigma}}udt+i{\varepsilon}a(t){\mid}u{\mid}^{2{\sigma}_0}udt=0$ is studied. Combining stochastic Strichartz-type estimates with $L^2$ norm estimates, we first derive the global existence for $L^2$ and $H^1$ solution of the stochastic $Schr{\ddot{o}}dinger$ equation with white noise dispersion and time-dependent loss/gain: $idu+{\Delta}u{\circ}d{\beta}+{\mid}u{\mid}^{2{\sigma}}udt+ia(t){\mid}u{\mid}^{2{\sigma}_0}udt=0$. Secondly, we prove rigorously the global diffusion-approximation limit of the solution for the former as ${\varepsilon}{\rightarrow}0$ in one-dimensional $L^2$ subcritical and critical cases.

Combustion Behavior in a Solid Fuel Ramjet Combustor (고체 램제트 추진기관 연소실에서의 연소 현상)

  • Lee, T. H.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.3
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    • pp.25-30
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    • 1999
  • An experimental investigation was conducted to explore the effects of air mass flux on the combustion efficiency and particle size distributions in a solid fuel ramjet using a fuel grain highly loaded with boron carbide. Particle distributions were measured at the grain exit and at the nozz1e entrance using a Malvern 2600 HSD. Combustion efficiency increased with decreasing air mass flux. In general, the particle distribution was trimodal or quadrimodal with node peaks at approximately 4, 15, and 25$\mu\textrm{m}$ and possibly one at less than 2$\mu\textrm{m}$. The larger particles were the result of surface agglomeration, primarily within the recirculation region. Higher inlet air temperature produced higher combustion efficiencies, apparently the result of enhanced combustion of the larger boron carbide particles that burn in a diffusion controlled regime.

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The Large Magnetocaloric Effect in Amorphous Fe80-xMnxZr10 (x = 4,6,8,10) Alloys

  • Moon, Y.M.;Min, S.G;Kim, K.S.;Yu, S.C.;Kim, Y.C.;Kim, K.Y.
    • Journal of Magnetics
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    • v.10 no.4
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    • pp.142-144
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    • 2005
  • The Magnetization behaviour has been measured for amorphous $Fe_{80-x}Mn_xZr_{10}$ (x = 4,6,8,10) alloys. The Curie temperature decreased from 236 K to 195 K with increasing Mn concentration (x = 4 to x = 10). The magnetization measurements were conducted at temperatures above the Curie temperature in the paramagnetic region. In all samples, the magnetic properties showed superparamagnetic behavior above $T_c$ where the mean magnetic moment of the superparamagnetic spin clusters decreased with increasing temperature. A large magnetic entropy change, ${\Delta}S_M$, which is calculated from H vs M curves associated with the ferromagnetic-paramagnetic transitions in amorphous, has been observed. With Mn concentration increasing, ${\Delta}S_M$ decreases 1.04, 0.95, 0.87 J/kg K at 222, 210, 195 K (the Curie temperature), respectively.

Large Eddy Simulation for the Prediction of Unsteady Dispersion Behavior of Hydrogen Fluoride (불산의 비정상 확산거동 예측을 위한 대와동모사)

  • Ko, M.W.;Oh, Chang Bo;Han, Y.S.;Choi, B.I.;Do, K.H.;Kim, M.B.;Kim, T.H.
    • Journal of the Korean Society of Safety
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    • v.30 no.1
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    • pp.14-20
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    • 2015
  • A Large Eddy Simulation(LES) was performed for the prediction of unsteady dispersion behavior of hydrogen fluoride (HF). The HF leakage accident occurred at the Gumi fourth industrial complex was numerically investigated using the Fire Dynamics Simulator (FDS) based on the LES. The accident area was modeled three-dimensionally and time-varying boundary conditions for wind were adopted in the simulation for considering the realistic accident conditions. The Message Passing Interface (MPI) parallel computation technique was used to reduce the computational time. As a result, it was found that the present LES simulation could predict the unsteady dispersion features of HF near the accident area effectively. The dispersion behaviors of the leaked HF was much affected by the unsteady wind direction. The LES could predict the time variation of the HF concentration reasonably and give an useful information for the risk analysis while the prediction with the time-averaging concept of HF concentration had a limitation for the amount of HF concentration at specific location point. It was identified that the LES is very useful to predict the dispersion characteristics of hazardous chemicals.

Effects of Hydrological Condition on the Coupled Thermal-Hydrological-Mechanical Behavior of Rock Mass Surrounding Cavern Thermal Energy Storage (암반 공동 열에너지저장소 주변 암반의 수리적 조건에 따른 열-수리-역학적 연계거동 분석)

  • Park, Jung-Wook;Rutqvist, Jonny;Lee, Hang Bok;Ryu, Dongwoo;Synn, Joong-Ho;Park, Eui-Seob
    • Tunnel and Underground Space
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    • v.25 no.2
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    • pp.168-185
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    • 2015
  • The thermal-hydrological-mechanical (T-H-M) behavior of rock mass surrounding a large-scale high-temperature cavern thermal energy storage (CTES) at a shallow depth has been investigated, and the effects of hydrological conditions such as water table and rock permeability on the behavior have been examined. The liquid saturation of ground water around a storage cavern may have a small impact on the overall heat transfer and mechanical behavior of surrounding rock mass for a relatively low rock permeability of $10^{-17}m^2$. In terms of the distributions of temperature, stress and displacement of the surrounding rock mass, the results expected from the simulation with the cavern below the water table were almost identical to that obtained from the simulation with the cavern in the unsaturated zone. The heat transfer in the rock mass with reasonable permeability ${\leq}10^{-15}m^2$ was dominated by the conduction. In the simulation with rock permeability of $10^{-12}m^2$, however, the convective heat transfer by ground-water was dominant, accompanying the upward heat flow to near-ground surface. The temperature and pressure around a storage cavern showed different distributions according to the rock permeability, as a result of the complex coupled processes such as the heat transfer by multi-phase flow and the evaporation of ground-water.

The Mechanical Behavior of Jointed Rock Masses by Using PFC2D (PFC2D를 이용한 절리암반의 역학적 물성 평가연구)

  • Park Eui-Seob;Ryu Chang-Ha
    • Tunnel and Underground Space
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    • v.15 no.2 s.55
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    • pp.119-128
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    • 2005
  • Although the evaluation of the mechanical properties and behavior of jointed rock masses is very important for the design of tunnel and underground openings, it has always been considered the most difficult problem. One of the difficulties in describing the rock mass behavior is the selection of the appropriate constitutive model. This limitation may be overcome with the progress in discrete element software such as PFC, which does not need the user to prescribe a constitutive model for rock mass. In this paper, a 30\;m\;\times\;30\;m\;\times\;30\;m m jointed rock mass of road tunnel site was analyzed. h discrete fracture network was developed from the joint geometry obtained from core logging and surface survey. Using the discontinuities geometry from the DFN model, PFC simulations were carried out, starting with the intact rock and systematically adding the joints and the stress-strain response was recorded for each case. With the stress-strain response curves, the mechanical properties of jointed rock masses were determined. As expected, the presence of joints had a pronounced effect on mechanical properties of the rock mass. More importantly, getting the mechanical response of the PFC model doesn't require a user specified constitutive model.