• 제목/요약/키워드: Synthesis parameters

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An Overrun Control Method and its Synthesis Method for Real-Time Systems with Probabilistic Timing Constraints (확률적인 시간 제약 조건을 갖는 실시간 시스템을 위한 과실행 제어 및 합성 기법)

  • Kim, Kang-Hee;Hwang, Ho-Young
    • Journal of KIISE:Computer Systems and Theory
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    • v.32 no.5
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    • pp.243-254
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    • 2005
  • Soft real-time applications such as multimedia feature highly variable processor requirements and probabilistic guarantees on deadline misses, meaning that each task in the application meets its deadline with a given probability. Thus, for such soft real-time applications, a system designer may want to improve the system utilization by allocating to each task a processor time less than its worst-case requirement, as long as the imposed probabilistic timing constraint is met. In this case, however, we have to address how to schedule jobs of a task that require more than (or, overrun) the allocated processor time to the task. In this paper, to address the overrun problem, we propose an overrun control method, which probabilistically controls the execution of overrunning jobs. The proposed overrun control method probabilistically allows overrunning jobs to complete for better system utilization, and also probabilistically prevents the overrunning jobs from completing so that the required probabilistic timing constraint for each task can be met. In the paper, we show that the proposed method outperforms previous methods proposed in the literature in terms of the overall deadline miss ratio, and that it is possible to synthesize the scheduling parameters of our method so that all tasks can meet the given probabilistic timing constraints.

A Study on Synthesis and Hydrolysis of the Maleated Polyethylene Wax (무수말레인산으로 그라프트된 폴리에틸렌 왁스의 중합과 가수분해에 대한 연구)

  • Yu, Si-Won;Choi, Joong-So;Na, Jae-Sik
    • Clean Technology
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    • v.19 no.4
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    • pp.393-400
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    • 2013
  • In this study, Polyethylene wax, which was produced in manufacturing process of high density polyethylene was grafted with maleic anhydride (MAH). The influences of reaction parameters on the graft polymerization as well as the effect of hydrolysis of the anhydride functions were investigated. The results show that the grafting degree increased and conversion of maleic anhydride decreased with an increase in MAH monomer content. This means the highest grafting efficiency for the reaction can be met when MAH monomer content is about 15 wt%. DCP (dicumyl peroxide) and DTBP (di-tert-butyl peroxide) have been used as the initiator and the highest yield of grafting was obtained when the initiator content is about 0.5 wt%. However, It can be seen that the gel content values of this polyethylene wax grafted MAH were below 2%. It was also observed that the grafting degree increased with an increase in reaction temperature and the maximum value was reached 2 hours later. Although MAH functions grafted onto polyethylene wax were mainly in the carboxylic acid forms, some anhydride form of MAH appeared in over 5% of grafting degree. As a result of hydrolysis reaction, it was observed that the conversion of anhydride group into carboxylic acid group was reached up to 10%.

V700 Cygni: A Dynamically Active W UMa-type Binary Star II

  • Kim, Chun-Hwey;Jeong, Jang-Hae
    • Journal of Astronomy and Space Sciences
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    • v.29 no.2
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    • pp.151-161
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    • 2012
  • An intensive analysis of 148 timings of V700 Cyg was performed, including our new timings and 59 timings calculated from the super wide angle search for planets (SWASP) observations, and the dynamical evidence of the W UMa W subtype binary was examined. It was found that the orbital period of the system has varied over approximately $66^y$ in two complicated cyclical components superposed on a weak upward parabolic path. The orbital period secularly increased at a rate of $+8.7({\pm}3.4){\times}10^{-9}$ day/year, which is one order of magnitude lower than those obtained by previous investigators. The small secular period increase is interpreted as a combination of both angular momentum loss (due to magnetic braking) and mass-transfer from the less massive component to the more massive component. One cyclical component had a $20.^y3$ period with an amplitude of $0.^d0037$, and the other had a $62.^y8$ period with an amplitude of $0.^d0258$. The components had an approximate 1:3 relation between their periods and a 1:7 ratio between their amplitudes. Two plausible mechanisms (i.e., the light-time effects [LTEs] caused by the presence of additional bodies and the Applegate model) were considered as possible explanations for the cyclical components. Based on the LTE interpretation, the minimum masses of 0.29 $M_{\odot}$ for the shorter period and 0.50 $M_{\odot}$ for the longer one were calculated. The total light contributions were within 5%, which was in agreement with the 3% third-light obtained from the light curve synthesis performed by Yang & Dai (2009). The Applegate model parameters show that the root mean square luminosity variations (relative to the luminosities of the eclipsing components) are 3 times smaller than the nominal value (${\Delta}L/L_{p,s}{\approx}0.1$), indicating that the variations are hardly detectable from the light curves. Presently, the LTE interpretation (due to the third and fourth stars) is preferred as the possible cause of the two cycling period changes. A possible evolutionary implication for the V700 Cyg system is discussed.

A Kinetic Study of Steam Gasification of Woodchip, Sawdust and Lignite (나무칩, 톱밥 바이오매스와 갈탄의 수증기 가스화반응 특성 연구)

  • Kim, Kyungwook;Bungay, Vergel C.;Song, Byungho;Choi, Youngtai;Lee, Jeungwoo
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.506-512
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    • 2013
  • Biomass and low-grade coals are known to be better potential sources of energy compared to crude oil and natural gas since these materials are readily available and found to have large reserves, respectively. Gasification of these carbonaceous materials produced syngas for chemical synthesis and power generation. Woodchip, sawdust and lignite were gasified with steam in a thermobalance reactor under atmospheric pressure in order to evaluate their kinetic rate information. The effects of gasification temperature ($600{\sim}900^{\circ}C$) and partial pressure of steam (20~90 kPa) on the gasification rate were investigated. The three different types of gas-solid reaction models were applied to the experimental data to predict the behavior of the gasification reactions. The modified volumetric model predicted the conversion data well, thus the model was used to evaluate kinetic parameters in this study. The observed activation energy of biomass, sawdust and lignite gasification reactions were found to be in reasonable range and their rank was found to be sawdust > woodchip > lignite. The expression of apparent reaction rates for steam gasification of the three solids was proposed to provide basic information on the design of coal gasification processes.

Dynamic Optimization of a Reactive Distillation Column Producing Methyl Acetate (메틸 아세테이트 생산을 위한 반응증류 공정의 동적 최적화)

  • Kim, Jiyong;Kim, Junghwan;Moon, Il
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.739-746
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    • 2008
  • The aim of this study is finding the optimal design parameters and the optimal operation variables of a reactive distillation column. Different from steady state optimization, dynamic optimization makes it possible considering operation ability as well as design problems at process design step. For performing dynamic optimization, dynamic simulation should be done first. If dynamic simulation is already finished, dynamic optimization can be performed with less effort than that of dynamic simulation.Reactive distillation systems involving reaction and separation in a single unit have the potential to reduce capital and operating costs, particularly when reaction have conversion constraint or when azeotropes exist making conventional separation difficult and expensive. This study here present work on the continuous distillation process, the homogeneous catalyzed esterification of methanol and acetic acid, the synthesis of methyl acetate. Based on an equilibrium stage model of a reactive distillation column a dynamic optimization problem was formulated and solved. And the results were verified by performing dynamic simulation and showing the variation of conversion and purity as the variation of the operation variables. As the results of dynamic optimization, this study found optimal feed ratio, reflux ratio and reboiler duty of this system. And as this study applied it to dynamic simulations the dynamic characteristics of a reactive distillation column are showed under optimal operating condition.

Synthesis, Potentiometric, Spectral Characterization and Microbial Studies of Transition Metal Complexes with Tridentate Ligand (세자리 리간드의 전이금속 착물에 대한 합성과 전위차 및 분광학적 확인 그리고 미생물학적 연구)

  • Jadhav, S.M.;Munde, A.S.;Shankarwar, S.G.;Patharkar, V.R.;Shelke, V.A.;Chondhekar, T.K.
    • Journal of the Korean Chemical Society
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    • v.54 no.5
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    • pp.515-522
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    • 2010
  • A relation between antimicrobial activities and the formation constants of solid complexes of Cu(II), Ni(II), Co(II), Mn(II) and Fe(III) with tridentate Schiff base ligand, 4-hydroxy-3(1-{2-(benzylideneamino)-phenylimino}-ethyl)-6-methyl-2Hpyran-2-one (HL) derived from o-phenylene diamines, dehydroacetic acid (DHA) and p-chloro benzaldehyde have been studied. The ligand and metal complexes were characterized by elemental analysis, conductivity, magnetic susceptibility, thermal analysis, X-ray diffraction, IR, $^1H$-NMR, UV-vis and mass spectra. From the analytical data, the stiochiometry of the complexes was found to be 1:2 (metal:ligand) with octahedral geometry. The molar conductance values suggest the nonelectrolytic nature of metal complexes. The X-ray diffraction data suggests monoclinic crystal system for Ni(II) and orthorhombic crystal system for Cu(II) and Co(II) complexes. The IR spectral data suggest that the ligand behaves as tridentate ligand with ONN donor atoms sequence towards central metal ion. Thermal behavior (TG/DTA) and kinetic parameters calculated by Coats-Redfern method suggests more ordered activated state in complex formation. The protonation constants of the complexes were determined potentiometrically in THF:water (60:40) medium at $25^{\circ}C$ and ionic strength ${\mu}=0.1\;M$ ($NaClO_4$). Antibacterial activities in vitro were performed against Staphylococcus aureu and Escherichia coli. Antifungal activities were studied against Aspergillus Niger and Trichoderma. The effect of the metal ions and stabilities of complexes on antimicrobial activities are discussed.

Synthesis and Magnetic Properties of Zn, Co and Ni Substituted Manganese Ferrite Powders by Sol-gel Method

  • Kwon, Woo-Hyun;Kang, Jeoung-Yun;Lee, Jae-Gwang;Lee, Seung-Wha;Chae, Kwang-Pyo
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.159-164
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    • 2010
  • The Zn, Co and Ni substituted manganese ferrite powders, $Mn_{1-x}$(Zn, Co, Ni)$_xFe_2O_4$, were fabricated by the solgel method, and their crystallographic and magnetic properties were studied. The Zn substituted manganese ferrite, $Zn_{0.2}Mn_{0.8}Fe_2O_4$, had a single spinel structure above $400^{\circ}C$, and the size of the particles of the ferrite powder increased when the annealing temperature was increased. Above $500^{\circ}C$, all the $Mn_{1-x}$(Zn, Co, Ni)$_xFe_2O_4$ ferrite had a single spinel structure and the lattice constants decreased with an increasing substitution of Zn, Co, and Ni in $Mn_{1-x}$(Zn, Co, Ni)$_xFe_2O_4$. The Mossbauer spectra of $Mn_{1-x}Zn_xFe_2O_4$ (0.0$\leq$x$\leq$0.4) could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. For x = 0.6 and 0.8 they showed two Zeeman sextets and a single quadrupole doublet, which indicated they were ferrimagnetic and paramagnetic. And for x = 1.0 spectrum showed a doublet due to a paramagnetic phase. For the Co and Ni substituted manganese ferrite powders, all the Mossbauer spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. The variation of the Mossbauer parameters are also discussed with substituted Zn, Co and Ni ions. The increment of the saturation magnetization up to x = 0.6 in $Mn_{1-x}Co_xFe_2O_4$ could be qualitatively explained using the site distribution and the spin magnetic moment of substituted ions. The saturation magnetization and coercivity of the $Mn_{1-x}$(Zn, Co, Ni)$_xFe_2O_4$ (x = 0.4) ferrite powders were also compared with pure $MnFe_2O_4$.

Time-Scale Modification of Polyphonic Audio Signals Using Sinusoidal Modeling (정현파 모델링을 이용한 폴리포닉 오디오 신호의 시간축 변화)

  • 장호근;박주성
    • The Journal of the Acoustical Society of Korea
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    • v.20 no.2
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    • pp.77-85
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    • 2001
  • This paper proposes a method of time-scale modification of polyphonic audio signals based on a sinusoidal model. The signals are modeled with sinusoidal component and noise component. A multiresolution filter bank is designed which splits the input signal into six octave-spaced subbands without aliasing and sinusoidal modeling is applied to each subband signal. To alleviate smearing of transients in time-scale modification a dynamic segmentation method is applied to subbands which determines the analysis-synthesis frame size adaptively to fit time-frequency characteristics of the subband signal. For extracting sinusoidal components and calculating their parameters matching pursuit algorithm is applied to each analysis frame of subband signal. In accordance with spectrum analysis a psychoacoustic model implementing the effect of frequency masking is incorporated with matching pursuit to provide a resonable stop condition of iteration and reduce the number of sinusoids. The noise component obtained by subtracting the synthesized signal with sinusoidal components from the original signal is modeled by line-segment model of short time spectrum envelope. For various polyphonic audio signals the result of simulation shows suggested sinusoidal modeling can synthesize original signal without loss of perceptual quality and do more robust and high quality time-scale modification for large scale factor because of representing transients without any perceptual loss.

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Recent Advances in Eco-friendly Nano-ink Technology for Display and Semiconductor Application (디스플레이 반도체 기술 적용을 위한 청정 나노잉크 제조 기술)

  • Kim, Jong-Woong;Hong, Sung-Jei;Kim, Young-Seok;Kim, Young-Sung;Lee, Jeong-No;Kang, Nam-Kee
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.1
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    • pp.33-39
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    • 2010
  • Printing technologies have been indicated as alternative methods for patterning conductive, semi-conductive or insulative materials on account of their low-cost, large-area patternability and pattern flexibility. For application of the printing technologies in manufacture of semiconductor or display modules, ink or paste composed of nanoparticles, solvent and additives are basically needed. Here, we report recent advances in eco-friendly nano-ink technology for semiconductor and display technology. Then, we will introduce an eco-friendly ink formation technology developed in our group with an example of manufacturing $SiO_2$ nanopowders and inks. We tried to manufacture ultrafine $SiO_2$ nanoparticles by applying a low-temperature synthetic method, and then attempted to fabricate the printed $SiO_2$ film onto the glass substrate to see whether the $SiO_2$ nanoparticles are feasible for the printing or not. Finally, the electrical characteristics of the films were measured to investigate the effect of the manufacturing parameters.

Architecture Design of High Performance H.264 CAVLC Encoder Using Optimized Searching Technique (최적화된 탐색기법을 이용한 고성능 H.264/AVC CAVLC 부호화기 구조 설계 기법)

  • Lee, Yang-Bok;Jung, Hong-Kyun;Kim, Chang-Ho;Myung, Je-Jin;Ryoo, Kwang-Ki
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.10a
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    • pp.431-435
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    • 2011
  • This paper presents optimized searching technique to improve the performance of H.264/AVC. The proposed CAVLC encoder uses forward and backward searching algorithm to compute the parameters. By zero-block skipping technique and pipelined scheduling, the proposed CAVLC encoder can obtain better performance. The experimental result shows that the proposed architecture needs only 66.6 cycles on average for each $16{\times}16$ macroblock encoding. The proposed architecture improves the performance by 13.8% than that of previous designs. The proposed CAVLC encoder was implemented using VerilogHDL and synthesized with Megnachip $0.18{\mu}m$ standard cell library. The synthesis result shows that the gate count is about 15.6K with 125Mhz clock frequency.

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