• 제목/요약/키워드: Surface state density

검색결과 311건 처리시간 0.028초

인이 도핑된 NiCo2O4 전극 제조 공정의 간소화를 통한 전극 특성의 변화 (Variations in electrode characteristics through simplification of phosphorus-doped NiCo2O4 electrode manufacturing process)

  • 이석희;차현진;박정환;손영국;황동현
    • 한국표면공학회지
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    • 제56권5호
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    • pp.299-308
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    • 2023
  • In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo2O4) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo2O4 and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo2O4 electrode exhibited a specific capacitance of 1,129 Fg-1 at a current density of 1 Ag-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo2O4 electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.

내력밀도법을 이용한 텐세그러티 구조물의 안정화 기법에 관한 연구 (A Study on the Stabilization Process of Tensegrity System using the Force Density Method)

  • 서삼열;고광웅
    • 한국공간구조학회논문집
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    • 제3권4호
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    • pp.77-84
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    • 2003
  • Tensegrity systems are stable structures which are reticulated spatial structures composed of compressive straight members, struts and cables. But there are some difficulties concerning surface stability, surface formation and construction method. One of the ways to solve this problem reasonably is combination of tesile members and rigid members. This structure is a type of flexible strutural system which is unstable initially because the cable material has little initial rigidity. Therefore tensegrity structure need to be introduced to the Initial stress for the self-equilibrated system having stable state. The rigidification of tensegrity systems is related to selfstress states which can be achieved only when geometrical and mechanical requirements are simultaneously satisfied. In this paper, for the stabilization of tesnsegrity structure it is proposed the modified self-equilibrated equation and the range of the various geometrical parameter about unit system. And we generate the model of double layed single curvature arch using the new squew quadruplex unit system.

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분자동역학기법을 이용한 나노 임프린트 리소그래피 공정에서의 고분자 변형모사 (Deformation of Polymer Resist in NIL Process by Molecular Dynamic Simulation)

  • 우영석;이우일
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.337-342
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    • 2007
  • In this study, molecular dynamics simulation of nano imprint lithography in which patterned stamp is pressed onto amorphous polyethylene(PE) surface are performed to study the behaviour of polymer. Force fields including bond, angle, torsion, and Lennard Jones potential are used to describe the inter-molecular and intra-molecular force of PE molecules and stamp, substrate. Periodic boundary condition is used in horizontal direction and canonical NVT ensemble is used to control the system temperature. As the simulation results, the behaviour of polymer is investigated during the imprinting process. The mechanism of polymer deformation is studied by means of inspecting the surface shape, volume, density, atom distribution. Deformation of the polymer resist was found for various of the stamp geometry and the alignment state of the polymer molecules.

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무성방전내에서 톨루엔 제거에 미치는 운전변수의 영향 (Effects of Operating Parameters on Toluene Removal in Dielectric Barrier Discharge Process)

  • 정재우;이용환;박경렬
    • 한국대기환경학회지
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    • 제18권3호
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    • pp.173-182
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    • 2002
  • We investigated the effects of operating variables, such as electrical. reactor and gas parameters on toluene removal and discharge property in the dielectric barrier discharge (DBD) process. The toluene removal was initiated with the energy transfer to the reactor by loading of voltages higher than the discharge onset value. The energy transfer and toluene removal increased with the applied voltage. Higher removal rate was observed with smooth surface electrode despite of lower energy transfer compared with the coarse electrode, because more uniform discharge can be obtained on smooth surface state. The decrease of dielectric material thickness enhanced the removal efficiency by increasing the discharge potential. The toluene removal efficiency decreased with the increase of the inlet concentration. The increase of gas retention time enhanced the removal efficiency by the increase of energy density. The oxygen and humidity contents seem to exert significant influences on the toluene removal by dominating the generation of electrons, ions, and radicals which are key factors in the removal mechanism.

Relationship Between the Structure and the Superconductivity in LaFeAsO

  • Jung, Dongwoon;Cho, Sungwoo;Lee, In-Ja
    • Bulletin of the Korean Chemical Society
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    • 제34권3호
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    • pp.912-916
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    • 2013
  • The electronic structure of LaFeAsO was analyzed by tight-binding band calculation based upon the normal and shrunk lattices. A strong Fermi surface nesting was found in the normal LaFeAsO, while most of the nesting area was disappeared in the shrunk LaFeAsO. It was found, therefore, high pressure atmosphere is required to become a superconductor for LaFeAsO by suppressing the SDW (spin density wave) state through the disappearance of the Fermi surface nesting.

경량콘크리트 제조를 위한 경량골재 사전흡수수 품질관리방안 (A Study on The Quality Control of Pre-absorbed Water Light-weight Aggregate Concrete)

  • 임상준;이한우;이병수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 추계 학술논문 발표대회
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    • pp.199-200
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    • 2011
  • Absorption of lightweight aggregate affects the properties of fresh and hardened concrete, so care must be taken. In this study, according to KS F 2533 absorption is measured to aggregate size, submerged time, holding time and practically ways to maintain a constant absorption was to seek. The findings for quality control of the lightweight aggregate concrete mixture is saturation of the surface-dry aggregate humidity 100% after 24 hours immersion in the environment has been stored for more than two days to absorb the state was able to define. Dry density at the surface of the lightweight aggregate and lightweight concrete mix design and placement is possible for it to apply.

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알루미늄 양극산화피막의 생성기구 (The mechanism of the formation of an anodic oxide layer on the aluminium)

  • 박순;강탁
    • 한국표면공학회지
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    • 제12권3호
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    • pp.167-173
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    • 1979
  • The structure of anodic aluminium oxide films formed in 2% oxalic asid at constant temperature was studied by the oid of the transmission and replica electron microscopy. Far the initial stage of oxidations, it is observed that pores are initiated from lattice defects as subgrain boundaries, and then spread radially. Some pores merge each other and the others cease to grow until the current density reaches to the steady state. The pore diameter and the cell size are proportional to the anodizing voltages, and it is considered that the pore initiation and growth are largely controlled by the field - assisted oxide dissolution.

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Surface Properties of the Hydrazinolyzed Poly(ethylene terephthalate)/Nylon 6 Fibers

  • Park, Hyeong-Sup;Gi, Moon-Seong;Jeong, Seok-Kyu;Park, Soo-Min
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1996년도 춘계학술발표회 논문집
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    • pp.158-161
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    • 1996
  • Microfibers of Poly(ethylene terephthalate)(PET)/Nylon 6 (P/N) was heat set at 170C in a fixed state and then treated with hydrazine at 30C for 5, 10, 15, 20, 30 and 40 h. Weight loss from the hydrazine treatment increased according to the hydrazine concentration(Fig.1). In order to investigate in detail the effect of the electrostatic attraction between the dye anion and hydrazide groups in cooperated by hydrazinolysis, -potential of P/N fiber was measured by streaming potential method. The surface charge density, o, of the fiber was evaluated from the -potential.

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로드/언로드 성능향상을 위한 서스펜션 상태행렬 연구 (A study on suspension state matrix to improve load/unload performance)

  • 이용현;김기훈;김석환;박노철;박영필;박경수;김철순
    • 정보저장시스템학회논문집
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    • 제5권1호
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    • pp.47-52
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    • 2009
  • Most hard disk drives that apply the ramp load/unload technology unload the heads at the outer edge of the disk while the disk is rotating. The load/unload includes the benefits as like an increased areal density, a reduced power consumption and an improved shock resistance. A lot of papers investigating the effects of the various load/unload parameters such as a suspension tab, a limiter, a ramp and air-bearing surface designs have been published. However, in previous researches, an effect of the suspension is not considered at each load/unload step. In this paper, we focus that a variation of the state matrix affects the load/unload performance on based on a state matrix that is a stiffness matrix of the suspension. Because the state matrix is related to the suspension at each load/unload step, to change the state matrix means the structural change of the suspension. Therefore, we investigated a range of a pitch static attitude(PSA) and a roll static attitude(RSA) for load/unload performance. We also analyzed an effect of the variation of the state matrix a range of load/unload velocity occurred a slider-disk contact. We determined the variation of the state matrix to improve the load/unload performance through comparison of each factor of state matrix.

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터보 냉동기용 핀튜브에 관한 연구 ( I ) - 응축 열전달에 관하여 - (A Study on Finned Tube Used in Turbo Refrigerator( I ) -for Condensation Hear Transfer-)

  • 조동현;한규일;김시영
    • 수산해양교육연구
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    • 제5권1호
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    • pp.31-44
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    • 1993
  • Through the early 1900's, the evolution of the surface condenser was closely tied to the development of steam engine and the turbine. As the chemical and petroleum industries evolved in the 1900's, the use of surface condensers in many different processes. Today, industry uses condensers in many shapes and sizes. The actual condensation process occurs on the outside surface of tubes. The nature of this surface geometry affects the condenser's heat transfer performance. The first condensers were built with plain tubes. As tube manufacturing techniques advanced, manufacturers started making tubes with integral fins. In the 1940's, fin densities were limited to about 600 to 700 fins per meter(fpm) because of manufacturing procedure. Today new manufacturing techniques allow production of tubes with fin densities ranging from 750 to 1600 fpm. The integral-fin tubes investigated in this paper are nominally 19 mm diameter. Eight tubes have been used with trapezodially shaped integral-fins having fin density from 748 to 1654 fpm and 10, 30 grooves. For comparison, tests are made using a plain tube having the same inside diameter and an outside diameter equal to that at the root of the fins for the finned tubes. Betty and Katz's theoretical modelis is used to predict the R-11 condensation coefficient on horizontal integral-fin tubes having 748, 1024 and 1299 fpm. Experiments are carried out using R-11 as working fluid. The refrigerant condensates at a saturation state of $30^{\circ}C$ on the outside tube surface cooled by coolant. The amount of noncondensable gases present in the test loop is reduced to a negligible value by repeated purging. For a given heat input to the boiler and given cooling water flow rate, all test data are taken at steady state. The observed heat transfer enhancement for the finned and grooved tubes significantly exceeded that to be expected on grounds of increased area. For the eight fin tubes and one plain tube tested, the best performance has been obtained with a tube having a fin density of 1299 fpm, and a fin bight of 1.2mm and 30 grooves.

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