• 제목/요약/키워드: Surface saturated reaction

검색결과 47건 처리시간 0.021초

Enzymatic reaction model for the production of symmetrical lipid molecules using the response surface methodology

  • Hong, Joon-Sun;Shin, Jung-Ah;Lee, Ki-Teak
    • 농업과학연구
    • /
    • 제45권2호
    • /
    • pp.265-282
    • /
    • 2018
  • The purpose of this research was to produce symmetric (Saturated-Unsaturated-Saturated, SUS) triacylglycerol (TAG) using palm stearin fraction oil (PSFO) and high oleic sunflower oil (HOSO) as substrates to replace cocoa butter. PSFO was blended with HOSO (1 : 2 weight ratio), and $lipozyme^{(R)}$ TLIM (20 weight % of the substrate) was added. Interesterification was carried out in a shaking water bath at $55^{\circ}C$ at 220 rpm for 6 hours. The response surface methodology (RSM) through the central composite face design was employed to observe the optimized SUS-TAG. The independent factors were the reaction temperature ($X_1$: 65, 75 and $85^{\circ}C$), reaction time ($X_2$: 1, 3 and 5 hours) and ratio of TLIM ($X_3$: 10, 15 and 20 weight %). The dependent variables were $Y_1$ = Saturated-Unsaturated-Unsaturated (SUU, area %), $Y_2=SUS$ (area %), $Y_3$ = Saturated-Saturated-Unsaturated (SSU, area %), $Y_4$ = Unsaturated-Unsaturated-Unsaturated (UUU, area %), and $Y_5=sn-2$ unsaturated fatty acid (area %). The optimal conditions from the central composite face design minimized acyl migration while maximizing the presence of unsaturated fatty acid at the sn-2 position (73.43 area %). The optimal conditions were $X_1=65^{\circ}C$, $X_2=1hour$, and $X_3=20weight%$. As a result of the response surface analysis, the lack of fits was found as $Y_1=0.622$, $Y_2=0.438$, $Y_3=0.264$, $Y_4=0.526$, and $Y_5=0.215$, and their $R^2$ were 0.897, 0.944, 0.826, 0.857, and 0.867, respectively.

외부 자격에 의한 수면상 단분자막의 동적 거동 (Dynamic Behaviors of Externally-stimulated Monolayers on the Water Surface)

  • 배명한;송경호;박태곤;박근호
    • 한국전기전자재료학회논문지
    • /
    • 제13권4호
    • /
    • pp.318-325
    • /
    • 2000
  • Dynamic behaviors of saturated-fatty acids $C_{16}$, $C_{18}$, $C_{20}$ and 8A5H with azobenzene were measured by displacement current method when the molecules are stimulated by pressure light and heat. When a barrier was compressed I-A, $\pi$-A isotherms of $C_{16}$, $C_{18}$, and $C_{20}$ were similar to each other but the displacement current of $C_{20}$ which has a long alkyl chain was relatively low. 8A5H showed the form of double liquid films and had a reversible reaction when a barrier was compressed and then expanded. When the molecules of 8A5H were stimulated by 365[nm] light the positive currents which were generated by the structural changes from trans to cis were measured. But the negative currents of the structural changes from cis to trans by 450[nm] light were too weak to detect. When the temperature of the water subphase was increased the surface pressures of the monolayers were increased early because of the thermal activations of the molecules and the double liquid films of 8A5H were disappeared above 40[$^{\circ}C$]EX>].

  • PDF

Fabrication of Hybrid Films Using Titanium Chloride and 2,4-hexadiyne-1,6-diol by Molecular Layer Deposition

  • 윤관혁;성명모
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.418-418
    • /
    • 2012
  • We fabricated a new type of hybrid film using molecular layer deposition (MLD). The MLD is a gas phase process analogous to atomic layer deposition (ALD) and also relies on a saturated surface reaction sequentially which results in the formation of a monolayer in each sequence. In the MLD process, polydiacetylene (PDA) layers were grown by repeated sequential surface reactions of titanium tetrachloride and 2,4-hexadiyne-1,6-diol with ultraviolet (UV) polymerization under a substrate temperature of $100^{\circ}C$. Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of the hybrid films. Polymerization of the hybrid films was confirmed by infrared (IR) spectroscopy and UV-Vis spectroscopy. Composition of the films was confirmed by IR spectroscopy and X-ray photoelectron (XP) spectroscopy. The titanium oxide cross-linked polydiacetylene (TiOPDA) hybrid films exhibited good thermal and mechanical stabilities.

  • PDF

쉴드 TBM 굴진에 따른 포화 점성토 지반의 침하거동을 고려한 한계 굴진면압과 한계 뒤채움압 (Critical face pressure and backfill pressure of shield TBM considering surface settlements of saturated clayey ground)

  • 김기석;오주영;이효범;최항석
    • 한국터널지하공간학회 논문집
    • /
    • 제20권2호
    • /
    • pp.433-452
    • /
    • 2018
  • 쉴드 TBM 공법은 터널 굴착으로 인한 터널 굴진면과 굴착면의 변형을 억제하여 지반의 변형을 최소화할 수 있는 공법이다. 이를 위해 쉴드 TBM의 운전 조건들을 적절히 제어하는 것은 매우 중요하다. 쉴드 TBM 공법의 여러 가지 운전 조건 중 굴진면압과 뒤채움주입압은 지반에 직접 압력을 가하는 과정으로 굴착에 인한 지반변위의 억제 뿐만 아니라, 지반 내 유효응력 및 간극수압의 변화에 영향을 미치는 요인이다. 굴진면압과 뒤채움압의 작용에 대한 지반의 반응은 지반의 강성 및 투수성에 따라 상이하다. 특히, 포화된 연약 점성토의 경우 굴진면압과 뒤채움압에 의한 지반 내 응력 변화의 영향이 장시간동안 잔류하므로 이에 대한 반응은 투수성이 큰 지반과 구별되는 거동을 보인다. 따라서 본 논문에서는 유한 요소법을 이용한 응력-간극수압 연계 매개변수해석을 통해 포화 점성토 지반에서 쉴드 TBM 운전 조건과 지반의 강성과 투수성이 지표침하에 미치는 영향에 대한 연구를 수행하였다. 연구 결과, 점성토 지반의 지표침하는 즉시침하와 압밀침하로 구분할 수 있었으며, 특히 압밀침하 거동은 지반의 투수성과 강성의 영향을 크게 받는 것으로 나타났다. 또한, 굴진면압과 뒤채움압의 증가가 항상 지표침하 감소로 이어지지는 않고, 임의 크기의 압력(한계 압력) 이상으로 증가된 굴진면압과 뒤채움압은 역으로 지표침하를 증가시키는 요인으로 작용할 수 있음이 확인되었다.

Direct Electrical Probing of Rolling Circle Amplification on Surface by Aligned-Carbon Nanotube Field Effect Transistor

  • Lee, Nam Hee;Ko, Minsu;Choi, Insung S.;Yun, Wan Soo
    • Bulletin of the Korean Chemical Society
    • /
    • 제34권4호
    • /
    • pp.1035-1038
    • /
    • 2013
  • Rolling circle amplification (RCA) of DNA on an aligned-carbon nanotube (a-CNT) surface was electrically interfaced by the a-CNT based filed effect transistor (FET). Since the electric conductance of the a-CNT will be dependent upon its local electric environment, the electric conductance of the FET is expected to give a very distinctive signature of the surface reaction along with this isothermal DNA amplification of the RCA. The a-CNT was initially grown on the quartz wafer with the patterned catalyst by chemical vapor deposition and transferred onto a flexible substrate after the formation of electrodes. After immobilization of a primer DNA, the rolling circle amplification was induced on chip with the a-CNT based FET device. The electric conductance showed a quite rapid increase at the early stage of the surface reaction and then the rate of increase was attenuated to reach a saturated stage of conductance change. It took about an hour to get the conductance saturation from the start of the conductance change. Atomic force microscopy was used as a complementary tool to support the successful amplification of DNA on the device surface. We hope that our results contribute to the efforts in the realization of a reliable nanodevice-based measurement of biologically or clinically important molecules.

저탄소강 용접열영향부의 NaCl, H2S 수용액에서 생성되는 부식스케일 분석 (Analysis on the Scales formed on the Heat Affected Zone of Low Carbon Steel Weld in NaCl and H2S Water Solutions)

  • 김민정;배동호;이동복
    • 한국표면공학회지
    • /
    • 제43권4호
    • /
    • pp.205-210
    • /
    • 2010
  • The A106 Gr B low carbon steel, which was used in the electric power plants and heavy chemical plants, was welded by multi-pass arc welding. The heat affected zone (HAZ) formed by welding was corroded in acid chloride solution, or in saturated $H_2S$ containing acid chloride solution, or in saturated $H_2S$ containing acid chloride solution under applied current. In this order of corrosion solution, the rate of corrosion increased, because $H_2S$ accelerated the iron dissolution, hydrogen evolution, and the formation of nonprotective FeS, whereas the applied current accelerated the electrochemical reaction. The scales formed in acid chloride solution consisted primarily of $Fe_3O_4$, while those formed in $H_2S$ containing acid chloride solution consisted primarily of $Fe_3O_4$ and FeS.

구름접촉을 하는 분말고속도공구강의 X선을 이용한 표면성상해석 (Analysis of Rolling Contact Surface on PM-High Speed Steel by X-ray Diffraction)

  • 이한영;김용진;배종수
    • Tribology and Lubricants
    • /
    • 제19권1호
    • /
    • pp.1-8
    • /
    • 2003
  • Recently, PM-high speed steel(PM-HSS) has reportedly been a good alternative material for rolling mill because of its superior performance to conventional HSS. This paper has been aimed to investigate the possibility for application to rolling contact element for PM-HSS by X-ray diffraction technique. The X-ray elastic constant for PH-HSS has been found by X-ray diffraction during the four-point bending test. Residual stress and half-value breadth on the contact surface during rolling contact fatigue process by X-ray diffraction have also been measured. The result of this study shows that the application of X-ray diffraction technique to PM-HSS could be as possible alternative material as conventional HSS. Half-value breadth on rolling contact surface by X-ray diffraction is not changed during rolling contact fatigue process. On the other hand, the residual stress is changed. This suggests that dislocation reaction has been hardly occurred in rolling contact, depending on super-saturated carbon in PM-HSS.

Pb-Sn 합금도금의 이론 및 실제적 경향 (Theoretical and Practical Aspects of Pb-Sn Alloy Plating)

  • 백영남
    • 한국표면공학회지
    • /
    • 제12권3호
    • /
    • pp.161-166
    • /
    • 1979
  • Theoretical and practical aspects are investigated for electrochemical behavious, plating processes and the structures of electrodeposit of Pb-Sn binary alloy plating through numerous literatures in this report. The anodic and cathodic electrode reaction mechanisms of Pb and Sn could co-deposit and make Pb-Sn alloy deposit from the results of cathode current density-cathode potential curves of Pb, Sn and Pb-Sn alloys in fluoborate solutions. The compositions of the best alloy plating solutions are obtained for the purpose of bearing, anticorrosion and solder plating. In general, the casting anodes of Pb-Sn alloys are used, but separated anodes of Pb and Sn pure metal are used in order to obtain the fine compositions of Pb-Sn alloy deposits. The electrodeposits of Pb-Sn alloy are in nonequilibrium state and saturated solid solutions. Thus, ${\beta}$-phase (Sn-phase) is precipitated by heat treatment. The texture and structure of the electrodeposit are associated with the surface energies of deposit lattice planes and with the cathode polarization. The electrodeposit of Pb-Sn alloy is shown as lamellar structure.

  • PDF

Direct Electrode Reaction of Fe(III)-Reducing Bacterium, Shewanella putrefaciens

  • Kim, Byung-Hong;Kim, Hyung-Joo;Hyun, Moon-Sik;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
    • /
    • 제9권2호
    • /
    • pp.127-131
    • /
    • 1999
  • Anaerobically grown cells of an Fe(III)-reducing bacterium, Shewanella putrefaciens IR-l, were electrochemically active with an apparent reduction potential of about 0.15 V against a saturated calomel electrode in the cyclic voltammetry. The bacterium did not grow fermentatively on lactate, but grew in an anode compartment of a three-electrode electrochemical cell using lactate as an electron donor and the electrode as the electron acceptor. This property was shared by a large number of Fe(III)-reducing bacterial isolates. This is the first observation of a direct electrochemical reaction by an intact bacterial cell, which is believed to be possible due to the electron carrier(s) located at the cell surface involved in the reduction of the natural water insoluble electron acceptor, Fe(III).

  • PDF

Electrokinetic-Fenton 기법에 의한 phenanthrene으로 오염된 토양의 처리

  • 김정환;김강호;한상재;김수삼
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2001년도 추계학술발표회
    • /
    • pp.51-54
    • /
    • 2001
  • This research was carried out to evaluate feasibility of using an Electrokinetic-Fenton(EK-Fenton) technique to treat hydrophobic organic pollutant(phenanthrene) from soils. Experiment examined the effect by introducing a continuous flow of a 3.5% hydrogen peroxide solution at the anode. An electric gradient of 1V/cm was applied to enhance the saturated flow in the soil cell for a period of 11 days. After 11 days or 1 pore volume, overall concentration of residual phenanthrene in the soil cell was 11% and residual phenanathrene concentration in the soil was found to increase with toward the cathode. This results indicated that Fenton-like reaction catalyzed by mineral surface was effective in oxidizing phenanthrene. This results also showed that hydrogen peroxide was effectively transported into the soil by electroosmotic flow as well as by diffusion.

  • PDF