• Title/Summary/Keyword: Surface protective layer

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Tribology Characteristics on the Atmospheric Pressure of Alumina Ceramics with Different Purity (순도를 달리한 알루미나 세라믹스의 분위기 압력변화에 따른 Tribology 특성)

  • Jin, Dong-Gyu;Park, Heung-Sik;Seo, Yeong-Baek;Ok, Cheol-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.2 s.173
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    • pp.448-454
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    • 2000
  • This study was undertaken to investigate tribological characteristics with atmospheric pressure for three alumina ceramics of different purity, such as, 85 %, 95 % and 99.7 %. The wear test was carried out using the wear test device which was designed for this study in air, $10^-2$ Torr and $10^-4$ Torr. The friction coefficient depends entirely on atmospheric pressure and alumina with lower purity than higher purity has been much affected by heat accumulation. The friction surface of ceramics have been protected in the air by the influence of the oxides transferred from STB2. However, the protective layer can not be formed due to the decrease of oxygen in vacuum.

Adhesion Characteristic and Porosity Change of Alkali Silicate Impregnant of Concrete (Silicate계 콘크리트 함침제 도포에 따른 부착특성 및 공극변화)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu;Lim, Young-Chul
    • Journal of the Korean Ceramic Society
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    • v.47 no.4
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    • pp.276-282
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    • 2010
  • There are the impregnating layer formation by surface protective materials or impregnants and the adhesion method by polymer, FRP sheet or steel plate in the surface protective method of concrete structure. The surface impregnation method by impregnants improves the durability of concrete structure by modifying the structure of the concrete surface and also have a merit that can be shortly applied in place without the decrease of concrete surface appearance and is easily applied again. This study is interested in manufacturing the concrete surface impregnants including lithium and potassium silicate for the repair of the exposed concrete and the color concrete requiring the advanced function in view of the concrete appearance. The durability and porosity properties was tested for the review of application. The result of this study show that the effective content of silicate ranges 5 to 20% and the separate application of the first impregnant and the second impregnant is effective for the optimum performance. The adhesion in tension is slightly increased but the reinforcement of concrete substrate is slight. So, the concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.

High Temperature Oxidation Characteristics of Ti-Al Intermetallic Compounds (Ti-Al계 금속간화합물의 고온산화특성)

  • 오인석;최창우;김길무;홍준표;김종집
    • Journal of the Korean institute of surface engineering
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    • v.25 no.5
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    • pp.253-261
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    • 1992
  • Ti-Al intermetallic compounds which can be used in gas turbine at elevated temperature were inves-tigated in order to improve oxidation resistance by the formation of protective oxide scale. Four Ti-Al alloys were prepared by plasma arc melting. As the amount of Al was increased among the alloys, oxida-tion resistance was improved by the formation of relatively purer Al2O3 layer. However, the alloys which have less amount of Al formed a duplex layer of Al2O3 and TiO2. When samples were oxidized in pure oxygen instead of air, oxidation resistance was improved because of formation of the purer Al2O3 layer.

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Effect of $Al_2O_3$ capping layer on properties of MgO protection layer for plasma display panel

  • Eun, Jae-Hwan;Lee, Jung-Heon;Kim, Soo-Gil;Kim, Hyeong-Joon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.628-631
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    • 2002
  • $Al_2O_3$ capping layer and MgO protective layer were deposited by electron beam evaporation method using single crystal source. Thickness of the capping layer, $Al_2O_3$, was varied from 5 nm to 10 nm. Surface morphology was observed by SEM and AFM before and after hydration. And microstructure of deposited $Al_2O_3$ layer and chemical shift of electron binding energy were also observed by high resolution TEM and XPS, respectively, after hydration. From these results, it was found that Mg atoms diffused into $Al_2O_3$ layer, reacted with moisture and formed $Mg(OH)_2$ during hydration. As thickness of $Al_2O_3$ increased, extent of hydration increased. $Al_2O_3$ capped MgO thin films and uncapped MgO thin films were deposited on AC-PDP test panel to characterize discharge properties. Although $Al_2O_3$ has poor discharge properties rather than MgO, because of many hydrated species on the surface of MgO, similar discharge properties were observed.

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Review on Molecular Simulation of Graphene from a Tribological Perspective (트라이볼로지 관점에서의 그래핀 분자시뮬레이션 연구동향)

  • Kim, Hyun-Joon;Chung, Koo-Hyun
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.55-63
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    • 2020
  • Recently, graphene has attracted considerable attention owing to its unique electrical, optical, thermal, and mechanical properties. The broad spectrum of applications from optics, sensors, and electronics to biodevice have been proposed based on these properties. In particular, graphene has been proposed as a protective coating layer and solid lubricant for microdevices and nanodevices because of its high mechanical strength, chemical inertness, and low friction characteristics. During the past decade, extensive efforts have been made to explore the tribological characteristics of graphene under various conditions and to expand its applicability. In addition to the experimental approaches, the molecular simulations performed provide fundamental insights into the friction and wear characteristics of graphene resulting from molecular interactions. This work is a review of the studies conducted over the past decade on the tribological characteristics of graphene using molecular simulation. These studies demonstrate the principal mechanisms of the superlubricity of graphene and help clarify the influences of surface conditions on tribological behavior. In particular, the investigation of the effects of the number of layers, strength of adhesion to the substrate, surface roughness, and commensurability provides deeper insights into the tribological characteristics of graphene. These fundamental understandings can help elucidate the feasibility of graphene as a protective coating layer and solid lubricant for microdevices and nanodevices.

Optical and Electrical Properties of MgO-CaO thin films as a Protective Layer for AC PDPS (교류형 PDP 보호막용 MgO-CaO 박막의 광학적 특성과 전기적 특성)

  • Jo, Jin-Hui;Kim, Rak-Hwan;Park, Jong-Wan
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.547-550
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    • 1999
  • Optical and electrical properties of MgO-CaO films as a protective layer for AC plasma display panel were studied. When the [(CaO/(MgO+CaO)] ratio of evaporation starting materials was optimum composition, 0.1, firing voltage and memory margin of the film were 176V and 0.5, respectively. When [CaO/(CaO+MgO)] was 0, 0.1 and 0.2, memory margin was 0.39, 0.5 and 0.41, respectively, and surface roughness of films was $27.7\AA$, $21.1\AA$ and $40.3\AA$, respectively. It was thought that memory margin had a reverse-relation with surface roughness. The density of film was calculated by measuring the refractive index of film. The density of MgO film was 3.21g/㎤ and the density of film, when [CaO/(CaO+MgO)] was 0.1, was 3.632g/㎤. The mixture of MgO-CaO films showed a good transmittance property in the visual range.

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A strudyon the improvement of the oxidation resistance for high temperature materials by coating process (코팅에 의한 고온재료의 내산화성 향상을 위한 연구)

  • 강석철;민경안;안연상;김길무
    • Journal of the Korean institute of surface engineering
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    • v.30 no.2
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    • pp.93-103
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    • 1997
  • High temperature materials used in the elevated temperature and corrosive atmosphere must have the good oxidation resistance and preserve their own mechanical properties simultaneously. For the oxidation resistance, it is very important to form a protective oxide scale such as $Al_2O_3$ or $Cr_2O_3$ on the substrate. However, the additions of protective oxide forming elements such as Cr and Al in the alloy to enhance its oxidation resistance are limited due to the deleterious effects on their mechanical properties. PECVD(P1asma Enhanced Chemical Vapor Deposition) coating processes were employed to improve the oxidation resistance at high temperature. Cr and/or A1 were coated on the substrates of Ni and Inconel 600 at various temperatures of 400, 500, $600^{\circ}C$ and at different conditions of specimen surfaces. Then, coated specimens were exposed to isothermal and cyclic oxidation conditions in air at 1000 and $1100^{\circ}C$. In order to enhance the adhesion between the substrate and coated layer, heat treatments of the coated specimens were conducted in a vacuum. At isothermal oxidation experiments, Al-coated Ni specimen showed better oxidation resistance than pure Ni. At cyclic oxidation experiments at $1000^{\circ}C$. Cr and Al-coated specimen showed better oxidation resistance. Cr-coated Inconel 600 had also showed better oxidation resistance due to Cr in the substrate. By PECVD coating process, oxidation resistance could be improved, but it was not improved as expected due to the weakness of the adhesion between the substrate and the coated layer.

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The Effect of Hydrogen in the Nuclear Fuel Cladding on the Oxidation under High Temperature and High Pressure Steam (고압 수증기하 산화에서 핵연료 피복관내 수소효과 연구)

  • Jung, Yunmock;Jeong, Seonggi;Park, Kwangheon;Noh, Seonho
    • Journal of the Korean institute of surface engineering
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    • v.47 no.1
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    • pp.7-12
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    • 2014
  • The characteristics of oxidation for the Zry-4 was measured in the $800^{\circ}C$ and high steam pressure (50 bar, 75 bar, 100 bar) conditions, using an apparatus for high pressure steam oxidation. The effect of accelerated oxidation by high-pressure steam was increased more than 60% in hydrogen-charged cladding than normal cladding. This difference between hydrogen charged claddings and normal claddings tends to be larger as the higher pressure. The accelerated oxidation effect of hydrogen charging cladding is regarded as the hydrogen on the metal layer affects the formation of the protective oxide layer. The creation of the sound monoclinic phase in Zry-4 oxidation influences reinforcement of corrosion-resistance of the oxide layer. The oxidation is estimated to be accelerated due to the creation of equiaxial type oxide film with lower corrosion resistance than that of columnar type oxide film. When tetragonal oxide film transformed into the monoclinic oxide film, surface energy of the new monoclinic phase reduced by hydrogen in the metal layer.

NEW PROGRESS IN TiN-BASED PROTECTIVE COATINGS DEPOSITED BY ARC ION PLATING

  • Huang, R.F.;Wen, L.S.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.265-275
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    • 1999
  • Titanium nitride and related overlayers produced by arc ion plating (AIP) are applied as commercial coatings in world-wide scale since the middle of 80s. Due to the achievements of low temperature deposition (LTD), they begin now to be used as wear and corrosion-resistant coatings for machine parts, besides applications on cemented carbide and high speed steel cutting tools. On the other side, TiN can be now applied successfully to brass, Al-alloy, ZnAl alloy articles as decorative coating through LTD. Various nitrides, carbonitrides, borides and other refractory compounds, such as (Ti, Al)N, TiCN, CrN, are used as the coatings for special heavy-duty working conditions instead of TiN since 90s. More and more multilayer coatings are applied now substituting single layer ones. Duplex processes are under development.

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