• 제목/요약/키워드: Surface polarity

검색결과 171건 처리시간 0.027초

Polarity-tuned Gel Polymer Electrolyte Coating of High-voltage LiCoO2 Cathode Materials

  • Park, Jang-Hoon;Cho, Ju-Hyun;Kim, Jong-Su;Shim, Eun-Gi;Lee, Yun-Sung;Lee, Sang-Young
    • 전기화학회지
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    • 제14권2호
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    • pp.117-124
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    • 2011
  • We demonstrate a new surface modification of high-voltage lithium cobalt oxide ($LiCoO_2$) cathode active materials for lithium-ion batteries. This approach is based on exploitation of a polarity-tuned gel polymer electrolyte (GPE) coating. Herein, two contrast polymers having different polarity are chosen: polyimide (PI) synthesized from thermally curing 4-component (pyromellitic dianhydride/biphenyl dianhydride/phenylenediamine/oxydianiline) polyamic acid (as a polar GPE) and ethylene-vinyl acetate copolymer (EVA) containing 12 wt% vinyl acetate repeating unit (as a less polar GPE). The strong affinity of polyamic acid for $LiCoO_2$ allows the resulting PI coating layer to present a highly-continuous surface film of nanometer thickness. On the other hand, the less polar EVA coating layer is poorly deposited onto the $LiCoO_2$, resulting in a locally agglomerated morphology with relatively high thickness. Based on the characterization of GPE coating layers, their structural difference on the electrochemical performance and thermal stability of high-voltage (herein, 4.4 V) $LiCoO_2$ is thoroughly investigated. In comparison to the EVA coating layer, the PI coating layer is effective in preventing the direct exposure of $LiCoO_2$ to liquid electrolyte, which thus plays a viable role in improving the high-voltage cell performance and mitigating the interfacial exothermic reaction between the charged $LiCoO_2$ and liquid electrolytes.

전사 방법에 따른 그래핀의 표면 에너지 변화 (Surface Energy of Graphene Transferred by Wet and Dry Transfer Methods)

  • 윤민아;김찬;원세정;정현준;김재현;김광섭
    • Tribology and Lubricants
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    • 제35권1호
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    • pp.9-15
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    • 2019
  • Graphene is a fascinating material for fabricating flexible and transparent devices owing to its thickness and mechanical properties. To utilize graphene as a core material for devices, the transfer process of graphene is an inevitable step. The transfer process can be classified into wet and dry methods depending on the surrounding environment. The adhesion between graphene and a target substrate determines the success or failure of the transfer process. As the surface energy of graphene is an important parameter that provides adhesion, it is useful to estimate the surface energy to understand the mechanisms of the transfer process. However, the exact surface energy of graphene is still disputed because the wetting transparency of graphene depends on the polarity of the liquid and target substrate. Previously reported results use graphene transferred by the wet method. However, there are few reports on the surface energy of graphene transferred by the dry method. In this study, the surface energy of graphene transferred by the wet and dry methods is estimated. Wetting transparency occurs for certain combinations of liquids and substrates. For graphene on a polar substrate, the surface energy decreases by 25 and 35% for the wet and dry transfer methods, respectively. However, the surface energy of graphene on dispersive substrates decreases by ~10% regardless of the transfer method. In conclusion, the surface energy of graphene is $36{\sim}38mJ/m^2$, and differs depending on the transfer method and polarity of the substrate.

조직 표면에서의 베타선 흡수선량 측정 (Measurement of Absorbed Dose at the Tissue Surface from a Plain $^{90}Sr+^{90}Y$ Beta Sources)

  • 하석호;김정묵;육종철
    • Journal of Radiation Protection and Research
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    • 제16권2호
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    • pp.17-26
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    • 1991
  • 외삽형 전리함을 사용하여 $^{90}Sr+^{90}Y(1.65mCi)$ 베타선원에 대해 교정점 30cm 거리에서 조직표면의 흡수선량을 측정하였다. 이때 흡수선량 측정에 영향을 주는 유효단면적, 입사창 감쇠율, 극성효과, 이온 재결합을 등의 보정인자를 분석하였다. 이들 인자를 보정한 후의 조직표면의 흡수선량은 $1.493{\mu}Gy/sec({\pm}2.9%)$로 평가되었다.

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DC 전압이 유입변압기 절연시스템에 미치는 영향에 관한 연구 (Study on the effect of DC voltage in oil-immersed transformer insulation system)

  • 장효재;김용한;석복렬
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1552-1553
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    • 2011
  • The HVDC transformer which is one of the main equipments for HVDC(High Voltage Direct Current) electric power transmission systems is exposed to not only AC voltage but also the inflowing DC voltage which comes from the DC-AC converter systems. Therefore, the HVDC transformer insulation system is required to withstand the electric field stress under AC, DC and DC polarity reversal conditions. However the electric field distributions under those conditions are different because the AC electric field and DC electric field are governed by permittivity and conductivity, respectively. In this study, the changes of electric potential and electric field of conventional AC transformer insulation system under DC polarity reversal test condition were analyzed by FEM(Finite Element Method). The DC electric field stress was concentrated in the solid insulators while the AC electric field stress was concentrated in the mineral oil. In addition, the electric stress under that condition which is affected by the surface charge accumulation at the interfaces between insulators was evaluated. The stress in some parts could be higher than that of AC and DC condition, during polarity reversal test. The result of this study would be helpful for the HVDC transformer insulation system design.

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HVPE법으로 성장시킨 GaN 박막의 기판에 따른 극성 특성 (Characterizations of GaN polarity controlled by substrate using the hydride vapor phase epitaxy (HVPE) technique)

  • 오동근;;최봉근;이성철;정진현;이성국;심광보
    • 한국결정성장학회지
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    • 제18권3호
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    • pp.97-100
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    • 2008
  • HVPE 법에 의해 성장시킨 GaN 박막이 기판에 따라서 극성과 비극성 특성의 변화에 대해 연구하였다. A-plane($11{\bar{2}}0$), C-plane(0001) and M-Plane($10{\bar{1}}0$) 사파이어 기판을 이용하여 $10\;{\mu}m$ 두께의 GaN 박막을 성장하였다. 광학현미경 및 원자력간 현미경(OM, AFM)을 이용해 표면 구조를 관찰하고, HRXD를 통해 이들은 모두 wurtzite 구조를 갖고 C-plane으로 성장시에는, 극성 특성을, A-plane 및 M-plane 성장 시에는 비극성 특성을 가짐을 확인하였으며, Photoluminescence (PL)측정 결과 3.4 eV에서 발광 피크, 2.2 eV에서 yellow luminescence peak를 확인하였다.

$SF_6$와 공기의 혼합기체중에서의 연면 코로나 방전 (A Study on the Surface Corona Discharge in the Gas with different Mixing Ratio of Air to $SF_6$)

  • 전춘생;조기선;우호환
    • 전기의세계
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    • 제26권6호
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    • pp.78-85
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    • 1977
  • This paper studies flashover voltage and surface corona loss of A.C and D.C in the mixed gas of air and SF$_{6}$ for solid insulators P.V.C, arcylic, glass and bakelite in two cases. In one case, those solids are covered with transformer oil and the other case, those solids are not covered with it. 1) The flashover voltage for each solids in SF$_{6}$ is more than three times compared with that in the air. The flashover voltage for P.V.C is the highest and then arcylic, glass, bakelite in a decreasing order. 2) The more the amount of SF$_{6}$ in the mixing ratio, the less corona loss. The P.V.C shows the least amount of corona loss and the bakelite the largest. 3) Compared with the corona loss of positive polarity and the negative polarity, the former has less corona loss than the latter. 4) The more the number of flashover discharge, the less insulation of each solids, but in case of bakelite, insulation almost vanishes after a couple of discharge. 5) When each insulator is covered with transformer oil, the flashover voltage generally increases and the corona loss decreases.eases.

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Apolar growth of Neurospora crassa leads to increased secretion of extracellular proteins

  • Lee, In-Hyung;Rodney G. Walline;Michael Plamann
    • 한국미생물생명공학회:학술대회논문집
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    • 한국미생물생명공학회 2000년도 Proceedings of 2000 KSAM International Symposium and Spring Meeting
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    • pp.78-89
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    • 2000
  • Protein secretion in filamentous fungi has been shown to be restricted to actively growing hyphal tips. To determine whether an increase in the amount of growing surface area of a fungus can lead to an increase in the amount of protein secretion, we examined secretion in a temperature-sensitive Neurospora crassa mcb mutant that shows a loss of growth polarity when incubated at restrictive-temperature. Incubation of the mcb mutant at restrictive-temperature results in a three- to five-fold increase in the level of extracellular protein and a 20- fold increase in carboxymethyl cellulase activity relative to a wild-type strain. A mutation in the cr-l gene has been shown previously to suppress the apolar growth phenotype of the mcb mutant, and we find that the level of extracellular protein produced by a mcb; cr-l double mutant was reduced to that of the wild-type control. Immunolocalization of a secreted endoglucanase revealed that proteins are secreted mainly at hyphal tips in hyphae exhibiting polar growth and over the entire surface area of bulbous regions of hyphae that are produced following a shift of the mcb mutant to restrictive-temperature. These results support the hypothesis that secretion of extracellular protein by a filamentous fungus can be significantly increased by mutations that alter growth polarity.

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티타늄 금속 표면 양극산화장치 개발 (Development of Titanium Metal Surface Anodizing Equipment)

  • 양근호;민병운
    • 한국전자통신학회논문지
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    • 제8권9호
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    • pp.1307-1312
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    • 2013
  • 본 논문에서는 알칼리성 또는 산성을 띠는 특정 용액 내에서 전기분해 원리를 이용하여 금속 표면을 산화시켜 절연피막을 형성하는 장치를 개발한다. 기존에는 주로 양극에만 펄스 형태로 전압을 인가하는 단극성(unipolar) 방식이지만 본 논문에서는 H-브리지를 이용하여 양극에 양(+)전압과 음(-)전압을 번갈아 가면서 전압을 공급하는 양극성(bipolar) 장치를 제작하였으며, 금속 시편의 특성에 맞는 다양한 전기적인 조건을 가지고 산화피막을 형성할 수 있는 장치를 개발하였다. 공급전류 가변은 PWM 변조를 이용하였으며, (+)와 (-)의 극성변화는 H-브리지를 이용하여 양극성 펄스전압을 공급할 수 있도록 하였다. 그 결과로써 단극성보다 균일한 기공을 갖는 피막이 형성되었다.

The Limit of Magnetic Helicity Estimation by a Footpoint Tracking Method during a Flux Emergence

  • Choe, Gwang Son;Yi, Sibaek;Jang, Minhwan;Jun, Hongdal;Song, Inhyuk
    • 천문학회보
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    • 제43권2호
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    • pp.58.2-58.2
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    • 2018
  • Theoretically, the magnetic helicity transport flux through the solar surface into the upper atmosphere can be estimated indefinitely precisely by magnetic field footpoint tracking if the observational resolution is infinitely fine, even with magnetic flux emergence or submergence. In reality, the temporal and spatial resolutions of observations are limited. When magnetic flux emerging or submerging, the footpoint velocity goes to infinity and the normal magnetic field vanishes at the polarity inversion line. A finite observational resolution thus generates a blackout area in helicity flux estimation near the polarity inversion line. It is questioned how much magnetic helicity is underestimated with a footpoint tracking method due to the absence of information in the blackout area. We adopt the analytical models of Gold-Hoyle and Lundquist force-free flux ropes and let them emerging from below the solar surface. The observation and the helicity integration can start at different emerging stages of the flux rope, i.e., the photospheric plane initially cuts the flux rope at different levels. We calculate the magnetic helicity of the flux rope below the photospheric level, which is eventually to emerge, except the helicity hidden in the region to be swept by the blackout area with different widths. Our calculation suggests that the error in the integrated helicity flux estimate is about half of the real value or even larger when small scale magnetic structures emerge into the solar atmosphere.

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Evo-Devo of Leaf Shape Control with a Special Emphasis on Unifacial Leaves in Monocots

  • Yamaguchi, Takahiro;Tsukaya, Hirokazu
    • 식물분류학회지
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    • 제37권4호
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    • pp.351-361
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    • 2007
  • In angiosperms, leaves typically develop as three-dimensional structure with dorsoventral, longitudinal, and lateral axes. We have shown that the control of two axes of leaves, longitudinal and lateral axis, can be genetically separable, and four classes of genes are responsible for the polar cell expansion and polar cell proliferation in Arabidopsis. In monocots, unifacial leaf, in which leaf surface consists only of abaxial identity, has been evolved in a number of divergent species. The unifacial leaves provide very unique opportunities for the developmental studies of the leaf axes formation in monocots, because their leaf polarities are highly disorganized. In addition, the mechanism of the parallel evolution of such drastic changes in leaf polarities is of interest from an evolutionary viewpoint. In this article, we describe our recent approaches to reveal the mechanism of unifacial leaf development and evolution, including recent advances in the leaf polarity specification in angiosperms.