• 조명전기설비학회논문지
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• 제22권5호
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• pp.47-52
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• 2008

본 논문에서는 모의 GIS 내부에 도전성 파티클, 미소돌기, 연면방전을 모의함으로 전하의 축적과 전계의 집중이 용이하도록 하여 부분방전을 모의하였다. 이때 부분방전 발생과 진전에 따른 방사전자파를 스펙트럼 분석기와 EMI EMC 측정용 안테나($30{\sim}2,000[MHz]$)를 사용하여 측정 분석하였다. 이러한 결과를 바탕으로 0.3[GHz]에서 1.7[GHz]대역에서 UHF법을 활용한 절연진단이 가능한 UHF 구형 센서를 설계하였다. 이러한 연구결과는 $SF_6$를 사용하는 실제 GIS 및 전력설비의 UHF 절연진단 시스템에 적용 가능한 UHF 진단센서로 활용할 수 있을 것이다.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.69-81
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• 2019

The corrosion inhibiting mechanism of Vietnam orange peel essential oil (OPEO) for mild steel in 1 N HCl solution was investigated elaborately. Corrosion inhibition ability of OPEO was characterized by electrochemical polarization, electrochemical impedance spectroscopy (EIS), and weight loss method. In the corrosive solution, OPEO worked as a mixed inhibitor and the inhibition efficiency of OPEO increased with the increase of its concentration. High inhibition efficiencies over 90% were achieved for the concentration of 3 - 4 g/L OPEO, comparable to that of 3.5 g/L urotropine (URO), a commercial corrosion inhibitor for acid media used in industry. By using adsorption isotherm models (Langmuir, Temkin and Frumkin), thermodynamic parameters of adsorption were calculated. The obtained results indicated physical adsorption mechanism of OPEO on the steel surface. The components responsible for the corrosion inhibition activity of OPEO were not only D-limonene, but also other compounds, which contain C=O, C=C, O-H, C-O-C, -C=CH and C-H bonding groups in the molecules.

• 공업화학
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• 제30권3호
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• pp.324-330
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• 2019

Petal-like nickel cobaltite ($NiCo_2O_4$)/reduced graphene oxide (rGO) composites with different $rGO-to-NiCo_2O_4$ weight ratios were synthesized using a simple hydrothermal method and subsequent thermal treatment. In the $NiCo_2O_4/rGO$ composite, the $NiCo_2O_4$ 3-dimensional nanomaterials contributed to the improvement of electrochemical properties of the final composite material by preventing the restacking of the rGO sheet and securing ion movement passages. The composite structure was examined by field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and Fourier-transform infrared (FT-IR) spectroscopy. The FE-SEM and TEM images showed that petal-like $NiCo_2O_4$ was supported on the rGO surface. Cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) were used for the electrochemical analysis of composites. Among the prepared composites, $0.075g\;rGO/NiCo_2O_4$ composite showed the highest specific capacitance of $1,755Fg^{-1}$ at a current density of $2Ag^{-1}$. The cycle performance and rate capability of the composite material were higher than those of using the single $NiCo_2O_4$ material. These nano-structured composites could be regarded as valuable electrode materials for supercapacitors that require superior performance.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.663-668
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• 2021

For the development of highly efficient quantum dot-sensitized solar cells (QDSCs), it is important to enhance the electrocatalytic activity of the counter electrodes (CEs). Herein, a fabrication process of Cu₂S CEs are optimized for the development highly efficient QDSCs. The surface of brass film is treated with HCl solution to prepare the Cu₂S CEs, and the concentraion as well as the temperature of HCl solution are controlled. It is found that the uniformity for the thickness of prepared Cu₂S CEs is enhanced when the diluted HCl solution is used, compared to the HCl solution of standard concentration. In addition, the electrocatalytic activity of the Cu₂S CEs is also increased with the modificed process, which is confirmed by impedance data and Tafel polarization curves. As a result, the photoconversion efficiency of QDSCs is improved from 4.49% up to 5.73%, when the concentraion and temperature of the HCl treatment are efficiently optimized.

• Journal of Electrochemical Science and Technology
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• 제12권2호
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• pp.217-224
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• 2021

In this study, Monte Carlo (MC) simulation is conducted with recurrence relation to study the effect of SiO₂ with different particle size and their roles in enhancing the ionic conductivity and lithium transference number of PMMA composite polymer electrolytes (CPEs). The MC simulated ionic conductivity is verified with the measurements from Electrochemical Impedance Spectroscopy (EIS). Then, the lithium transference number of CPEs is calculated using recurrence relation with the MC simulated current density and the reference transference number obtained. Incorporation of micron-size SiO₂ (≤10 ㎛) fillers into the mixture improves the ionic conductivity from 8.60×10^-5 S/cm to 2.35×10^-4 S/cm. The improvement is also observed on the lithium transference number, where it increases from 0.088 to 0.3757. Furthermore, the addition of nano-sized SiO₂ (≤12 nm) fillers further increases the ionic conductivity up towards 3.79×10^-4 S/cm and lithium transference number of 0.4105. The large effective surface area of SiO₂ fillers is responsible for the improvement in ionic conductivity and the transference number in PMMA composite polymer electrolytes.

• Corrosion Science and Technology
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• 제21권6호
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• pp.423-433
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• 2022

The objective of this study was to determine whether Cymbopogon citratus extract as a corrosion inhibitor from natural tropical resources could prevent corrosion of carbon steel in sulfuric acid solution. Inhibitory action of this extract was investigated using electrochemical methods such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Those methods revealed corrosion rate, efficiency of inhibition, and adsorptions isotherm values when the extract was added to the sulfuric acid solution at concentration up to 500 ppm with various immersion time at ambient temperature. Results revealed that higher concentration of the extract and longer immersion time decreased the corrosion rate of carbon steel whereas the inhibition efficiency of the extract was increased up to 97.25%. The value of charge transfer resistance was increased significantly by adding the extract at concentration up to 500 ppm with an immersion time of 60 minutes. The type of the extract was a mixed inhibitor. It could inhibit the corrosion process in both anodic and cathodic sides electrochemically. Results of this study suggest that the mechanism of adsorption on the surface of carbon steel is related to Langmuir adsorption isotherm.

• Corrosion Science and Technology
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• 제22권2호
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• pp.99-107
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• 2023

Layered silicate clay montmorillonite (MMT) has been used in nanocomposite coating to improve corrosion protection by reinforcing the barrier property. The better dispersion of MMT in the coating produces a higher barrier effect. Pretreatment with MMT could favor the delamination of clay platelets, facilitating MMT dispersion in the coating. In the present work, a montmorillonite/silica (MMT/Si) composite was prepared by the in situ sol-gel method. x-ray diffraction measurements and field-emission scanning electron microscopy observations showed silica crystal formation and increased basal spacing between the MMT platelets. Composite MMT/Si particles were introduced in an epoxy resin to reinforce the corrosion protection of the coating applied on the AA2024 surface. Electrochemical impedance spectroscopy (EIS) was performed to characterize the protective property of the coating. The results demonstrated the high barrier effect of the coating containing 5 wt% of MMT/Si. Adhesion evaluation after a salt spray test exhibited a high adherence to the epoxy coating containing MMT/Si.

• Composites Research
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• 제20권2호
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• pp.27-31
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• 2007

미래의 환경에서는 위성을 이용한 통신서비스의 운송체 내에서의 사용이 기하급수적으로 확대될 전망이다. 이를 위해서는 안테나의 성능 향상 및 역학적 에너지의 고효율성에 기하고, 구조적인 안정을 보장하기 위한 복합 안테나 구조의 설계, 제조 및 해석 기술이 필요하다. 복합 안테나 구조가 안테나의 역할 및 구조체로의 역할을 하기 위해서는 접착필름의 사용이 필수적이다. 하지만 접착필름은 얇은 두께로 인하여 설계시 고려되지 못하고 유전체로 작용하여 전자기적 영향을 끼치게 되어 설계자가 기대하는 성능을 얻지 못한다. 따라서, 이러한 접착필름의 전자기적 특성을 실험적으로 알아본다.

• 한국결정성장학회지
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• 제33권2호
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• pp.78-82
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• 2023

The oxygen evolution reaction (OER) is the primary challenge in renewable energy storage technologies, specifically electrochemical water splitting for hydrogen generation. We report effects of Mo doping into Ni layered double hydroxide (Ni-LDH) microcrystal on electrocatalytic activities. In this study, Mo doped Ni-LDH were grown on three-dimensional porous nicekl foam (NF) by a facile solvothermal method. Homogeneous LDH structure on the NF was clearly observed. However, the surface microstructure of the nickel foam began to be irregular and collapsed when Mo precursor is doped. Electrocatalytic OER properties were analyzed by Linear sweep voltammetry (LSV) and Electrochemical impedance spectroscopy (EIS). The amount of Mo doping used in the electrocatalytic reaction was found to play a crucial role in improving catalytic activity. The optimum Mo amount introduced into the Ni LDH was discussed with respect to their OER performance.

• Journal of Oral Medicine and Pain
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• 제48권3호
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• pp.112-117
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• 2023

Coronoid process hyperplasia (CPH) of the mandible is a rare condition in which abnormal elongation of the coronoid process leads to chronic mandibular hypomobility. CPH causes impingement or impedance of the coronoid process on the inner surface of the frontal part of the zygomatic bone during mouth opening. The lack of significant symptoms makes the diagnosis difficult. Its etiology remains inconclusive despite several theories being suggested. In this report, three reviewed cases are presented. All three patients visited our clinic with limited mouth opening as the chief complaint. Standard clinical and radiographic examinations were conducted under the initial impression of temporomandibular disorders (TMDs), and restricted jaw movements were confirmed in all cases. The absence of improved signs and symptoms following conservative treatment for TMDs or the indeterminate plain radiographs required the attending clinicians to consider three-dimensional imagery. Computed tomography revealed bilateral coronoid hyperplasia in all cases and impingement on the zygomatic bone in two of the three cases. After concluding that this condition caused the patients' limited mouth opening, the patients were referred to the Department of Oral and Maxillofacial Surgery for possible bilateral coronoidectomy or coronoidotomy. CPH usually presents no symptoms apart from a progressive reduction of mouth opening over time. Diagnosis is often delayed, and patients may undergo unnecessary treatment procedures. Clinicians should be aware of this condition and exercise caution in the differential diagnosis of patients with chronic mandibular hypomobility.