• Title/Summary/Keyword: Surface diffusion

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Oxidation of TiZrAlN nanocomposite thin films in air at temperatures between 500 and $700^{\circ}C$ (TiZrAlN의 500-$700^{\circ}C$ 사이에서 공기 중 산화)

  • Kim, Min-Jeong;Bong, Seong-Jun;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.167-170
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    • 2011
  • Quaternary TiZrAlN nanocomposite thin films with a composition of 20.7Ti-22.2Zr-2.7Al-54.4N (at.%) were deposited by the closed-field unbalanced magnetron sputtering (CFUBMS) method and oxidized in air at temperatures between 500 and $700^{\circ}C$. The oxides formed were $TiO_2$, $ZrO_2$, and $Al_2O_3$. The films had inferior oxidation resistance because the amounts of $ZrO_2$ and $TiO_2$ were large while the amount of $Al_2O_3$ was small. The oxidation progressed primarily by the inward diffusion of oxygen and the outward diffusion of nitrogen.

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A Study on Metalliding of Al on Steel from Molten Fluorides (불화물계 용융염중에서 Steel 기지 소재의 Al 전해피복에 관한 연구)

  • 이민구;서길원;백영현
    • Journal of the Korean institute of surface engineering
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    • v.26 no.4
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    • pp.183-191
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    • 1993
  • Diffusion coating(metalliding) of aluminium on steel from molten fluorides(29.2wt.% LiF-11.7wt.% NaF-59.1wt.% KF, FLINAK) was studied. The electrolytic cell consists of a steel cathode and a consumable aluminium anode. Effects of manganese on the aluminium deposition were also investigated. The quality of the deposit was analyzed by SEM, OM, EPMA, EDXA, and also examined by means of Micro-Vickers hardness and corrosion tests. Deposit layer was identified as an aluminium-rich iron alloy caused by diffusion process. The optimum condition for the metalliding was found to be the current density, 50 to $150mA/\textrm{cm}^2$, the bath tem-perature, $57.5^{\circ}C$, and the amount of AlF3, 10wt.%. Addition of manganese fluoride (up to 5wt.%) as a co-de-posit element improved significantly the quality of the deposit layer.

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A study on the growth rate of the carbide layer formed by the reactive deposition (반응석출법에 의한 탄화물 피복속도에 관한 연구)

  • 남기석;변응선;이구현;김도훈
    • Journal of the Korean institute of surface engineering
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    • v.27 no.5
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    • pp.303-311
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    • 1994
  • In this study, the factors, such as coating temperature T(K), reaction time t(sec) and mobile carbon content $C^*$ (wt%) of steels affecting, the growth rate of carbide layer were investigated in the reactive deposition and diffusion coating using the fluidized bed. From the results, the coating thickness d(cm) can be expressed by an equation. d=$C^*$$(KT)^{1/2}$, where K=K$\circ$exp(~Q/RT), KTEX>$\circ$ = 1.4$\times$$10^{-2}cm^{-2}$/sec, and Q=46Kcal/ mol. It was in a good aggrement with the experimental results, reguardless of the diffusion coating method and the carbide layer. Therefore, if the mobile carbon content of carbon steels and alloyed steels is known, the thickness under coating conditions can be predicted from the previous equation.

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High Temperature Oxidation of Ti-15Mo-5Zr-3Al Alloy (Ti-15Mo-5Zr-3Al 합금의 고온산화)

  • 우지호;김종성;백종현;이동복
    • Journal of the Korean institute of surface engineering
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    • v.31 no.5
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    • pp.278-285
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    • 1998
  • Alloys of Ti-15Mo-5Zr-3Al(wt%) were oxidized in air between 700 and $900^{\circ}C$. It was found that the oxidation resistance is much better than that of either commercially available pure Ti-6Al-4V(wt%) alloys. The oxide scales were primarily composed of thick Ti-ox-ides which were formed by the inward diffusion of oxygen from the atmosphere. At higher temperatures a thin $\alpha$-$Al_2O_3$ layer was formed on Ti-oxides owing to the outward diffusion of Al from the base alloys. Molybdenum, the noblest metal among the alloy components, was predominantly present behind the oxide-substrate interface. Zirconium, an oxygen active metal, was present at both the oxide layer and the substrate.

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Selectrive Liquid Phase Epitaxy of GaAs` Kinetics and MOrphology (비소화칼륨의 선택적 액상 에피층 성장;성장기구 및 형태)

  • Kim, Sang Bae;Kwon, Young Se
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.6
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    • pp.820-832
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    • 1986
  • In contrast to conventional liquid phase epitaxy of GaAs, surface kinetics limited growth is predominant in selective liquid phase epitaxy. For the stripe openings in the high-index crystal-lographic directions, the well-known facet formations and the decompositions into the low index planes or smooth circular surfaces are observed depending on the growth kinetics. For the low index direction stripe, surface kinetics limited growth is evident. By a numerical calcualtion we show that these phenomena are due to the enhanced masstransport by two dimensional diffusion and growth rate anisotropy which is found to be very stdrong with cusped minima for some singular planes in the solution growth as well as in vapor phase epitaxy. Morphological stability is briefly treated in terms of diffusion and its implications on device application are stated. Tese phenomena may be common to III-V compound semiconductors as well as GaAs.

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Uniform Ag Thin Film Growth on an Sb-terminated Si(111) Surface

  • Park, Kang-Ho;Ha, Jeong-Sook;Lee, El-Hang
    • ETRI Journal
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    • v.19 no.2
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    • pp.71-81
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    • 1997
  • We report on the room-temperature-growth of highly uniform and ultrathin Ag films on Sb-terminated Si(111) surfaces, as evidenced from a scanning tunneling microscopy (STM) study in an UHV system. With predeposition of one monolayer (ML) of Sb, uniform growth of Ag islands was observed at room temperature. The Sb layer suppresses the surface diffusion of Ag atoms on Si surface and increases the Ag island density, and then the increased island density is believed to cause coalescence of Ag islands before the beginning of multilayer growth in higher coverages, resulting in the growth of atomically flat and uniform islands on the Sb surfactant layer.

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Investigation and research trend and for SiC complex made by Si-vapor diffusion reaction on carbon surface (카본표면에서 Si 증기입자의 확산 반응에 의한 SiC 복합체형성 검토 및 연구동향)

  • Park, Jang-Sik;Hwang, Jeong-Tae
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.195-195
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    • 2014
  • 탄화규소(SiC)의 복합체는 고온강도, 내식성, 내마모성, 내화학 특성, 열충격성 및 기계적 특성이 우수하며 제조공정으로 CVD 공정은 많이 연구되어져 있으나 비교적 간단한 구조로 우수한 특성을 얻을 수 Si 증발입자 확산방법에 대한 체계적인 연구가 수행되고 있지 않다. 본 논문에서는 Si 증발입자가 탄소표면에서 확산 반응으로 형성되는 SiC 복합체에 대한 검토 및 연구 개발 동향을 기술한다.

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A Study on Generation Quality Comparison of Concrete Damage Image Using Stable Diffusion Base Models (Stable diffusion의 기저 모델에 따른 콘크리트 손상 영상의 생성 품질 비교 연구)

  • Seung-Bo Shim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.28 no.4
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    • pp.55-61
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    • 2024
  • Recently, the number of aging concrete structures is steadily increasing. This is because many of these structures are reaching their expected lifespan. Such structures require accurate inspections and persistent maintenance. Otherwise, their original functions and performance may degrade, potentially leading to safety accidents. Therefore, research on objective inspection technologies using deep learning and computer vision is actively being conducted. High-resolution images can accurately observe not only micro cracks but also spalling and exposed rebar, and deep learning enables automated detection. High detection performance in deep learning is only guaranteed with diverse and numerous training datasets. However, surface damage to concrete is not commonly captured in images, resulting in a lack of training data. To overcome this limitation, this study proposed a method for generating concrete surface damage images, including cracks, spalling, and exposed rebar, using stable diffusion. This method synthesizes new damage images by paired text and image data. For this purpose, a training dataset of 678 images was secured, and fine-tuning was performed through low-rank adaptation. The quality of the generated images was compared according to three base models of stable diffusion. As a result, a method to synthesize the most diverse and high-quality concrete damage images was developed. This research is expected to address the issue of data scarcity and contribute to improving the accuracy of deep learning-based damage detection algorithms in the future.

A Study on 3-Dimensional Advection-Diffusion Model Operating Density Current Generator in Agriculture Lake (물순환장치 가동에 따른 농업용저수지의 3차원 이송확산모의에 관한 연구)

  • An, Jae-Soon;Lee, Young-Shin;Oh, Dae-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.7
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    • pp.3275-3284
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    • 2012
  • This study analyzed a 3D hydrodynamic advection diffusion using the EFDC model (Environmental Fluid Dynamics Code) in the agriculture lake to prevent stratification when we install a water circulator. EFDC model was predicted the range of the water circulator and various operational parameters ware derived for minimize the impact of the internal lake. Through EFDC simulation, water circulation is started overall circulation after 30days and a lake overall circulation showed that it was possible operated the water circulator after about 100days. Also, advection diffusion concentration was low in a lake when water circulator operate intermittent condition than continuous condition. And the entire circulation was stable in this condition. The S/B (Surface/Bottom) ratio can reduce the impact of lake as the surface water mixing a lot of. When the same condition (S/B ratio(3:1)), Case 8 (50days operation: 50days stop) of condition were able to minimize the impact of lake.

Diffusion and Oxidation of Ti3+ Interstitials on a Reduced TiO2 (001) Surface: A Crystal-face Dependency (TiO2 (001)면에서 Ti 결함의 확산과 산화: 결정면에 대한 의존성)

  • Kim, Yu-Kwon
    • Journal of the Korean Vacuum Society
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    • v.21 no.5
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    • pp.242-248
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    • 2012
  • Valence band of a vacuum-reduced $TiO_2$ (001) surface has been carefully examined using synchrotron x-ray photoelectron spectroscopy to investigate variation of the gap state upon oxidation and thermal diffusion of $Ti^{3+}$ interstitials from the bulk. We compare our results with that obtained from $TiO_2$ (110) and aim to address a crystal-face dependency in the oxidation and diffusion rates of $Ti^{3+}$ interstitials. We find very similar behaviors in the oxidation and thermal diffusion rate of $Ti^{3+}$ interstitials between the two crystal faces suggesting a negligible crystal-face dependency in this case.