• 접착 및 계면
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• 제15권1호
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• pp.1-8
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• 2014

이온 교환막은 전기투석, 확산투석, Redox flow 전지, 연료전지 등 다양하고 넓은 분야에서 사용되고 있다. 초음파를 이용하여 만들어진 PVC 양이온 교환막을 시간을 변화시켜 가면서 술폰화 반응에 의해 제조하였다. 술폰화제로 황산을 사용하였으며, 술폰화 PVC 양이온 교환막의 기본구조와 특성을 FT-IR, EDX, Water uptake, 이온교환용량(IEC), 전기저항(ER), 전도도, 이온수송수 및 표면 morphology를 SEM 분석하였다. FT-IR 스펙트럼 분석결과 술폰화 PVC 양이온 교환막에 술폰산기가 도입되었음을 확인하였으며 멤브레인의 Water uptake, IEC, 전기 저항 및 ion transport number의 최대값은 각각 40.2%, 0.87 meq/g, $35.2{\Omega}{\cdot}cm^2$ 및 0.88이었다.

• Journal of Magnetics
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• 제10권3호
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• pp.80-83
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• 2005

Cobalt ferrite and garnet powders were grown using a conventional ceramic method in two different ways for understanding the magnetic interaction between structurally different materials. Structures of these powders were investigated by using an X-ray diffractometer (XRD) and the magnetic interaction between iron ions and the magnetic properties of the powders were measured by a $M\ddot{o}ssbauer$ spectroscopy and a vibrating sample magnetometer (VSM), respectively. The result of the XRD measurement showed that the annealing temperature higher than $1200^{\circ}C$ was necessary to grow a $(CoFe_2O_4)_{0.5}(Y_3Fe_5O_{12})_{0.5}$ powder. $M\ddot{o}ssbauer$ spectra for the powders grown separately and mixed mechanically consisted of sub-spectra of cobalt ferrite and garnet, however, powders annealed together had an extra sub-spectrum, which was related with the magnetic interaction between the grain surface of cobalt ferrite and the one of the garnet. In case of annealing the powders at the temperature large enough to crystallize them, raw chemicals became fine cobalt ferrite and garnet particles at first and then these fine particles were aggregated and formed large grains of ferrite powders. The result of the VSM measurement showed that the powders prepared at $1200^{\circ}C$ had the similar saturation magnetization and the coercivity regardless of the preparation method.

• 한국광학회지
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• 제32권2호
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• pp.79-85
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• 2021

본 논문에서는 빔 확산각 최소화를 통해 장거리에서 측정이 가능하도록 한 ToF 레이저 거리센서 광학계 설계에 대한 연구를 진행하였다. 거리센서는 장거리 측정 시 거리가 멀어질수록 레이저 빔의 확산각으로 인해 물체 표면에 도달하는 빔의 광량이 급격히 저하되며, 이로 인해 센서에 수신되는 광량도 감소되어 측정이 되지 않거나 측정 오차가 발생하게 된다. 일반적으로 빔 확산각을 최소화하는 광학계로 실린더 렌즈가 사용된다. 그러나 실린더 렌즈를 이용한 광학계는 광학계 크기가 커지는 문제뿐만 아니라 조립 공차의 어려움으로 인해 성능이 저하된다는 문제점이 있어 최근 비구면 렌즈를 사용하는 추세가 증가하고 있다. 따라서 본 연구에서는 실린더 렌즈를 이용한 광학계와 비구면 렌즈를 이용한 광학계의 광효율과 조립공차를 비교 분석하고자 한다.

• 융합정보논문지
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• 제11권12호
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• pp.115-126
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• 2021

본 연구에서는 내외수 범람을 동시에 고려하여 침수해석을 수행하는 시뮬레이션 모형을 개발하였다. 외수 침수해석을 위해 제방 월류 및 파제에 의한 하천범람 유입량을 고려할 수 있도록 하였고, 내수 침수해석을 위해서 이중배수체계 개념을 반영하도록 구성하였다. 지표면 침수해석과 관련하여 하천의 유동해석과 제내지의 유동해석을 통합적으로 수행하기 위해 유한요소법(FEM)을 적용하여 침수확산 해석을 수행할 수 있도록 하였다. 모형의 검증을 위해 우선 개념모델에 대해서 적용하였고, 이어서 실제 유역에 대해서 적용하였다. 본 연구를 통해 홍수로 인한 피해를 줄이고 홍수 피해를 저감하기 위한 효과적인 대책을 마련하기 위해 활용될 수 있을 것으로 기대된다.

• 멤브레인
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• 제29권1호
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• pp.30-36
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• 2019

본 연구에서는 titanium nitride (TiN) 나노 섬유와 poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) 전도성 고분자로 이루어진 전극과 poly(vinyl alcohol) (PVA) 기반 고분자 전해질 분리막을 이용하여 슈퍼 캐퍼시터를 제조하였다. TiN 나노 섬유의 경우 높은 전기 전도도와 이차원적 구조로 인한 스케폴드 효과를 기대할 수 있다는 점에서 전극 물질로 사용되었다. PEDOT-PSS 전도성 고분자는 수소 이온과 산화-환원 반응을 통해 보다 높은 정전용량을 나타낼 수 있으며 용액상에 분산이 용이해 유무기 복합제를 형성하기에 적합하였다. PVA 기반의 고분자 전해질 분리막은 기존의 액상의 전해질의 문제인 외부 충격에 대한 안정성을 확보할 수 있으며 염으로 사용된 $H_3PO_4$의 경우 수소 이온은 빠른 확산으로 인해 캐퍼시터의 충방전 효율에 이점이 있다. 본 연구에서 보고된 PEDOT-PSS/TiN 슈퍼캐퍼시터의 정전용량은 약 75 F/g으로 기존의 탄소기반 캐퍼시터에 비해 큰 폭으로 증가한 값이다.

• 한국재료학회지
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• 제29권7호
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• pp.412-424
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• 2019

Global fitting functions for Fe-selective chlorination in ilmenite($FeTiO_2$) and successive chlorination of beneficiated $TiO_2$ are proposed and validated based on a comparison with experimental data collected from the literature. The Fe-selective chlorination reaction is expressed by the unreacted shrinking core model, which covers the diffusion-controlling step of chlorinated Fe gas that escapes through porous materials of beneficiated $TiO_2$ formed by Fe-selective chlorination, and the chemical reaction-controlling step of the surface reaction of unreacted solid ilmenite. The fitting function is applied for both chemical controlling steps of the unreacted shrinking core model. The validation shows that our fitting function is quite effective to fit with experimental data by minimum and maximum values of determination coefficients of $R^2$ as low as 0.9698 and 0.9988, respectively, for operating parameters such as temperature, $Cl_2$ pressure, carbon ratio and particle size that change comprehensively. The global fitting functions proposed in this study are expressed simply as exponential functions of chlorination rate(X) vs. time(t), and each of them are validated by a single equation for various reaction conditions. There is therefore a certain practical merit for the optimal process design and performance analysis for field engineers of chlorination reactions of ilmenite and $TiO_2$.

• 한국해양공학회지
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• 제35권2호
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• pp.141-149
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• 2021

The A60 class deck penetration piece is a fire-resistance apparatus installed on the deck compartment to protect lives and to prevent flame diffusion in the case of a fire accident in a ship or offshore plant. In this study, the sensitivity of the fire-resistance performance and approximation characteristics for the A60 class penetration piece was evaluated by conducting a transient heat-transfer analysis and fire test. The transient heat-transfer analysis was conducted to evaluate the fire-resistance design of the A60 class deck penetration piece, and the analysis results were verified via the fire test. The penetration-piece length, diameter, material type, and insulation density were used as the design factors (DFs), and the output responses were the weight, temperature, cost, and productivity. The quantitative effects of each DF on the output responses were evaluated using the design-of-experiments method. Additionally, an optimum design case was identified to minimize the weight of the A60 class deck penetration piece while satisfying the allowable limits of the output responses. According to the design-of-experiments results, various approximate models, e.g., a Kriging model, the response surface method, and a radial basis function-based neural network (RBFN), were generated. The design-of-experiments results were verified by the approximation results. It was concluded that among the approximate models, the RBFN was able to explore the design space of the A60 class deck penetration piece with the highest accuracy.

• Corrosion Science and Technology
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• 제20권4호
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• pp.204-209
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• 2021

Corrosion failure analysis of the flow plate, which is one of the accessories of the plate heat exchanger in a district heating system, was performed. The flow plate is made of 316 stainless steel, and water at different temperatures in the flow plate exchanges heat in a non-contact manner. The flow plate samples in which water mixing issues occurred were collected. Corrosion-induced pits, oxides, and contaminants were observed at locations where two plates are regularly in contact. The EDS analysis of the surface oxides and contaminants revealed that they were composed of carbon, silicon, and magnesium, which came from chemical adhesives. The IC/ICP analyses showed that the concentration of chloride ions was 30 ~ 40 ppm, which was not sufficient to cause corrosion of stainless steel. In the crevice, a local decrease in dissolved oxygen occurs along with an increase in chloride ions, thus forming an acidic environment. These environments destroyed the passive film of stainless steel, resulting in pits. Moreover, contaminants formed a narrower gap between the two metal plates and inhibited the diffusion of ions, thereby accelerating crevice corrosion.

• 대한금속재료학회지
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• 제47권9호
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• pp.573-579
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• 2009

Titanium/aluminum/stainless steel(Ti/Al/STS) clad materials have received much attention due to their high specific strength and corrosion-resisting properties. However, it is difficult to fabricate these materials, because titanium oxide is easily formed on the titanium surface during heat treatment. The aim of the present study is to derive optimized cladding conditions and thereupon obtain the stable quality of Ti/Al/STS clad materials. Ti sheets were prepared with and without pre-heat treatment and Ti/Al/STS clad materials were then fabricated by cold rolling and a post-heat treatment process. Microstructure of the Ti/Al and STS/Al interfaces was observed using a Scanning Electron Microscope(SEM) and an Energy Dispersed X-ray Analyser(EDX) in order to investigate the effects of Ti pre-heat treatment on the bond properties of Ti/Al/STS clad materials. Diffusion bonding was observed at both the Ti/Al and STS/Al interfaces. The bonding force of the clad material with non-heat treated Ti was higher than that with pre-heat treated Ti before the cladding process. The bonding force decreased rapidly beyond $400^{\circ}C$, because the formed Ti oxide inhibited the joining process between Ti and Al. Bonding forces of STS/Al were lower than those of Ti/Al, because brittle $Fe_3Al$, $Al_3Fe$ intermetallic compounds were formed at the interface of STS/Al during the cladding process. In addition, delamination of the clad material with pre-heat treated Ti was observed at the Ti/Al interface after a cupping test.

• 대한금속재료학회지
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• 제47권8호
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• pp.488-493
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• 2009

Direct syntheses of bulk $Ti_3Al$ via electro-discharge-sintering (EDS) of a stoichiometric elemental powder mixture were investigated. A capacitor bank of $450{\mu}F$ was charged with three input energies, 0.5, 1.0, and 1.5 kJ. The charged capacitor bank was then instantaneously discharged through 0.3 g of a Ti-25.0 at.%Al powder mixture for consolidation. Complete phase transformation occurred in less than $200{\mu}sec$ by the discharge and a bulk $Ti_3Al$ compact was obtained. Compared with consolidated samples fabricated by conventional methods such as high vacuum sintering and casting, the electro-discharge-sintered $Ti_3Al$ compact shows a very fine microstructure with a hardness value of 425 Hv. Electro-discharge-sintering under a $N_2$ atmosphere successfully modified the surface Ti oxide of the $Ti_3Al$ compact into Ti nitride, which concurred with the synthesis and consolidation of $Ti_3Al$. Complete conversion yielding a single phase $Ti_3Al$ is primarily dominated by the fast solid state diffusion reaction.