• 제목/요약/키워드: Surface decontamination

검색결과 141건 처리시간 0.037초

RF 플라즈마를 이용한 금속 코발트와 몰리브데늄의 표면 식각 연구 (A Study on Surface Etching of Metallic Co and Mo in R.F. Plasma)

  • 서용대;김용수;정종헌;오원진
    • 한국표면공학회지
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    • 제34권1호
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    • pp.10-16
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    • 2001
  • Recently plasma etching research has been focused on the metal surfaces in the nuclear industry. In this study, surface etching reaction of metallic Co and Mo, principal contaminants in the spent nuclear components, in CF$_4$/O$_2$, gas plasma has been experimentally investigated to look into the applicability and the effectiveness of the technique for the surface decontamination. Experimental variables are $CF_4$/$O_2$ ratio and substrate temperature between 29$0^{\circ}C$ and 38$0^{\circ}C$. Experimental results Show that the optimum gas composition is 80%CF$_4$-20%$O_2$ and the metallic Co and Mo are etched out well enough in the temperatures range. Cobalt starts to be etched above $350^{\circ}C$ and the etching rate increases with increasing substrate temperature. Maximum rate achieved at 38$0^{\circ}C$ under 220 W r.f. plasma power is 0.06 $\mu\textrm{m}$/min. On the other hand, the metallic Mo is etched easily even at low temperature and the reaction rate drastically increases as the substrate temperature goes up. Highest rate obtained under the same conditions is $1.9\mu\textrm{m}$/min. OES (Optical Emission Spectroscopy) analysis reveals that the intensities of F atom and CO molecule reach maximum at the optimum gas composition, which demonstrates that the principal reaction mechanism is fluorination and/or carbonyl reaction. It is confirmed, therefore, that dry processing technique using reactive plasma is quite feasible and applicable for the decontamination of surface-contaminated parts or equipments.

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532 nm 파장의 큐스위치 Nd:YAG 레이저를 이용한 스테인리스 스틸 표면 제염특성 (Decontamination Characteristics of 304 Stainless Steel Surfaces by a Q-switched Nd:YAG Laser at 532 nm)

  • 문제권;바이갈마;원휘준;이근우
    • 방사성폐기물학회지
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    • 제8권3호
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    • pp.181-188
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    • 2010
  • 레이저 용발법에 의한 금속 표면 제염특성을 평가하였다. 레이저로는 파장 532 nm, 펄스에너지 150 mJ, 펄스폭 5 ns의 큐스위치 Nd:YAG를 적용하였고, 금속 표면에 $CsNO_3$, $Co(NH_4)_2(SO_4)_2$, $Eu_2O_3$ 그리고 $CeO_2$를 오염시켜 이들의 제염 특성을 평가하였다. 제염 변수로는 레이저 적용횟수, 레이저 에너지 밀도 및 레이저 조사 각도 특성을 평가하였으며 각각 8, 13.3 J/$cm^2$$30^{\circ}$의 최적 조건을 확인하였다. 제염 효율은 오염성분의 비점과 관련이 있었으며 $CsNO_3>Co(NH_4)_2(SO_4)_2>Eu_2O_3>CeO_2$ 순이었다. 또한 여러 에너지 밀도 조건에서 스테인레스 스틸 재질의 식각 깊이 제어 특성을 규명하였다.

CHEMICAL DECONTAMINATION OF SOIL CONTAMINATED WITH Cs-137

  • H. J. Won;Kim, G. N.;C. H. Jung;Park, W. K.;Kim, M. G.;W. Z. Oh;Park, J. H.
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 Proceedings of the 4th Korea-China Joint Workshop on Nuclear Waste Management
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    • pp.83-95
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    • 2004
  • The removal efficiency of several washing agents on the $Cs^+$ ion was investigated. Leaching of $Cs^+$ ion from the soil surface by washing agents is affected by the exchange capability of the washing solution. Reuse tests of the effective soil washing agents such as $BaCl_2$, NaOH, citric acid+ $HNO_3$ and oxalic acid were performed. NaOH, citric acid + $HNO_3$ and oxalic acid solutions can be reused after passing through the ion exchange column. Among the tested solutions, both of citric acid+ $HNO_3$ and oxalic acid were effective for the decontamination of TRIGA research reactor soil. The radioactivity of soils can be reduced to a release level by the successive application.

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생물테러시 실내제독을 위한 효율적인 오존가스의 적용 방법 (Application of Gaseous Ozone for Cleaning Biological Weapon Agent Contaminated Building)

  • 윤제용;정우동;문성민;조민
    • 한국군사과학기술학회지
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    • 제11권2호
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    • pp.101-108
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    • 2008
  • This study attempted to develop the technology by gaseous ozone for decontaminating building affected by a model of biological weapon agent(Bacillus subtilis spores) instead of Bacillus anthracis spore. The use of ozone is attractive method from a practical point of view of decontamination procedure since it has strong oxidation power but no residue after application. We examined the disinfection efficiency of gaseous ozone to Bacillus subtilis spores which suspension was sprayed on different material surfaces and dried. Three different types of gaseous ozone was applied : dry ozone, dry ozone with humidified air, and water bubbled wet ozone. Dry ozone(1500ppm) failed to achieve any significant inactivation for 2hrs. However, six log reduction of B. subtilis spore was achieved within 30min by 1500ppm of water bubbled wet ozone. This result shows the noticeable inactivation efficiency by gaseous ozone compared with previous studies. Good performance by wet ozone was also found for military material surface.(i.e. : gas mask hood, protective garments, army peinted metal surface).

Effect of Spinal Cord Removal before or after Splitting and Washing on CNST Decontamination of Beef Carcasses

  • Lim, D.G.;Kim, D.H.;Lee, M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제20권11호
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    • pp.1770-1776
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    • 2007
  • Beef carcasses were examined to explore the effects of spinal cord removal and washing on central nervous system tissue (CNST) decontamination of the surface during the slaughtering process. A total of 15 carcasses were split by sawing centrally down the vertebral column and left sides of split carcasses were used for analysis. Samples were collected by swabbing the surface from 4 defined parts on the interior and 4 on the exterior of carcasses from the abattoir and analyzed using an ELISA-based test. The results showed that automatic and manual spray washing decreased CNST contamination, especially on the interior ventral parts of carcass surfaces (p<0.01), but did not decrease CNST on the interior dorsal parts. Increasing washing time to 60 s did not affect the reduction of CNST contamination. Samples following spinal cord removal prior to splitting showed lower calculated levels of "risk material" than the stated limit of detection (0.1%) of the ELISA kit on interior and exterior carcass parts (p<0.01). Therefore, spinal cord removal prior to splitting could be a very effective way to minimize CNST contamination of beef carcasses.

Acceptable Decontamination Factor for Near-Surface Disposal of PEACER Wastes

  • Kim, Sung-Il;Lee, Kun-Jai
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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    • pp.280-289
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    • 2005
  • A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DE As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than $98.5\%$ of LLFP have to be removed to meet below dose constraint within the DF more than 5.0E+03. Besides, because of the relative short half-life of Sr-90, the increasing of the institutional control period is recommended for most important input parameter to determine DF.

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