• Journal of Surface Science and Engineering
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• v.33 no.2
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• pp.77-86
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• 2000

In this study effects of La starting compounds and substrates on the densification of (P $b_{0.92}$L $a_{0.05}$)Ti $O_3$ thin films were investigated. After the heat treatment on platinized silicon at $650^{\circ}C$ for 30min thickness of PLT(i) thin films (from La-isopropoxide) shrank by 27%, while 33% reduction occurred for PLT (a) thin films (from La-acetate). These PLT(i) films showed less densified surface microstructure compared to the PLT (a) . Lower shrinkage of the films on platinized silicon than on bare silicon (41% and 40% for PLT (i) and PLT (a) respectively) is attributed to the earlier development of crystallinity in the film, which arrests film densification. In order to maximize sintering before crystallization, heat treatment at $400^{\circ}C$ for 3 hours followed by $650^{\circ}C$ for 30 min was attempted. This method increased the shrinkage of the PLT (i) and PLT (a) films two times and 1.5 times as much as that observed for the films heat treated at $650^{\circ}C$ for 30min, respectively. FTIR results indicated that first pyrolysis in the film is associated with the burning of acetate ligands. Condensation reaction between OHs was found to occur preferentially between $350^{\circ}C$ and $450^{\circ}C$, whereas majority of polycondensation between ROH-OH appears to occur until $300^{\circ}C$ and be completed below $450^{\circ}C$.EX>.

• Journal of the Korean Society of Safety
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• v.14 no.1
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• pp.101-107
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• 1999

$TiO_2$ and $xTiO_2-ySiO_2$ system photocatalysts were developed by sol-gel method based on the change of production parameters, and their structure of crystallization and the specific surface area was measured. Considering the efficiency of the ethanol decomposition using the catalyst, the conclusion was made as follows: 1) By means of X-ray analysis of $TiO_2$ powder that is obtained from water and Titanium alkoxide with various molar ratios, it is shown that structure of crystallization is a dominating structure and, on the other hand, the crystallization of rutile also partly exists. The specific surface area is at its maximum value at R=6, which is the molar ratio of water vs. alkoxide, whereas its value goes down as the molar ratio increases. In the reaction of using $TiO_2$ catalyst, the ethanol is decomposed into the extent of 15 ~30% in an hour and three hours are necessitated for 70% decomposition. 2) $TiO_2/SiO_2$ powder is developed from Titanium and Silicon alkoxide by a hetero-condensation process. The increase of SiO$_2$ contents causes the decrease of the degree of crystallization of the gel, whereas the specific surface area preferentially increases. In the decomposition reaction of the ethanol, the decomposition efficiency represents 25~60% in an hour. It is, however, examined that the efficiency inactively increases corresponding to the duration of reaction time. It is shown that more than 90% of ethanol is decomposed when reaction time is about three hours and the efficiency illustrates the maximum value for 60-$TiO_2/4O-SiO_2$ catalyst.

• 한국해양학회지
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• v.30 no.4
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• pp.341-354
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• 1995

Fluorescence characteristic and amino acids composition of organic matter were determined from extracted seawater samples at eight stations in the East Sea of Korea. Organic compounds have been extracted onto C-18 Sep-Pak cartridges. Three dimensional excitation/emission fluorescence contouring of extracts showed two markedly distinct characterized fluoroscopies representing protein-like biomacromolecule and humic-like geomacromolecule. Protein-like biomacromolecule showing fluorescence maxima at 280 nm/330 nm (excitation/emission) were abundant in the surface mixed layer and then apparently decreased below the thermocline at most stations. It suggests that source of biomacromolecule is comely related with vigorous biological synthetic activity in the surface layer and bacteria decompose its biologically labile components near the thermocline and in the deeper layer. On the other hand, humiliate geomacromolecule showing fluorescence maxima at 330 nm/430 nm (excitation/emission) were low in the surface mixed layer implying photochemical oxidation and then increased below the thermocline at most stations. It suggests that geomacromolecule might be transformed by condensation of bio-refractoryorganic fraction after decomposition of biomacromolecule and particulate organic carbon derived from the surface mixed layer. HPLC measurements of amino acids showed similar composition between seawater and extracted organic macromolecule after hydrolysis. Glycine, serine and alanine were predominant, accounting for more than 50% of total amino acids. Dissolved free amino acids of seawater were more abundant in the surface layer(0.7∼1.8 uM) than the deeper layer (0.2∼0.4 uM). D/L racemic ratio of alanine of extracted organic matter showed lower value in the surface layer than the deeper layer. It suggests that biomacromolecule predominant in the surface layer is relatively young, rapidly recycling and biologically labile.

• Mycobiology
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• v.36 no.2
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• pp.93-98
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• 2008

Two Schiff base ligands $L_1\;and\;L_2$ were obtained by the condensation of glycylglycine respectively with imidazole-2-carboxaldehyde and indole-3-carboxaldehyde and their complexes with Zn(II) were prepared and characterized by microanalytical, conductivity measurement, IR, UV-Vis., XRD and SEM. The molar conductance measurement indicates that the Zn(II) complexes are 1:1 electrolytes. The IR data demonstrate the tetradentate binding of $L_1$ and tridentate binding of $L_2$. The XRD data show that Zn(II) complexes with $L_1\;and\;L_2$ have the crystallite sizes of 53 and 61 nm respectively. The surface morphology of the complexes was studied using SEM. The in vitro biological screening effects of the investigated compounds were tested against the bacterial species Staphylococcus aureus, Escherichia coli, Klebsiella pneumaniae, Proteus vulgaris and Pseudomonas aeruginosa and fungal species Aspergillus niger, Rhizopus stolonifer, Aspergillus flavus, Rhizoctonia bataicola and Candida albicans by the disc diffusion method. A comparative study of inhibition values of the Schiff base ligands and their complexes indicates that the complexes exhibit higher antimicrobial activity than the free ligands. Zinc ions are proven to be essential for the growth-inhibitor effect. The extent of inhibition appeared to be strongly dependent on the initial cell density and on the growth medium.

• Corrosion Science and Technology
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• v.2 no.5
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• pp.207-211
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• 2003

The weather resistance of five coatings systems based on alkyd, chlorinated rubber, epoxy, polyurethane and fluoropolymer were studied by natural exposure test and accelerated test. The coatings were exposed at Hanoi station with urban industry atmosphere and at Baichay station with marine atmosphere. The degradation of coatings was evaluated by gloss measurement and surface analysis by scanning electronic microscopy. The results obtained show that among coatings tested the gloss of polyurethane and fluoropolymer coatings remained highly and those of alkyd, chlorinated rubber and epoxy coatings were very low after two years of atmospheric exposure. Under accelerating conditions the gloss of fluoropolymer coatings remained highly after 80 cycles of testing. By comparison with accelerating test in UV-condensation chamber the conditions at atmospheric stations are more aggressive.

• Journal of the Korea Institute of Building Construction
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• v.17 no.6
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• pp.493-498
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• 2017

This study is a pioneer investigation to enhance the insulation capacity of the conventional aerated concrete using hydrophobic aerogels. As the main test parameters, aerogel content varied from 0% to 40% of the foam volume. Test results showed that the compressive strength of aerated concrete containing aerogels was lower by 17%~34% than that of the conventional aerated concrete. In addition, the effect of the aerogels on reducing thermal conductivity of aerated concrete is insignificant because of the partial condensation and abnormal distribution of the hydrophobic aerogels. Hence, further hydrophilic treatment for the surface of aerogels is recommended to minimize the decrease in compressive strength and enhance the insulation capacity of aerated concrete.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.12
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• pp.1734-1743
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• 2003

Aerosol generator using an electrically heated tube furnace is a stable apparatus to supply nanometer sized aerosols by using the evaporation and condensation processes. Using this method, we can generate highly concentrated polydisperse aerosols with relatively narrow size distribution. In this work, characteristics of particle size distribution, generated from a tube furnace, were experimentally investigated. We evaluated effects of several operation parameters on particle generation: temperature in the tube furnace, air flow rates through the tube, size of boat containing solid sodium chloride(NaCl). As the temperature increased, the geometric mean diameter increased and the total number concentration also increased. Dilution with air affected the size distribution of the particles due to coagulation. A smaller sized boat, which has small surface area to contact with air, brings smaller particles of narrow size distribution in comparison of that of a larger boat. Finally, we changed the electrical mobility diameter of aggregate sodium chloride particles by varying relative humidity of dilution air, and obtained non-aggregate sodium chloride particles, which are easy to generate exact monodisperse particles.

• Transactions of the Korean Society of Mechanical Engineers
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• v.3 no.3
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• pp.91-97
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• 1979

Boundary layer equations (partial differential equations) can be transformed to ordinary diffential equations with constant coeffieients in terms of similarity transformed to ordinary differential equations with constant coeffieients in terms of similarity transformations in the heat tranfer analysis on the surface of any axiaymmetric boiles. The azimuth functions can not be uniquely determined because of the singular behavior at the stagnation point(X=0.deg.).In spite of the azimuth functions behaving singularly, many of researchers have analyzed the heat transfer problem on a horizontal chlinder or a sphere, supposing the set of solutions( $H_{1}$ & G$_{1}$) of being yieled from the simple differential equation to be unique solution of therazimuth functions. In order to ascertain whether mathematical incompatibility as mentioned above can be admitted in the viewpoint of enginerring or not, condensation heat transfer coefficients on a sphere are computed for all azimuth functions( $H_{1}$ G$_{1}$ & $H_{2}$ G$_{2}$) and comparisons with the experimental result are discussed.

• The Transactions of the Korean Institute of Power Electronics
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• v.20 no.2
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• pp.105-114
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• 2015

Heated glasses are widely used to prevent surface condensation and freezing in ship and building windows. This study proposes a heated glass temperature control system composed of power and control circuits to control the temperature of heated glasses. The proposed temperature control system adopts a digital controller instead of a conventional analog controller. Thus, the proposed system has better characteristics, such as precise setup and control of glass temperature, setup and control of output power, and control mode change between ON/OFF and phase controls. The system can also implement multi-functional control algorithms. The control characteristics are not dependent upon external disturbances, such as ambient temperature and electrical noises. Furthermore, the proposed temperature control system utilizes the power line communication (PLC) method to control the number of heated glasses without any extra communication lines. The system proposes a new communication protocol with strong immunity to electrical switching noises. A new sensorless algorithm is used to detect the temperature of the heated glass. This study presents the design guidelines in detail and its effectiveness are confirmed by implementing a 4-kw prototype temperature control system.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.5
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• pp.1264-1274
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• 1994

Heat transfer performance of integral-fin tube which is used in recipro turbo refrigerator or high compact heat exchangers is studied. Eight tubes with trapezoidal shaped integral-fins having fin densities from 748 to 1654 fpm and 10, 30 internal grooves are tested. A plain tube having the same(inner and outer) diameter as the fin tubes is also tested for comparison. Pool boiling heat transfer of R-11 is investigated experimentally and theoretically on single tube arrangement. The refrigerant evaporates at saturation state of 1 bar on the outside tube surface and heat is supplied by not water which circulates inside of the tube. From the result of eight fin tubes and one plain tube tested, a tube having 1299 fpm-30 grooves shows the best performance. A maximum overall heat transfer coefficient of this tube is about 4000 $W/m^{2}K$ at 2.8m/s of water velocity. The maximum heat transfer enhancement (i.e., the ratio of overall heat transfer coefficients of finned to plain tubes)is about 2.1.