• Title/Summary/Keyword: Surface area

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Effect of pore structure on electrochemical performance of EDLC (EDLC의 전기화학적 성능에 대한 메조기공 구조의 효과)

  • Lee, Myung-Suk;Shin, Yun-Sung;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.310-317
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    • 2010
  • The electrochemical properties of electric double layer capacitor(EDLC) was studied by controlling pore size distribution and specific surface area of the activated carbon fiber(ACF). The mesoporous ACF, which was prepared by the iron exchange method, showed the tendency of increasing average pore size and decreasing total surface area. The mesoporous ACF (surface area = 2225 $m^2$/g, pore size=1.93 nm) showed increased mesopore(pore size=1~3nm) volume from 0.055 cc/g to 0.408 cc/g compared to its raw ACF. The charging capacity of the EDLC which uses the prepared mesoporous ACF also increased from 0.39 F/$cm^2$ to 0.55 F/$cm^2$. From these results, it can be known that the electrochemical properties of EDLC are mainly dependent on the specific surface area, but above the surface area 2200 $m^2$/g, it is the mesopore volume that affects the performance of the capacitor considerably. Because the increased mesopore volume results in a decreased ion mobility resistance, the charge capacitance is enhanced.

Roles of displacement speed of premixed flame embedded in isotropic turbulent decaying flow (직접수치해법을 이용한 난류 예혼합 화염전파속도 연구)

  • Han, In-Suk;Huh, Kang-Yul
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.177-186
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    • 2006
  • Flame surface area is a critical parameter determining turbulent flame speed. Three-dimensionaldirect numerical simulations (DNS) were conducted to figure out the evolution process of flame surface area. Fully compressible Navier-Stokes equations are solved to reproduce premixed flame embedded in isotropic decaying turbulent flow. The tangential straining and curvature of propagating surface affect development of flame area. In this study, four different turbulent intensity flows and three different Le number flames are investigated to force changes in straining and curvature effects. Consistent results are obtained for the probability density functions (PDF) of strain and curvature with previous researches. It is revealed that displacement speed, which is a speed of flame surface relative to unburnt flow, controls the balance between sink and source of flame surface area.

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The Effects of Surface Energy and Roughness on Adhesion Force (표면에너지와 거칠기가 응착력에 미치는 영향)

  • Rha, Jong-Joo;Kwon, Sik-Cheol;Jeong, Yong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.11 s.254
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    • pp.1335-1347
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    • 2006
  • Surface energies calculated from measured contact angles between several solutions and test samples, such as Si wafer, $Al_2O_3$, $SiO_2$, PTFE(Polytertrafluoroethylene), and DLC(Diamond Like Carbon) films, based on geometric mean method and Lewis acid base method. In order to relate roughness to adhesion force, surface roughness of test samples were scanned large area and small by AFM(Atomic Force Microscopy). Roughness was representative of test samples in large scan area and comparable with AFM tip radius in small scan area. Adhesion forces between AFM tip and test samples were matched well with order of roughness rather then surface energy. When AFM tips having different radius were used to measure adhesion force on DLCI film, sharper AFM tip was, smaller adhesion force was measured. Therefore contact area was more important factor to determine adhesion force.

Roles of Displacement Speed of Premixed Flame Embedded in Isotropic Turbulent Decaying Flow (직접수치해법을 이용한 난류 예혼합 화염전파속도 연구)

  • Han, In-Suk;Huh, Kang-Yul
    • Journal of the Korean Society of Combustion
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    • v.12 no.2
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    • pp.10-19
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    • 2007
  • Flame surface area is a critical parameter determining turbulent flame speed. Three-dimensional direct numerical simulations(DNS) were conducted to figure out the evolution process of flame surface area. Fully compressible Navier-Stokes equations are solved to reproduce premixed flame embedded in isotropic decaying turbulent flow. The tangential straining and curvature of propagating surface affect development of flame area. In this study, four different turbulent intensity flows and three different Le number flames are investigated to force changes in straining and curvature effects. Consistent results are obtained for the probability density functions (PDF) of strain and curvature with previous researches. It is revealed that displacement speed, which is a speed of flame surface relative to unburnt flow, controls the balance between sink and source of flame surface area.

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CHARACTERISTICS OF RESIDUAL CARBON DERIVED FROM THE COMBUSTION OF VACUUM RESIDUE IN A TEST FURNACE

  • Park, Ho-Young;Seo, Sang-Il
    • Environmental Engineering Research
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    • v.12 no.3
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    • pp.109-117
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    • 2007
  • The characteristics of carbonaceous particles collected from the combustion of Vacuum Residue (VR) in a test furnace have been investigated. The physical and chemical characterization includes particle size, scanning electron microscopy of the surface structure, measurement of porosity, surface area and density, EDX/XRD analyses and measurement of chemical composition. The studies show that the carbonaceous VR particles are very porous and spheroidal, and have many blow-holes on the surface. The particles become smaller and more sponge-like as the reaction proceeds. The present porosity of VR particles is similar to that of cenospheres from the combustion of heavy oil, and the majority of pores are distributed in macro-pores above $0.03\;{\mu}m$ in diameter. Measurements of pore distribution and surface area showed that the macro-pores contributed most to total pore volume, whereas the micro-pores contributed to total surface area.

New Geometric modeling method: reconstruction of surface using Reverse Engineering techniques

  • Jihan Seo
    • Proceedings of the Safety Management and Science Conference
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    • 1999.11a
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    • pp.565-574
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    • 1999
  • In reverse engineering area, it is rapidly developing reconstruction of surfaces from scanning or digitizing data, but geometric models of existing objects unavailable many industries. This paper describes new methodology of reverse engineering area, good strategies and important algorithms in reverse engineering area. Furthermore, proposing reconstruction of surface technique is presented. A method find base geometry and blending surface between them. Each based geometry is divided by triangular patch which are compared their normal vector for face grouping. Each group is categorized analytical surface such as a part of the cylinder, the sphere, the cone, and the plane that mean each based geometry surface. And then, each based geometry surface is implemented infinitive surface. Infinitive average surface's intersections are trimmed boundary representation model reconstruction. This method has several benefits such as the time efficiency and automatic functional modeling system in reverse engineering. Especially, it can be applied 3D scanner and 3D copier.

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A Study on Land Surface Temperature Changes in Redevelopment Area Using Landsat Satellite Images : Focusing on Godeok-dong and Dunchon-dong in Gangdong-gu, Seoul (Landsat 위성영상을 활용한 재건축 지역의 지표 온도 변화에 관한 연구 : 서울특별시 강동구의 고덕동과 둔촌동을 중심으로)

  • Jihoon HAN;Chul SON
    • Journal of the Korean Association of Geographic Information Studies
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    • v.26 no.2
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    • pp.42-54
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    • 2023
  • The population is concentrated in the metropolitan areas in Korea, and low-density residential areas are transforming into high density residential areas through redevelopment to meet this demand. However, large-scale redevelopment in a short period of time has a negative impact on the urban climate, such as generating a heat island effect due to the reduction of urban green areas. In this study, the change in surface temperature from 2013 to 2022 in the redevelpment areas of Godeok-dong and Dunchon-dong, Gangdong-gu, Seoul, was analyzed using Landsat 8 satellite images. In the Godeok-dong area, the difference in surface temperature was analyzed for the target redevelopment area, forest area, mixed forest and urban area, and low density residential area. In the Dunchon-dong area, the difference in surface temperature was analyzed for the target redevelopment area, forest area, and low density residential area. The difference in surface temperature was analyzed through multiple regression analysis conducted yearly over the three different stages in redevelopment period. The results from the multiple regression analysis show that in both areas, the land surface temperature of target redevelopment area was higher than that of the forest area and lower than low density residential area. It can be seen that these results occurred because the low-density residential area in Godeok-dong and Dunchon-dong had a lower green area ratio and a higher building-to-land ratio than the target redevelopment area. The results of this study suggest that even if low-density residential areas are transforming into high-density areas, adjusting the management of green areas and building-to-land ratio can contribute to lessen urban heat island effect.

Electricity generation from surface floating air cathode microbial fuel cell according to the wastewater flow-rate and the ratio of cathode surface area to anode surface area (표면부유 공기양극 미생물연료전지에서 유량 및 전극 면적비에 따른 전력생산 특성)

  • Yoo, Kyu-Seon;Song, Young-Chae;Woo, Jung-Hui;Chung, Jae-Woo;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.591-596
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    • 2011
  • Surface floating air cathode microbial fuel cell (MFC) having horizontal flow was developed for the application of MFC technology. RVC (Reticulated vitreous carbon) coated with anyline was used as anode electrode and carbon cloth coated with Pt (5.0 g Pt/$m^2$, GDE LT250EW, E-TEK) was used as cathode electrode. As results of continuous operation with changing the flow rate from 4.3 mL/min to 9.5 mL/min, maximum power density of 4.5 W/$m^3$ was acquired at 5.4 mL/min, which was at 0.35 m/hr of flow velocity under anode electrode. When the ratio of cathode surface area to anode surface area($A_c/A_a$) was changed to 1.0, 0.5, and 0.25, the maximum power density of 2.7 W/$m^3$ was shown at the ratio of 1.0. As the ratio decreased from 1.0 to 0.25, the power density also decreased, which is caused by increasing the internal resistance resulted from reducing the surface area to contact with oxygen. Actually, internal resistances of the ratio of 1.0, 0.5, and 0.25 were 63.75${\Omega}$, 142.18${\Omega}$, and 206.12${\Omega}$, respectively.

A surface extension method using several functions

  • 김회섭
    • Proceedings of the Korean Society of Computational and Applied Mathematics Conference
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    • 2003.09a
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    • pp.3.2-3
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    • 2003
  • We propose a method of surface extension method using several functions. Interpolation theory is well developed in curve and surface. But extrapolation theory is not well developed because it is not unique outside the useful domain. It requires continuous, first derivative, second derivative continuous extension for matching in NC(Numerical Control) machine. In the past, we generate data outside the useful area and refit those data using least squares method. this has some problems which have some errors within the useful area. We keep the useful area and extend the unuseful area by a function

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The Changes of Specific Surface Area of Soils after Peroxidation and Its Implication for the Calculation of Critical toads of Soil Acidification (Peroxidation 전후의 토양 비표면적 변화와 토양산성화 임계부하량 계산에의 의의)

  • Yeo, Sang-Jin;Lee, Bumhan;Soyoung Sung;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.195-204
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    • 2002
  • Mineralogy and the exposed surface area are two of the most important factors controlling dissolution and weathering rates of soils. The mixture of inorganic and organic materials of various size distributions and structures that constitute soils makes the calculation of weathering rates difficult. The surface area of soil minerals plays an important role in most of programs for calculating the weathering rates and critical loads. The Brunauer-Emmett-Teller (BET) measurement is recommended for the measurement of specific surface area. However, BET values measured without organic matter removal are in fact those far all the N2-adsorbed surface areas, including the surfaces covered and aggregated with organisms. Surfaces occupied by organisms are assumed to be more reactive to weathering by organic activities. Therefore, the BET surface area difference before and after organic removal depicts the area occupied by organisms. The present study shows that the BET values after organic matter removal using $H_2$O$_2$ are larger than those without removal by 1.68~4.87 $m^2$/g. This implies that BET measurement without organic removal excludes the reactive area occupied by organisms and that the area occupied by organisms in soils is much larger than expected. It is suggested that specific surface area measurement for calculating weathering rates of mineral soils should be made before and after organic matter removal. The results of a column experiment are presented to demonstrate the potential retarding influence that this organic matter may have on mineral dissolution and weathering.