• Title/Summary/Keyword: Surface analyses

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A Study of Localized Corrosion Mechanisms in the Multilayered Coatings by Cathodic Arc Deposition (음극아크증착법으로 합성한 다층박막의 국부부식 기구에 관한 연구)

  • 김호건;안승호;이정호;김정구;한전건
    • Journal of the Korean institute of surface engineering
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    • v.36 no.4
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    • pp.301-306
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    • 2003
  • Multilayered WC-Ti/suv $1-x/Al_{x}$ N coatings were deposited on AISI D2 steel using cathodic arc deposition (CAD) method. These coatings contain structural defects such as pores or droplets. Thus, the substrate is not completely isolated from the corrosive environment. The growth defects (pores, pinholes) in the coatings are detrimental to corrosion resistance of the coatings used in severe corrosion environments. The localized corrosion behavior of the coatings was studied in deaerated 3.5 wt.% NaCl solution using electrochemical techniques (potentiodynamic polarization test) and surface analyses (GDOES, SEM, AES, TEM). The porosity was calculated from the result of potentiodynamic polarization test of the uncoated and coated specimens. The calculated porosity is higher in the $WC-Ti_{0.6}$ $Al_{0.4}$ N than others, which is closely related to the packing factor. The positive effects of greater packing factor act on inhibiting the passage of the corrosive electrolyte to the substrate and lowering the localized corrosion kinetics. From the electrochemical tests and surface analyses, the major corrosion mechanisms can be classified into two basic categories: localized corrosion and galvanic corrosion.

Structure Analyses of Rubber/Filler System under Shear Flow by Using Time Resolved USAXS Method

  • Nishitsuji, Shotaro;Takenaka, Mikihito;Amino, Naoya;Ishikawa, Yasuhiro
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.156-160
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    • 2019
  • The changes in the dispersion of carbon black in liquid polyisoprene under shear flow with time have been investigated by time-resolved ultra small-angle X-ray scattering (USAXS) method. The analyses of USAXS profile immediately after the start of shear flow clarified that the aggregates of carbon black with a mean radius of gyration of 14 nm and surface fractal dimension of 2.5 form the fractal network structure with mass-fractal dimension of 2.9. After the application of the shear flow, the scattering intensity increases with time at the observed whole entire q region, and then the a shoulder appears at $q=0.005nm^{-1}$, indicating that the agglomerate is broken and becomes smaller by shear flow. The analysis by the Unified Guinier/Power-law approach yielded several characteristic parameters, such as the sizes of aggregate and agglomerate, mass-fractal dimension of agglomerate, and surface fractal dimension of the primary particle. While the mean radius of gyration of the agglomerate decreases with time, the mean radius of gyration of the aggregate, mass fractal dimension, and surface fractal dimension don't change with time, indicating that the aggregates peel off the surface of the agglomerate.

Static and quasi-static slope stability analyses using the limit equilibrium method for mountainous area

  • Hosung Shin
    • Geomechanics and Engineering
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    • v.34 no.2
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    • pp.187-195
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    • 2023
  • Intensive rainfall during the summer season in Korea has triggered numerous devastating landslides outside of downtown in mountainous areas. The 2D slope stability analysis that is generally used for cut slopes and embankments is inadequate to model slope failure in mountainous areas. This paper presents a new 3D slope stability formulation using the global sliding vector in the limit equilibrium method, and it uses an ellipsoidal slip surface for static and quasi-static analyses. The slip surface's flexibility of the ellipsoid shape gives a lower FS than the spherical failure shape in the Fellenius, Bishop, and Janbu's simplified methods. The increasing sub-columns of each column tend to increase the FS and converge to a steady value. The symmetrical geometric conditions of the convex turning corners do not indicate symmetrical failure of the surface in 3D analysis. Pseudo-static analysis shows that the horizontal seismic force decreases the FS and increases the mass volume at the critical failure state. The stability index takes the FS and corresponding sliding mass into consideration to assess the potential risk of slope failure in complex mountainous terrain. It is a valuable parameter for selecting a vulnerable area and evaluating the overall risk of slope failure.

THD Lubrication Analysis of a Surface-Textured Parallel Thrust Bearing with Rectangular Grooves: Part 1 - Effect of Film-Temperature Boundary Condition (사각형 그루브로 Surface Texturing한 평행 스러스트 베어링의 열유체윤활 해석: 제1보 - 유막온도경계조건의 영향)

  • Park, TaeJo;Kang, JeongGuk
    • Tribology and Lubricants
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    • v.38 no.6
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    • pp.267-273
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    • 2022
  • Surface texturing is the latest technology for processing grooves or dimples on the friction surface of a machine. When appropriately applied, it can reduce friction and significantly increase durability. Despite many studies over the past 20 years, most are isothermal (ISO) analyses in which the viscosity of the lubricant is constant. In practice, the viscosity changes significantly owing to the heat generated by the viscous shear of the lubricant and film-temperature boundary condition (FTBC). Although many thermohydrodynamic (THD) analyses have been performed on various sliding bearings, only few results for surface-textured bearings have been reported. This study investigates the effects of the FTBC and groove number on the THD lubrication characteristics of a surface-textured parallel thrust bearing with multiple rectangular grooves. The continuity, Navier-Stokes, and energy equations with temperature-viscosity-density relations are numerically analyzed using a commercial computational fluid dynamics code, FLUENT. The results show the pressure and temperature distributions, variations of load-carrying capacity (LCC), and friction force with four FTBCs. The FTBCs greatly influence the lubrication characteristics of surface-textured parallel thrust bearings. A groove number that maximizes the LCC exists, which depends on the FTBC. ISO analysis overestimates the LCC but underestimates friction reduction. Additional analysis of various temperature boundary conditions is required for practical applications.

Analyses on the Increment of Surface Hydrophobicity of Epoxy Composites by Thermal Treatment (열철리에 따른 Epoxy 복합재료의 표면 소수성증가에 관한 해석)

  • Lim, Kyung-Bum;Lee, Beak-Su;Chung, Mu-Yong;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.4
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    • pp.153-160
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    • 2001
  • In order to analyze the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to high temperature. Then, the degradation process was evaluated by comparing contact angle, surface potential, surface resistivity, and XPS. The experimental results showed that the amount of weight loss, contact angle, surface potential and surface resistivity increased up to 200 $^{\circ}C$ as a function of temperature. These phenomena show the existence of hydrophobic surface. With the change to the hydrophobic surface and the electrical potential and resistivity on FRP surface increased. In XPS to analyze surface chemical structures, the increased hydrophobicity in thermal increase of unsaturated double bond in carbon chains. Aslo, thermal treatment caused the discoloration on the point of treated surface. These phenomena were attributed to the generations of ether group.

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A Study on the Surface Analysis of Plasma-Treated PET Film (플라즈마 처리된 PET 필름의 표면분석에 관한 연구)

  • Lim Kyung-Bum;Choi Hoon-Young;Lee Seok-Hyun;Lee Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.12
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    • pp.596-600
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    • 2004
  • In this study, the surface properties of PET film were analyzed after plasma surface treatment. After plasma treatment of surface roughness and XPS were evaluated to analyze the chemical property, while the surface potential decay and surface resistance rate was measured to analyze the electric관 characteristic. When plasma discharge treatment was conducted for less than 10 minutes, the electrical insulating property was improved by evaporation of low molecular weight materials and cleaning of surface. However, when the treatment was conducted for more than 10 minutes, the insulating property was decreased due to excessive discharge energy. Analyses of chemical characteristics showed that 10-minute treatment resulted in increase of C-O and O=C-O bonds. However, when treated for more than 10 minutes. they were relatively decreased.

Prediction of bending fatigue lifes of rail welded parts (레일용접부 피로수명 예측)

  • 양신추;이진욱;나성훈
    • Proceedings of the KSR Conference
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    • 1999.05a
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    • pp.390-397
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    • 1999
  • This paper investigates about the prediction of rail bending fatigue lifes for the purpose of the effective maintenance of surface irregularities of rail welded parts. The rail bending stresses are calculated using a track dynamic analysis program. The rail surface irregularities measured in situ are given as inputs in the analyses. On the other hand, the S-N curves are derived based on the results of bending fatigue tests. Using data found so far, rail fatigue lifes are estimated adopting a modified Miner's rule. The useful guides for maintenance of rail welded part are proposed in terms of grinding period and grinding depth of rail surface irregularities.

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ON CRACK INTERACTION EFFECTS OF IN-PLANE SURFACE CRACKS USING ELASTIC AND ELASTIC-PLASTIC FINITE ELEMENT ANALYSES

  • Kim, Jong-Min;Huh, Nam-Su
    • Nuclear Engineering and Technology
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    • v.42 no.6
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    • pp.680-689
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    • 2010
  • The crack-tip stress fields and fracture mechanics assessment parameters for a surface crack, such as the elastic stress intensity factor or the elastic-plastic J-integral, can be affected significantly by the adjacent cracks. Such a crack interaction effect due to multiple cracks can alter the fracture mechanics assessment parameters significantly. There are many factors to be considered, for instance the relative distance between adjacent cracks, the crack shape, and the loading condition, to quantify the crack interaction effect on the fracture mechanics assessment parameters. Thus, the current assessment codes on crack interaction effects (crack combination rules), including ASME Sec. XI, BS7910, British Energy R6 and API 579-1/ASME FFS-1, provide different rules for combining multiple surface cracks into a single surface crack. The present paper investigates crack interaction effects by evaluating the elastic stress intensity factor and the elastic-plastic J-integral of adjacent in-plane surface cracks in a plate through detailed 3-dimensional elastic and elastic-plastic finite element analyses. The effects on the fracture mechanics assessment parameters of the geometric parameters, the relative distance between two cracks, and the crack shape are investigated systematically. As for the loading condition, an axial tension is considered. Based on the finite element results, the acceptability of the crack combination rules provided in the existing guidance was investigated, and the relevant recommendations on a crack interaction for in-plane surface cracks are discussed. The present results can be used to develop more concrete guidance on crack interaction effects for crack shape characterization to evaluate the integrity of defective components.

A Study on Characteristics of Surface Modified Polyimide Film by Wet Process (습식 표면개질 처리된 폴리이미드 필름 표면의 특성에 관한 연구)

  • Koo, S.B.;Lee, H.K.
    • Journal of the Korean institute of surface engineering
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    • v.39 no.4
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    • pp.166-172
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    • 2006
  • Metallized Polyimide films are extensively used as base materials in microelectronics, optical and automotive applications. However it is difficult to deposit metals on those because of their structural stabilities. In this work, polyimide films are modified by a wet process with alkalinemetalhydroxide and additives to introduce functional groups. The surface molecular structures of polyimide are investigated using X-ray photoelectron spectroscopy(XPS), fourier transform infrared reflection spectroscopy(FTIR-ATR), atomic force micro-scopic(AFM). XPS spectra and FTIR spectra show that the surface structure of polyimide is converted into potassium polyamate. AFM image and AFM cross-sectional analyses reveal the increased roughness on the modified surface of polyimide films. As a result, it is shown that the adhesion strength between polyimide surface and electroless nickel layer is increased by the nano-anchoring effect.

Peel Strength Analyses of Copper/Epoxy System (구리/에폭시 계의 필 접착력 분석)

  • 최광성;유진;이호영
    • Journal of the Korean institute of surface engineering
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    • v.29 no.4
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    • pp.238-252
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    • 1996
  • In order to study the effect of interface oxides on the adhesion strength of the copper/epoxy system, copper foils were immersed in black oxide or brown oxide forming solutions before lamination with epoxy prepregs, and variation of peel strength with the treatment time were investigated. Results showed that peel strength decreased rapidly up to 1 minute of treatment lime and remained constant in the case of the black oxide treated specimens, which was accompanied by the thickening of $Cu_2O$ at the Copper/Epoxy interface during the period. In contrast, peel strength increased rapidly up to 1 minute of treatment time and remained constant in the case of the brown oxide treated specimens, which could be ascribed to the thickening of CuO. Subsequent heat treatments of the Copper/Epoxy laminations at $120^{\circ}C$ in air showed that peel strength remained constant in the case of the black oxide treated specimens but decreased gradually in the case of the brown oxide treated specimens. Following XPS analyses revealed that the latter was possibly caused by the coalescence of CuO at the Copper/Epoxy interface into $Cu_2O$.

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