• Journal of Environmental Impact Assessment
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• v.28 no.3
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• pp.245-262
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• 2019

The objectives of this study were to construct a three-dimensional water quality model (EFDC) for the river reach between Chilgok Weir and Gangjeong-Goryong Weir (GGW) located in Nakdong River, and evaluate the effect of hydraulic changes, such as water level and flow velocity, on the control of water quality and algae biomass. After calibration, the model accurately simulated the temporal changes of the upper and lower water temperatures that collected every 10 minutes, and appropriately reproduced changes in organic matter, nitrogen, phosphorus, and cyanobacteria. However, the simulated values were overestimated for the diatoms and green algae cell density, possibly due to the uncertainties of the parameters associated with algae metabolism and the lack of zooplankton predation function in the simulations. As a result of scenario simulation of running the water level of GGW from EL. 19.44 m to EL. 14.90 m (4.54 m drop), Chl-a and algae cell density decreased significantly.In particular,the cyanobacteria on the surface layer, which causes algal bloom, declined by 56.1% in the low water level scenario compared to the existing management level. The results of this study are in agreement with the previous studies that maintenance of critical flow velocity is effective for controlling cyanobacteria, and imply that hydraulic control such as decrease of water level and residence time in GGW is an alternative to limit the overgrowth of algae.

• Korean Journal of Materials Research
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• v.29 no.2
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• pp.92-96
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• 2019

Transition metal oxide is widely used as a water electrolysis catalyst to substitute for a noble metal catalyst such as $IrO_2$ and $RuO_2$. In this study, the sol-gel method is used to synthesize the $Cu_xCo_{3-x}O_4$ catalyst for the oxygen evolution reaction (OER),. The CuxCo3-xO4 is synthesized at various calcination temperatures from $250^{\circ}C$ to $400^{\circ}C$ for 4 h. The $Cu_xCo_{3-x}O_4$ synthesized at $300^{\circ}C$ has a perfect spinel structure without residues of the precursor and secondary phases, such as CuO. The particle size of $Cu_xCo_{3-x}O_4$ increases with an increase in calcination temperature. Amongst all the samples studied, $Cu_xCo_{3-x}O_4$, which is synthesized at 300?, has the highest activity for the OER. Its onset potential for the OER is 370 mV and the overpotential at $10mA/cm^2$ is 438 mV. The tafel slope of $Cu_xCo_{3-x}O_4$ synthesized at $300^{\circ}C$ has a low value of 58 mV/dec. These results are mainly explained by the increase in the available active surface area of the $Cu_xCo_{3-x}O_4$ catalyst.

• Clean Technology
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• v.24 no.4
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• pp.307-314
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• 2018

In this study, NMO (Natural Manganese Ore), $MnO_2$, and $Mn_2O_3$ catalysts were used in the selective catalytic reduction process to remove nitrogen oxides (NOx) using $NH_3$ as a reducing agent at low temperatures in the presence of oxygen. In the case of the NMO (Natural Manganese Ore), it was confirmed that the conversion of nitrogen oxides in the stability test did not change even after 100 hours at 423 K. The Kinetics experiments were carried out within the range where heat and mass transfer were not factors. From a steady-state Kinetics study, it was found that the low-temperature SCR reaction was zero order with the respect to $NH_3$ and 0.41 ~ 0.57 order with the respect to NO and 0.13 ~ 0.26 order with the respect to $O_2$. As temperature increases, the reaction order decreases as a result of $NH_3$ and oxygen concentration. It was confirmed that the reaction between the $NH_3$ dissociated and adsorbedon the catalyst surface and the gaseous nitrogen monoxide (E-R model) and the reaction with the adsorbed nitrogen monoxide (L-H model) occur.

• Korean Journal of Optics and Photonics
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• v.29 no.6
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• pp.241-246
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• 2018

In this paper, a low-cost optical temperature sensor is implemented, using a fiber Bragg grating (FBG) as the temperature probe and a low-cost VCSEL with temperature-dependent output wavelength as the light source. To analyze the wavelength of the reflected light from the FBG, an interrogation was applied using a method of referring to the internal temperature according to the output wavelength of the VCSEL. When the temperature of the VCSEL was adjusted from 14 to $52.2^{\circ}C$, the output wavelength varied from 1519.90 to 1524.25 nm. The degree of wavelength tuning according to temperature was $0.114nm/^{\circ}C$. The variable wavelength repeatability error according to temperature was ${\pm}0.003nm$, and the temperature measurement error was ${\pm}0.18^{\circ}C$. As a result of measuring the temperatures from 22.3 to $194.2^{\circ}C$, the value of the internal temperature change of the light source according to the applied temperature ${\Delta}T$ was $0.146^{\circ}C/{\Delta}T$, the change in reflected wavelength of the temperature probe according to applied temperature ${\Delta}T$ was measured at $16.64pm/^{\circ}C$. and the temperature measurement error of the sensor was ${\pm}1^{\circ}C$.

• The Journal of the Korea institute of electronic communication sciences
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• v.14 no.3
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• pp.497-504
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• 2019

We fabricated $HfO_2$ thin films using RF magnetron sputtering method, and investigated structural and optical properties of $HfO_2$ thin films with RTA temperatures in $N_2$ ambient. $HfO_2$ thin films exhibited polycrystalline structure regardless of annealing process, FWHM of M (-111) showed reduction trend. The surface roughness showed the smallest of 3.454 nm at a annealing temperature of $600^{\circ}C$ in result of AFM. All $HfO_2$ thin films showed the transmittance of about 80% in visible light range. By fitting the refractive index from the transmittance and reflectance to the Sellmeir dispersion relation, we can predict the refractive index of the $HfO_2$ thin film according to the wavelength. The $HfO_2$ thin film annealed at $600^{\circ}C$ exhibited a high refractive index of 2.0223 (${\lambda}=632nm$) and an excellent packing factor of 0.963.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.4
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• pp.497-502
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• 2019

Metal oxide nanostructures are promising materials for advanced applications, such as high sensitive gas sensors, and high capacitance lithium-ion batteries. In this study, tin oxide (SnO) nanostructures were grown on a Si wafer substrate using a two-zone horizontal furnace system for a various substrate temperatures. The raw material of tin dioxide ($SnO_2$) powder was vaporized at $1070^{\circ}C$ in an alumina crucible. High purity Ar gas, as a carrier gas, was flown with a flow rate of 1000 standard cubic centimeters per minute. The SnO nanostructures were grown on a Si substrate at $350{\sim}450^{\circ}C$ under 545 Pa for 30 minutes. The surface morphology of the as-grown SnO nanostructures on Si substrate was characterized by field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). Raman spectroscopy was used to confirm the phase of the as-grown SnO nanostructures. As the results, the as-grown tin oxide nanostructures exhibited a pure tin monoxide phase. As the substrate temperature was increased from $350^{\circ}C$ to $424^{\circ}C$, the thickness and grain size of the SnO nanostructures were increased. The SnO nanostructures grown at $450^{\circ}C$ exhibited complex polycrystalline structures, whereas the SnO nanostructures grown at $350^{\circ}C$ to $424^{\circ}C$ exhibited simple grain structures parallel to the substrate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.4
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• pp.458-463
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• 2019

Palladium (Pd) is widely used as a catalyst and noxious gas sensing materials. Especially, various researches of Pd based hydrogen gas sensor have been studied due to the noble property, Pd can be adsorbed hydrogen up to 900 times its own volume. In this study, palladium oxide (PdO) nanostructures were grown on Si substrate ($SiO_2(300nm)/Si$) for 3 to 5 hours at $230^{\circ}C{\sim}440^{\circ}C$ using thermal chemical vapor deposition system. Pd powder (source material) was vaporized at $950^{\circ}C$ and high purity Ar gas (carrier gas) was flown with the 200 sccm. The surface morphology of as-grown PdO nanostructures were characterized by field-emission scanning electron microscopy(FE-SEM). The crystallographic properties were confirmed by Raman spectroscopy. As the results, the as-grown nanostructures exhibit PdO phase. The nano-cube structures of PdO were synthesized at specific substrate temperatures and specific growth duration. Especially, PdO nano-cube structrures were uniformly grown at $370^{\circ}C$ for growth duration of 5 hours. The PdO nano-cube structures are attributed to vapor-liquid-solid process. The nano-cube structures of PdO on graphene nanosheet can be applied to fabricate of high sensitivity hydrogen gas sensor.

• Korean Journal of Remote Sensing
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• v.35 no.2
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• pp.327-336
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• 2019

The caldera lake "Chun-ji" is located at the summit of Baekdu volcano, which is in the border of China and North Korea. Chun-ji Lake has altitude 2,189 m above sea level. The Chun-ji is freezing in the winter when the water temperature goes down to zero for a year, and it melts in the season when the water temperature goes up again. However,since it is located at a high altitude, there are many cloudy days, and it is difficult to observe with optical images. For this reason, radar images, which are less influenced by weather than optical images, are more effective for observing the ice of heaven and earth. In this study, 75 TerraSAR-X images from chun-ji area were used for analysis from 2015 to 2017, and the calculated ice area and temperature changes were analyzed. As a result, the ice of the caldera lake formed was formed in early December and slowly melted until mid-April. During this period, temperatures in the Samjiyeon area were about $-10^{\circ}C$ when ice was produced, and the temperature was about $0^{\circ}C$ in mid-April when it was thawing. Correlation coefficients between ice surface area and temperature in winter 2015 and 2016, where global ice is produced,show a high correlation of -0.82 and -0.75. In addition to the results of this study, it can be used as an indicator to monitor the volcanic activity by comparing the result of the recent volcanic activity with the result of the increase in water temperature using various imagery.

• Journal of Wetlands Research
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• v.24 no.4
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• pp.367-376
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• 2022

LID technologies are capable of mitigating the negative impacts of non-point source (NPS) pollution generated in different land uses. Apart from the increase in point and non-point pollutant generation, highly developed and paved areas generally affect microclimate conditions. This study evaluated both the efficiency of Low Impact Development (LID) facilities in treating NPS pollutant loads as well as the unit pollutant loads (UPL) generated in various urban features (such as parking lots and highways). This investigation also looked at how LID technology helped to alleviate Urban Heat Island (UHI) conditions. As compared to the typical unit pollutant loads in South Korea, the unit pollutant loads at Kongju National University were relatively low, because of no classes, limited vehicular transmission, and low anthropogenic activities during vacation. After receiving treatment from the LID facilities, the effluent pollutant loads were significantly decreased. The sedimentation in filtration mechanisms considerably reduced the pollutant fractions in the influent. Additionally, it was shown that LID facilities' mean surface temperatures are up to 7.2℃ lower than the nearby paved environment, demonstrating the LID systems reducing the UHI impact on an urban area.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.35-41
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• 2021

VWTi, which is used as a commercial catalyst in NH3-SCR, exhibits excellent denitrification performance at 300 to 400 ℃, but there is a problem that efficiency decreases at low temperatures below 300 ℃. Research on catalysts containing promoter to increase low-temperature denitrification efficiency is steadily progressing. However, research on the cause of the improvement in low-temperature denitrification efficiency of the catalyst and the catalyst properties is insufficient. In this study, it was confirmed that by adding Sb to VWTi, denitrification performance was improved by more than 10% in NH3-SCR reaction below 300 ℃. At this time, the space velocity and the size of the catalyst particles were controlled to exclude the influence of external/internal diffusion. In addition, the catalytic properties according to the presence or absence of Sb were investigated by performing BET, TEM/EDS, O2-TPD, H2-TPR and DRIFTs analysis. It was judged that the addition of Sb increased the adsorbed oxygen species on the surface of the catalyst, thereby enhancing the redox properties of the catalyst at low temperature and exhibiting excellent denitrification performance.