• Ocean and Polar Research
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• v.28 no.3
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• pp.331-337
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• 2006

Organophosphorus pesticides (OPs) were analyzed in surface water samples from the Saemangeum environment. IBP was the most abundant among 10 OPs analyzed, and accounted fur over 95% of total amount of OPs. Concentrations of IBP measured in Mangyeong River water and surface seawater ranged from 670 to 1100ng/l and from 45 to 1000 ng/l, respectively. In general, a decreasing trend of OP concentrations towards open sea was observed. The concentrations of IBP and salinity demonstrated a strong correlation $(r^2=0.96)$. This indicates that IBP showed conservative behavior in the study area, and seawater dilution is a major factor affecting distribution and variation of OPs in the Sammgem environment.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.283-284
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• 2006

The ship performs heat exchange using seawater to keep main engine and auxiliary machinery at optimum temperature. In heat exchanger, refrigerant located outside of copper tube is cooled by seawater flowing through inside of copper tube. On the other hand, seawater erosion and corrosion nay occasionally cause the corrosion of the copper tube in A/C(Air Conditioner) condenser. This corrosion of copper tube makes seawater and refrigerant mixed, seriously damaging A/C system. In this study, accordingly, the exact ive mechanism of the corrosion on the condenser entailing serious problems occasional is investigated through the electrochemical polarization experiments on the condenser's component materials. According to the experiments, the corrosive procedures on the copper tube was verified by the fact that passive film of the copper tube surface which is destroyed by the pressure of sucked seawater, is damaged by the corrosive ingredients in the seawater.

• Corrosion Science and Technology
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• v.19 no.3
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• pp.115-121
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• 2020

In this study, erosion tests and erosion-corrosion tests of Al5083-H321 aluminum alloy were conducted at various flow rates in seawater. The erosion tests were conducted at a flow rate of 0 to 20 m/s, and erosion-corrosion tests were performed by potentiodynamic polarization method at the same flow rate. Characteristic evaluation after the erosion test was conducted by surface analysis. Characteristic evaluation after the erosion-corrosion test was performed by Tafel extrapolation and surface analysis. The results of the surface analysis after the erosion test showed that surface damage tended to increase as the flow rate increased. In particular, intermetallic particles were separated due to the breakdown of the oxide film at 10 m/s or more. In the erosion-corrosion test, the corrosion current density increased as the flow rate increased. Additionally, the surface analysis showed that surface damage occurred in a vortex shape and the width of the surface damage tended to increase as the flow rate increased. Moreover, damage at 0 m/s, proceeded in a depth direction due to the growth of pitting corrosion, and the damaged area tended to increase due to acceleration of the intermetallic particle loss by the fluid impact.

• Ocean and Polar Research
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• v.30 no.4
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• pp.407-418
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• 2008

Seawater samples were collected at discrete depths from five stations across the polar front in the Drake Passage (Antarctic Ocean) by the $20^{th}$ Korea Antarctic Research Program in December, 2006. Nitrate concentrations of seawater increase with depth within the photic zone above the depth of Upper Circumpolar Deep Water (UCDW). In contrast, ${\delta}^{15}N$ values of seawater nitrate decrease with depth, showing a mirror image to the nitrate variation. Such a distinct vertical variation is mainly attributed to the degree of nitrate assimilation by phytoplankton as well as organic matter degradation of sinking particles within the surface layer. The preferential $^{14}{NO_3}^-$ assimilation by the phytoplankton causes $^{15}{NO_3}^-$ concentration to become high in a closedsystem surface-water environment during the primary production, whereas more $^{14}{NO_3}^-$ is added to the seawater during the degradation of sinking organic particles. The water-mass mixing seems to play an important role in the alteration of ${\delta}^{15}N$ values in the deep layer below the UCDW. Across the polar front, nitrate concentrations of surface seawater decrease and corresponding ${\delta}^{15}N$ values increase northward, which is likely due to the degree of nitrate utilization during the primary production. Based on the Rayleigh model, the calculated ${\varepsilon}$ (isotope effect of nitrate uptake) values between 4.0%o and 5.8%o were validated by the previously reported data, although the preformed ${\delta}^{15}{{NO_3}^-}_{initial}$ value of UCDW is important in the calculation of ${\varepsilon}$ values.

• Journal of the Korean institute of surface engineering
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• v.52 no.1
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• pp.23-29
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• 2019

Electrolytic corrosion of the ship's hull can be occurred due to stray current during welding work using shore power and electrical leakage using shore power supply. The electrolytic corrosion characteristics were investigated for Al5083-H321 through potentiodynamic polarization and galvanostatic corrosion test in natural seawater. Experiments of electrolytic corrosion were tested at various current densities ranging from $0.01mA/cm^2$ to $10mA/cm^2$ for 30 minutes, and at various applied time ranging from 60 to 240 minutes. Evaluation of electrolytic corrosion was carried out by Tafel extrapolation, weight loss, surface analysis after the experiment. In the electrolytic corrosion characteristics of Al5083-H321 as the current density increased, the surface damage tended to proportionally increase. In the current density of $0.01mA/cm^2$ for a applied long time, the damage tended to grow on the surface. In the case of $10mA/cm^2$ current density for a applied long time, the damage progressed to the depth direction of the surface, and the amount of weight loss per hour increased to 4 mg/hr.

• Ocean and Polar Research
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• v.25 no.spc3
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• pp.423-426
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• 2003

The seawater exchange breakwater equipped with an oscillating water channel and water transmitting pipes has a very spectacular function that seawater supply can be greatly increased due to the upsurge of the water surface inside the channel at resonance condition which can be reached when the incident wave period becomes close to the natural period of the channel. The variations of the water level and period inside the channel are very important factors in enhancing the efficiency of sea water exchange, especially when designing the breakwater cross-section in shallow water zone which requires longer resonance period with the elongated horizontal projection of the channel. In the present study, a hydraulic experiment was performed varying the length of the oscillating channel, and the resonance periods and water surface variations are analyzed in terms of water transmission through the pipes.

• Journal of the Korean institute of surface engineering
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• v.51 no.5
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• pp.316-324
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• 2018

Harsh seawater environment is subdivided into marine atmosphere, splash zone, tidal zone, submerged zone and bottom of sea depending on the exposed part. Since corrosion rate depends on the conditions of the exposed parts, proper protection and maintenance for each parts are essential for long-term use of steel structures in seawater environment. For steel structures which were installed in Shiwha Lake, a special maintenance system is required to guarantee its long-term durability and safety. As the tidal power plant has recently been operated, the salinity has risen due to the rapid influx of seawater upstream into Sihwa Lake and the corrosion tendency of the structure is variable according to the water level fluctuation. In this study, corrosion properties of steel structures under water level fluctuation was evaluated by corrosion rate measurement, visual inspection and natural potential measurement and their durability and life management were discussed in view of the effect of variation in of seawater level fluctuations in Shihwa Lake.

• Journal of Radiation Protection and Research
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• v.21 no.2
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• pp.107-115
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• 1996

An electrolytic enrichment technique was used to measure low levels of tritium in seawater around the Korean peninsula. Tritium concentrations were determined for surface seawater samples collected from the East Sea, the South Sea, and the Yellow Sea. The tritium concentrations in surface seawater samples from the study area ranged from $0.12 BqL^{-1}\;to\;1.50BqL^{-1}$ with a mean value of $0.60{\pm}0.35 BqL^{-1}$. The means of the tritium concentration were $0.54{\pm}0.30 BqL^{-1}$ for the East Sea, $0.48{\pm}0.35 BqL^{-1}$ for the South Sea, and $0.77{\pm}0.32 BqL^{-1}$ for the Yellow Sea. The tritium concentrations in the sea areas did not show much difference no matter where the samples were taken. Due to the limited number and distribution of sampling points, no systematic change in tritium levels with latitude was observed. Measured tritium levels were similar to those observed in other data collected near Japan, but higher than mid-Pacific Ocean measurements.

• Corrosion Science and Technology
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• v.20 no.5
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• pp.281-288
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• 2021

Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl^- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10^-4 mA/cm² and 1.11 × 10^-4 mA/cm² and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

• Journal of the Korea Institute of Building Construction
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• v.18 no.2
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• pp.185-193
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• 2018

In this study, using Granulated Blast Furnace Slag (GBFS), an industrial byproduct, and Phosphogypsum (PG), and Waste Lime (WL) as activator, non-sintering binder (NSB) which does not require a sintering process was produced, and the chemical penetration resistance was evaluated through a seawater resistance experiment. The result of the experiment showed that the inside of NSB mortar saw almost no influence from the ions in seawater due to its dense structure. Also, as it appears that only the surface reacts with ions in seawater while spreading inward is suppressed, the high seawater resistance of NSB could be confirmed.