• Title/Summary/Keyword: Surface Alloying

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Corrosion Behavior of AZ91 Magnesium Alloy (AZ91 마그네슘합금의 부식거동)

  • Yim, Chang Dong;Kim, Young Min;Park, Sung Hyuk;You, Bong Sun
    • Korean Journal of Metals and Materials
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    • v.50 no.9
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    • pp.619-627
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    • 2012
  • One of the barriers limiting wide applications of magnesium alloys to various industries is their poor corrosion resistance. The corrosion properties of AZ91 magnesium alloy, which is the most popular magnesium casting alloy, are affected by microstructural and environmental factors. The corrosion properties of AZ91 magnesium alloy are affected by the corrosion properties of ${\alpha}-Mg$ and ${\beta}$ phases, the volume fraction and distribution of ${\beta}$ phase and area ratio of ${\alpha}-Mg/{\beta}$ phases. The corrosion properties of AZ91 magnesium alloy under various environments also change according to the passivity of films and types of corrosion products formed on its surface. The corrosion resistance of the magnesium alloys can be improved by microstructural control through the addition of alloying elements and optimization of the production process.

A Study on Wear Properties of Alloys in High Temperature Condition (고온 환경에서 합금의 마모 및 마찰 특성에 관한 연구)

  • Choe, S.Y.;Nemati, Narguess;Kim, D.E.
    • Tribology and Lubricants
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    • v.35 no.1
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    • pp.24-29
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    • 2019
  • In this work we investigated the friction and wear characteristics of a magnesium alloy, which has been receiving much attention as a light metal in industrial applications such as automobiles and aerospace. Magnesium is one of the lightest structural material that has high specific strength, lightweight, low density and good formability. However, current issue of using magnesium alloy is that magnesium has weakness against temperature. As the temperature increases, magnesium undergoes poor creep resistance and ease of softening, and therefore, its mechanical strength decreases sharply. To solve this issue, a new type of magnesium alloy that retains high strength at high temperature has been proposed. The tribological behavior of this alloy was investigated using a tribotester with reciprocating motion and heating plate. A stainless steel ball was used as a counter surface. Results showed that extrusion process has similar wear behavior to the commonly used casting process but retains good mechanical strength and durability. The presence of an alloying element enhanced the wear properties especially in high temperature. This study is expected to be utilized as fundamental data for the replacement of high density materials currently used in mechanical industries to a much lighter and durable heat-resistant materials.

Microstructural Control of Al-Sn Alloy with Addition of Cu and Si (Cu와 Si 첨가에 의한 Al-Sn 합금의 미세조직 제어)

  • Son, Kwang Suk;Park, Tae Eun;Kim, Jin Soo;Kang, Sung Min;Kim, Tae Hwan;Kim, Donggyu
    • Korean Journal of Metals and Materials
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    • v.48 no.3
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    • pp.248-255
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    • 2010
  • The effect of various alloying elements and melt treatment on the microstructural control of Al-Sn metallic bearing alloy was investigated. The thickness of tin film crystallized around primary aluminum decreased with the addition of 5% Cu in Al-Sn alloy, with tin particles being reduced in size by intervening the Ostwald ripening. With the addition of Si in Al-10%Sn alloy, the tin particles were crystallized with eutectic silicon, resulting in uniform distribution of tin particles. With the addition of Cu and Si in Al-Sn alloy, both the tensile strength and yield strength increased, with the increasing rate of yield strength being less than that of tensile strength. Although the Al-10%Sn-7%Si alloy has similar tensile strength compared with Al-10%Sn-5%Cu, the former showed superior abrasion resistance, resulting from preventing the tin particles from movement to the abrasion surface.

The Formation of Anodic Oxide Film by Anodizing Voltage and Time of 6061 Aluminum Alloy (알루미늄 6061 합금의 양극 산화 인가 전압과 시간에 따른 표면의 산화피막층 형성 거동)

  • Park, Youngju;Jeong, Chanyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.68-72
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    • 2021
  • Aluminum is a lightweight metal and has excellent properties with regard to conductivity, workability, and strength. It has been used in various industries owing to its economic benefits. To improve upon the mechanical properties and processability by adding various alloying elements to aluminum, improving the corrosion resistance and heat resistance by electrochemically forming a porous anodic film having a thickness and hardness on the surface of the aluminum alloy is crucial. In this study, the aluminum 6061 alloy was controlled by an anodization process in a 0.3M oxalic acid electrolyte at room temperature to investigate the oxide film parameters such as porosity and thickness depending on the modulating applied voltage and time. The anodizing experiment was performed by increasing the time from 1 h to 9 h at 2-h intervals at applied voltages of 50 V and 60 V.

Comparison of punch life of powder high speed tool steel and high speed tool steel (분말고속도공구강과 고속도공구강의 펀치 수명 비교)

  • Lee, Woo-Ram;Lee, Chun-Kyu
    • Design & Manufacturing
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    • v.16 no.1
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    • pp.9-14
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    • 2022
  • A lot of research is being done on metal materials to improve the lifespan of molded parts. As a result, excellent mold materials have been developed that withstand high hardness at high temperatures and frictional heat generated from high-speed cutting. In this study, the press mold life of powder high-speed tool steel and general high-speed tool steel was compared. Powdered high-speed steel is composed of alloying elements such as tungsten, maldividene, cobalt, chromium, and vanadium in steel, which improves wear resistance compared to high-hardness and high-speed tool steels. The mold parts of both steel types were manufactured in the same way from heat treatment to machining, and the powder high-speed tool steel was 66HRC and the high-speed tool steel was 61HRC. As a result of the experiment, it was observed that the number of punching of powder high-speed tool steel was improved by 40-50%, and powder high-speed tool steel had fewer impurities, uniform texture, and excellent surface structure. It has a microscopic structure.

Analysis Mechanism of Roll Forming Manufacturing Process using HIP (Hot Isostatic Press) Process (HIP(열간 등방압) 공정을 이용한 압연 롤 제조 공정의 해석 메커니즘)

  • W. Kim
    • Transactions of Materials Processing
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    • v.32 no.3
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    • pp.114-121
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    • 2023
  • During rolling, rolling mill rolls endure wear when shaping metal billets into a desired form, such as bars, plates, and shapes. Such wear affects the lifespan of the rolls and product quality. Therefore, in addition to rigidity, wear performance is a key factor influencing the performance of rolling mill rolls. Conventional methods such as casting and forging have been used to manufacture rolling mill rolls. However, powder alloying methods are increasingly being adopted to enhance wear resistance. These powder manufacturing methods include atomization, canning to shape the powder, hot isostatic pressing to combine the powder alloy with conventional metals, and various wear performance tests on rolls prepared with powder alloys. In this study, numerical simulations and experimental tests were used to develop and elucidate the wear analysis mechanism of rolling mill rolls. The wear characteristics of the rolls under various rolling conditions were analyzed. In addition, experimental tests (wear and surface analysis tests) and wear theory (Archard wear model) were used to evaluate wear. These tests were performed on two different materials in various powder states to evaluate the different aspects of wear resistance. In particular, this study identifies the factors influencing the wear behavior of rolling mill rolls and proposes an analytical approach based on the actual production of products. The developed wear analysis mechanism can serve the future development of rolls with high wear resistance using new materials. Moreover, it can be applied in the mechanical and wear performance testing of new products.

Investigation of Through-thickness Microstructural Evolution in a 600 MPa-Grade Reinforced Steel Bar Manufactured by Tempcore Process (Tempcore 공정을 통해 제조된 600 MPa급 철근의 두께방향 미세구조 변화 분석)

  • Jiwon Park;Hyunji Kim;Singon Kang
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.6
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    • pp.367-373
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    • 2023
  • 600 MPa-grade deformed bar samples were manufactured by conventional hot rolling and subsequent Tempcore heat treatment processes. Considering the short-time water quenching step of the Tempcore process for hot-rolled steel, it is inevitable that the temperature profile of the deformed bar depends strongly on its position throughout the sample thickness. As a result, its microstructure can be easily divided into two regions, the surface and the core regions. The former is expected to have a fresh martensite microstructure under rapid cooling conditions, but self-tempering occurs due to the intense heat flow from the hot core region after the process. The latter is generally known to exhibit a mixed microstructure of ferrite and pearlite due to its slow cooling rate. In this study, detailed microstructural evolutions were examined through the thickness direction. The large variation of the microstructure through the thickness direction in the deformed bar samples is partly due to the easy carbon diffusion from the limited additions of alloying elements.

Effect of Milling Speed on the Structural and Magnetic Properties of Ni70Mn30 Alloy Prepared by Planetary Ball Mill Method

  • Hussain, Imad;Lee, Ji Eun;Jeon, So Eun;Cho, Hyun Ji;Huh, Seok-Hwan;Koo, Bon Heun;Lee, Chan Gyu
    • Korean Journal of Materials Research
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    • v.28 no.10
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    • pp.539-543
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    • 2018
  • We report the structural, morphological and magnetic properties of the $Ni_{70}Mn_{30}$ alloy prepared by Planetary Ball Mill method. Keeping the milling time constant for 30 h, the effect of different ball milling speeds on the synthesis and magnetic properties of the samples was thoroughly investigated. A remarkable variation in the morphology and average particle size was observed with the increase in milling speed. For the samples ball milled at 200 and 300 rpm, the average particle size and hence magnetization were decreased due to the increased lattice strain, distortion and surface effects which became prominent due to the increase in the thickness of the outer magnetically dead layer. For the samples ball milled at 400, 500 and 600 rpm however, the average particle size and hence magnetization were increased. This increased magnetization was attributed to the reduced surface area to volume ratio that ultimately led to the enhanced ferromagnetic interactions. The maximum saturation magnetization (75 emu/g at 1 T applied field) observed for the sample ball milled at 600 rpm and the low value of coercivity makes this material useful as soft magnetic material.

Oxide Nanolayers Grown on New Ternary Ti Based Alloy Surface by Galvanic Anodizing-Characteristics and Anticorrosive Properties

  • Calderon Moreno, J.M.;Drob, P.;Vasilescu, C.;Drob, S.I.;Popa, M.;Vasilescu, E.
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.257-264
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    • 2017
  • Film of new Ti-15Zr-5Nb alloy formed during galvanic anodizing in orthophosphoric acid solution was characterized by optical microscope, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and Raman micro-spectroscopy. Its anticorrosive properties were determined by electrochemical techniques. The film had a layer with nanotube-like porosity with diameters in 500-1000 nm range. The nano layer contained significant amounts of P and O as well as alloying element. Additionally, Raman micro-spectroscopy identified oxygen as oxygen ion in $TiO_2$ anatase and phosphorous as $P_2O_7{^{4-}}$ ion in phosphotitanate compound. All potentiodynamic polarization curves in artificial Carter-Brugirard saliva with pH values (pH= 3.96, 7.84, and 9.11) depending on the addition of 0.05M NaF revealed nobler behavior of anodized alloy and higher polarization resistance indicating the film is thicker and more compact nanolayer. Lower corrosion rates of the anodized alloy reduced toxicity due to less released ions into saliva. Bigger curvature radii in Nyquist plot and higher phase angle in Bode plot for the anodized alloy ascertain a thicker, more protective, insulating nanolayer existing on the anodized alloy. Additionally, ESI results indicate anodized film consists of an inner, compact, barrier, layer and an outer, less protective, porous layer.

Effect of Annealing Heat Treatment to Corrosion Resistance of a Copper (구리의 내식성에 미치는 어닐링 열처리의 영향)

  • Kim Jin-Kyung;Moon Kyung-Man;Lee Jin-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.654-661
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    • 2005
  • Copper is a well known alloying element that is used to improve the resistance to general corrosion of stainless steel And also Cu cation have the anti-fouling effect to inhibit adhesion of the marine algae and shellfish to the surface of heat exchanger cooling pipe or outside wall of the ship, Therefore there are some anti-fouling methods such as anti-fouling Paint mixed with copper oxide or MGPS(Marine Growth Preventing System) by using Cu cation dissolved to the sea wather solution. Cu cation can be dissolved spontaneously by galvanic current due to Potential difference between Cu and cooling pipe of heat exchanger with Ti material, which may be one of the anti-fouling designs. In this study the effect of annealing heat treatment to galvanic current and Polarization behavior was investigated with a electrochemical points of view such as measurement of corrosion Potential, anodic polarization curve. cyclic voltammetric curve, galvanic current etc The grain size of the surface in annealed at $700^{\circ}C$ was the smallest than that of other annealing temperatures. and also the corrosion Potential showed more positive potential than other annealing temperatures. The galvanic current between Ti and Cu with annealed at $700^{\circ}C$ was the largest value in the case of static condition. However its value in the case of flow condition was the smallest than the other temperatures. Therefore in order to increase anti-fouling effect by Cu cation, the optimum annealing temperature in static condition of sea water is $700^{\circ}C$, however non- heat treated specimen in the case of flow condition may be desirable.