• Journal of Korean Society for Atmospheric Environment
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• v.29 no.5
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• pp.642-655
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• 2013

In this study, semi-continuous measurements of $PM_{2.5}$ mass, organic and elemental carbon (OC and EC), black carbon (BC), and ionic species concentrations were made for the period of April 03~13, 2012, at a South Area Supersite at Gwangju. Possible sources causing the high concentrations of major chemical species in $PM_{2.5}$ observed during a haze episode were investigated. The measurement results, along with meteorological parameters, gaseous pollutants data, air mass back trajectory analyses and PSCF (potential source contribution function) results, were used to study the haze episode. Substantial enhancements of OC, EC, BC, $K^+$, $SO{_4}^{2-}$, $NO{_3}{^-}$, $NH{_4}{^+}$, and CO concentrations were closely associated with air masses coming from regions of forest fires in southeastern China, suggesting likely an impact of the forest fires. Also the PSCF maps for EC, OC, $SO{_4}^{2-}$, and $K^+$ demonstrate further that the long-range transport of smoke plumes of forest fires detected over the southeastern China could be a possible source of haze phenomena observed at the site. Another possible source leading to haze formation was likely from photochemistry of precursor gases such as volatile organic compounds, $SO_2$, and $NO_2$, resulting in accumulation of secondary organic aerosol, $SO{_4}^{2-}$ and $NO{_3}{^-}$. Throughout the episode, local wind directions were between 200 and $230^{\circ}C$, where two industrial areas are situated, with moderate wind speeds of 3~5 m/s, resulting in highly elevated concentration of $SO_2$ with a maximum of 15 ppb. The $SO{_4}^{2-}$ peak occurring in the afternoon hours coincided with maximum ambient temperature ($24^{\circ}C$) and ozone concentration (~100 ppb), and were driven by photochemistry of $SO_2$. As a result, the pattern of $SO{_4}^{2-}$ variations in relation to wind direction, $SO_2$ and $O_3$ concentrations, and the strong correlation between $SO_2$ and $SO{_4}^{2-}$ ($R^2=0.76$) suggests that in addition to the impact of smoke plumes from forest fires in the southeastern China, local $SO_2$ emissions were likely an important source of $SO{_4}^{2-}$ leading to haze formation at the site.

• Korean Journal of Agricultural and Forest Meteorology
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• v.9 no.2
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• pp.75-87
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• 2007

Groundwater recharge rates were estimated and compared in a headwater catchment at the Gwangneung Supersite using three different methods: water-table fluctuation (WTF), mass balance, and hydrograph separation techniques. Data were obtained during the rainy season from June to September 2005. Two different WTF methods estimated the groundwater recharge rate as 25.9% and 23.6%. The mass balance calculation of chloride ions indicated recharge rates of 13.4% on average. Baseflow separation using chloride ion as a tracer from six storm hydrographs produced a 14.0% net baseflow rate on average. Because of the implicit assumption of a long-term steady state without storage change, recharge rates calculated by mass balance and hydrograph separation were smaller than those done with WTF methods, which include the amount of increased storage due to the water-level rise. Subsequently, the WTF method is superior to others in the estimation of groundwater recharge rate to comprehend the dynamic characteristics of the hydrologic cycle.

• Korean Journal of Agricultural and Forest Meteorology
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• v.9 no.2
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• pp.149-160
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• 2007

KoFlux Gwangneung Supersite comprises complex topography and diverse vegetation types (and structures), which necessitate complementary multi-disciplinary measurements to understand energy and matter exchange. Here, we report the results of this ongoing research with special focuses on carbon/water budgets in Gwangneung forest, implications of inter-dependency between water and carbon cycles, and the importance of hydrology in carbon cycling under monsoon climate. Comprehensive biometric and chamber measurements indicated the mean annual net ecosystem productivity (NEP) of this forest to be ${\sim}2.6\;t\;C\;ha^{-1}y^{-1}$. In conjunction with the tower flux measurement, the preliminary carbon budget suggests the Gwangneung forest to be an important sink for atmospheric $CO_2$. The catchment scale water budget indicated that $30\sim40%$ of annual precipitation was apportioned to evapotranspiration (ET). The growing season average of the water use efficiency (WUE), determined from leaf carbon isotope ratios of representative tree species, was about $12{\mu}mol\;CO_2/mmol\;H_2O$ with noticeable seasonal variations. Such information on ET and WUE can be used to constrain the catchment scale carbon uptake. Inter-annual variations in tree ring growth and soil respiration rates correlated with the magnitude and the pattern of precipitation during the growing season, which requires further investigation of the effect of a monsoon climate on the catchment carbon cycle. Additionally, we examine whether structural and functional units exist in this catchment by characterizing the spatial heterogeneity of the study site, which will provide the linkage between different spatial and temporal scale measurements.