• 한국건축시공학회지
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• 제21권4호
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• pp.269-279
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• 2021

Palm Oil Fuel Ash(POFA)는 콘크리트의 물리적 특성 및 내구성을 향상시키기 위해 일정량 시멘트를 치환하여 사용된다. 그러나 높은 강열감량과 각진 입자 형상으로 인해 POFA를 사용한 콘크리트의 워커빌리티가 감소한다. 본 연구에서는 micro-POFA를 혼입한 시멘트 페이스트의 초기 물리적, 수화 특성에 감수제 종류 및 사용량이 미치는 영향을 mini-slump 실험, 초기 압축 강도, TGA, XRD, SEM을 이용하여 검토하였다. micro-POFA 치환율이 증가함에 따라 시멘트 페이스트의 유동성은 감소하였으며, 감수제의 사용량이 증가할수록 시멘트 페이스트의 유동성은 증가하였다. 또한, 감수제의 사용은 시멘트 페이스트의 초기 압축 강도를 저하시켰으며, 사용량이 증가할수록 압축 강도 저하가 뚜렷하게 나타났다. 미세분석을 통해 감수제가 C-S-H 형성을 억제하고 상대적으로 Ca(OH)₂의 생성량을 증가시켰기 때문이라고 사료된다.

• Computers and Concrete
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• 제5권6호
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• pp.559-572
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• 2008

The effects of fly ash and superplasticizer (SP) on workability of concrete are quite difficult to predict because they are dependent on other concrete ingredients. Because of high complexity of the relations between workability and concrete compositions, conventional regression analysis could be not sufficient to build an accurate model. In this study, a workability model has been built using artificial neural networks (ANN). In this model, the workability is a function of the content of all concrete ingredients, including cement, fly ash, blast furnace slag, water, superplasticizer, coarse aggregate, and fine aggregate. The effects of water/binder ratio (w/b), fly ash-binder ratio (fa/b), superplasticizer-binder ratio (SP/b), and water content on slump were explored by the trained ANN. This study led to the following conclusions: (1) ANN can build a more accurate workability model than polynomial regression. (2) Although the water content and SP/b were kept constant, a change in w/b and fa/b had a distinct effect on the workability properties. (3) An increasing content of fly ash decreased the workability, while raised the slump upper limit that can be obtained.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 추계 학술논문 발표대회
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• pp.35-36
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• 2016

Recently, with the increasing demand of high performance of concrete, the mix design of concrete mixture has became low water-to-binder ratio with high binder content. To compensate these trend of mix design, high range water reducer, or superplascizier has been invented to achieve high flowable concrete. Although this superplasticizer provides favorable workability based on its dispersing action on the components of concrete mixture, it has an limitation of decreasing viscosity of the mixture, and thus it is difficult to secure sufficient workability for high performance concrete mixtures with high binder content. To improve the workability of concrete with high viscosity, recently, low-viscosity type superplasticizer was introduced, and in this research, a fundamental properties of low-viscosity type superplasticizer is evaluated.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.148-149
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• 2022

The use of high-strength grout applied for facility foundations and bridges has recently been expanding in offshore wind farm. Wind farm in offshore require bearing capacity for horizontal loads such as wind, waves, and earthquakes. In order to improve the bearing force of the base part, sufficient fluidity and a certain strength should be ensured so that the high-strength grout is densely charged in the narrow space of the connection part. Therefore, in this study, changes in fluidity and strength according to the ratio of PC-based superplasticizer mixed in high-strength grout were measured. As a result, as the ratio of the superplasticizer increased, fluidity increased and strength decreased. However, the strength did not decrease when the ratio of superplasticizer was above a 0.005. Therefore, it was confirmed that the fluidity change was remarkable when a 0.005 ratio of PC-based superplasticizer were added.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.813-816
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• 2008

본 연구에서는 시멘트페이스트의 유동성 및 수화반응속도에 미치는 폴리카르본산계 고성능AE감수제의 영향에 대해서 첨가율, 분자구조 등의 관점에서 검토를 하였다. 시멘트페이스트의 유동성은 폴리카르본산계 고성능AE감수제를 첨가하는 것에 따라 증가하였다. 또한 그래프트가 짧은 폴리카르본산계 고성능AE감수제를 사용한 경우가 그래프트가 긴 것에 비해 저첨가율에서의 유동성은 향상되었다. 시멘트페이스트의 최고수화발열속도까지의 도달시간에 미치는 폴리카르본산계 고성능AE감수제의 영향은 첨가율이 증가함에 따라 증가하였다. 더욱이 시멘트페이스트의 유동성이 동일할 정도의 첨가량에 있어서도 그래프트가 긴 폴리카르본산계 고성능AE감수제의 경우가 그래프트의 길이가 짧은것의 경우보다 최고수화발열속도까지의 도달시간에 미치는 영향은 작다는 것을 알 수 있었다.

• 한국건설순환자원학회논문집
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• 제5권1호
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• pp.68-75
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• 2017

본 연구에서는 프리스트레스트 콘크리트용 고품질 그라우트를 개발하기 위한 기초 자료로 활용하기 위해 그라우트의 화학 혼화제로 고성능 감수제와 증점제의 양과 사용방법이 유동성, 블리딩률, 체적변화 및 압축강도에 미치는 영향에 대해 검토하였다. 증점제와 고성능 감수제가 유동성에 미치는 영향에 대해 검토한 결과, 증점제와 고성능 감수제를 조합사용한 경우에는 고성능 감수제의 사용량이 너무 적으면 응집현상이 발생하여 유동성이 저하되나, 고성능 감수제 사용량 0.1% 이상부터 유동성이 크게 향상되는 것으로 나타났다. 증점제의 사용량이 증가할수록 블리딩률이 감소하며, 고성능 감수제는 0.05%까지 블리딩률이 증가하나, 0.1%부터 블리딩률이 감소하는 것으로 나타났다. 또한 고성능 감수제와 증점제를 각각 0.15%를 조합한 그라우트의 배합이 유하시간, 플로우, 블리딩 및 체적변화 측면에서 가장 양호한 것으로 분석되었다.

• 한국건축시공학회지
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• 제3권1호
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• pp.115-122
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• 2003

In order to analyze liquidity change according to increasing the charge of superplasticizer, we inputted charges by dividing into six steps, 0% through 1.25%; at the same time, to observe liquidity change according to the change of charge-time, we carried out the experiment applying 30-minute intervals, i.e. at beginning of mixing, 30, 60 and 90 minutes. The results are below. 1) According to increasing the charge of superplasticizer, the liquidity of concrete was enhanced, however, when inputted 1.25%, a little segregation was occurred, which allowed us to make a conclusion that concrete performance would be deteriorated due to this segregation. 2) When we inputted 1.25% of superplsticizer, steady liquidity features were shown regardless of the charge-time of concrete, which allowed us to make a conclusion that this input would be the best for liquidity performance considering only liquidity features. 3) After analyzing the dynamical features of liquid concrete, the result showed that there was not significant effect on revelation of compressive strength. We concluded form this result that there was no influence on the stripping-time of a mold form. 4) When we charge superplasticizer in concrete more than 1%, we, in advance, should clearly judge the concrete performance required during constructing in site, as it were, the compressive strength or liquidity etc.; furthermore, we had better decide a charge and input-time of superplasticizer to meet the required performance.

• 한국세라믹학회지
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• 제47권5호
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• pp.387-393
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• 2010

To improve concrete quality one of the most widely used chemical admixtures is polycarboxylate type superplasticizer. Unlike lignosulfonate and naphthalene-sulfonate, it has high dispersion property and excellent sustainable dispersion property for cement and concrete. Thus, polycarboxylate type superplasticizer has been widely used as a high-performance water reducing admixture together with silica fume in high-performance concrete and other applications for the dispersion of high-strength concrete over 100 MPa. However, even though there have been many studied on the dispersion of concrete by the structure of polycarboxylate type superplasticizer, there have a few studied that clarified the relationships between its rheological properties and microstructure properties in the early hydration behavior of ordinary portland cement. To investigate the correlations between the rheological properties and microstructure of cementitious materials with polycarboxylate type superplasticizer, this study experimented on the rheology, pore structure, heat evolution, and consistency in early hydration as well as on the compressive strength by early dispersion characteristics.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.743-748
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• 2002

Properties of concrete have been tested with Polycarboxylic superplasticizers based on Malein Anhydride Acid Polymer synthesized in a laboratory, to decide the proper formulation for concrete. Ready-mixed concrete has been placed at field with the chosen formulated Polycarboxylic superplasticizer. The superplasticizer showed quite a performance in workability retention and strength development of concrete at laboratory test and field application.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.638-644
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• 1999

Workability time of superplasticized concrete is maintained generally for 30-60 minutes only. Therefore it is of great advantage for the concrete producer to use a high range water reducer which provides an extended slump life. Recently slump retentive srperplasticizer has been developed. Concrete mixing tests were done to know slump, setting, air content, bleeding and hardening characteristics of concrete using slump retentive superplasticizer. With slump retentive superplasticizer, high quality concrete was produced and slump loss of concrete was reduced in big way, making long transportation time possible as a practical alternative to on-site addition.